Experimental study of the crystallization conditions of ailikites in the Ilbokich uplift of the Siberian platform
DOI:
https://doi.org/10.17308/geology/1609-0691/2026/3/62-74Keywords:
ultramafic lamprophyre, aillikite, experiment, melts, upper mantle, peridotiteAbstract
Introduction: the object of this article is the ultramafic lamprophyres, whose low-power dikes were discovered during drilling within the Riphean Irkineevo-Chadobetsky trough of the Ilboki Upland on the southwestern edge of the Siberian Craton. Experimental studies of ultramafic lamprophyres (in this case, ailikites) have not been conducted before. Such studies will allow us to identify mineral parageneses that crystallized at different pressures and thus compare them with the conditions of lamprophyre formation. The objective of this work is to experimentally study the phase associations of the ailikites of the Irkineevo-Chadobetsky depression at various pressures. Based on the mineralogical, petrographic, and thermobarometric results obtained for these rocks, two pressure and temperature ranges were selected for the experiments: 4−5 GPa/1000−15000C and 2.5 GPa/1000−11000C.
Methodology: the experiments used the powder of the least altered sample of Ilb28 ailikit, selected in the gas condensate field Ilbokichskoe-3. Experiments at 4.0 and 5.0 GPa were carried out on the anvil-hole type apparatus NL-13T with a toroidal seal based on a press with a force of 500 tons, and at 2.5 GPa – on the cylinder-piston apparatus CP-40. The analysis of the experimental products was carried out using a CamScan MV 2300 (VEGA TS 5130MM) electron microscope equipped with EDS INCA Energy 350 and a Tescan VEGA-II XMU equipped with EDS INCA Energy 450 and WDS Oxford INCA Wave 700 at the D.S. Korzhinsky Institute of Experimental Mineralogy of the Russian Academy of Sciences (IEM RAS).
Results and discussion: experiments at 2.5 to 5.0 GPa revealed phase associations that may be characteristic of ailikites under various P-T conditions. The phase association at 5.0 GPa differs significantly from the natural ailikite association. At 4.0 and 2.5 GPa, the phase associations of Ol+Cpx+Phl are similar and differ only in the quantitative ratios of these phases. These associations are similar to the natural ailikite association, and the compositions of the phases at these pressures are most similar to the compositions of minerals in ailikite. All of this indicates that the pressures at which the ailikite mineral associations were formed did not exceed 4.0 GPa, but they could have formed over a wide temperature range.
Conclusion: the study of the obtained mineral associations showed that the indicated TiO2- and F-rich ultramafic lamprophyres were formed at pressures not exceeding 4.0 GPa. The indicator phases are Ti-F-containing clinohumite and Ti-containing garnet, which appear at a pressure of 5.0 GPa.
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1. Rock N. M. S. The nature and origin of ultramafic lamprophyres: alnöites and allied rocks. Journal of Petrology, 1986, vol. 27, no. 1, pp. 155−196.
2. Rock N. M. S. Lamprophyres. New York, 1991. 285 p.
3. Le Maitre R. W., Streckeisen A., Zanettin B., Le Bas M. J., Bonin B., Bateman P. Igneous Rocks. A Classification and Glossary of Terms (2nd ed.) Cambridge University Press, 2002.
4. Tappe S., Foley S. F., Jenner G. A., Kjarsgaad B. A. Integrating Ultramafic Lamprophyres into the IUGS Classification of Igneous Rocks: Rationale and Implications. Journal of Petrology, 2005, vol. 46, no. 9, pp. 1893–1900.
5. Kargin A. V., Nosova A. A., Postnikov A. V., Chugaev A. V., Postnikova O. V., Popova L. P., Poshibaev V. V., Sazonova L. V., Dokuchaev A. Y., Smirnova M. D. Devonian ultramafic lamprophyre in the Irkineeva–Chadobets trough in the southwest of the Siberian Platform: Age, composition, and implications for diamond potential prediction. Geol. Ore Deposits, 2016, vol. 58, pp. 383–403.
6. Zhdanov V. V., Kostin A. E., Kukharenko E. A., Landa E. A., Lukyanova L. I., Masaitis V. L., Moskalenko Z. D., Pushkarev Yu. D., Sharpenok L. N., Markovsky B. A., Mikhailov V. L. Petrographicheskii kodeks. Magmaticheskie, metamorficheskie, metasomaticheskie, impaktnyie obrazovaniya. [Petrographic Code. Igneous, metamorphic, metasomatic, impact formations.] 2nd edition. Saint Petersburg publ., 2008, 196 p. (In Russ.)
7. Nosova A. A., Sazonova L. V., Kargin A. V., Smirnova M. D., Lapin A. V., Shcherbakov V.D. Olivine in ultramafic lamprophyres: chemistry, crystallisation, and melt sources of Siberian Pre- and post-trap aillikites. Contributions to Mineralogy and Petrology, 2018, vol. 173, no. 55.
8. Smirnova M. D., Sazonova L. V., Nosova A. A., Kargin A. V., Shcherbakov V. D. Phenocrysts and megacrysts of olivines from ultramafic lamprophyres of the chadobets and ilbokich uplifts. European Geosciences Union General Assembly, Geophysical Research Abstracts, Germany: Copernicus GmbH on behalf of the European Geosciences Union, 2017, 19 p. EGU2017–335.
9. De Hoog J., Gall, L., Cornell D. H. Trace-element geochemistry of mantle olivine and application to mantle petrogenesis and geothermobarometry. Chemical Geology, 2010, vol. 270, no. 1, pp. 196−215.
10. Girnis A. V., Brey G. P., Ryabchikov I. D. Origin of group 1A kimberlites: fluid saturated melting experiments at 45–55 kbar. Earth and Planetary Science Letters, 1995, vol.134, no. 3−4, pp. 283−296.
11. Tappe S., Foley S. F., Jenner G. A., Heaman L. M., Kjarsgaard B. A., Romer R. L., Stracke A., Joyce N., Hoefs J. Genesis of ultramafic lamprophyres and carbonatites at Aillik Bay, Labrador: a consequence of incipient lithospheric thinning beneath the North Atlantic craton. Journal of Petrology, 2006, vol. 47, no. 7, pp. 1261−1315.
12. Dasgupta, Rajdeep, Hirschmann Marc M., McDonough William F., Spiegelman Marc, Withers Anthony C. Trace element partitioning between garnet lherzolite and carbonatite at 6.6 and 8.6 GPa with applications to the geochemistry of the mantle and of mantle-derived melts. Chemical Geology, 2009, vol. 262, no. 1, pp. 57−77.
13. Hasterok D., Chapman. D. S. Heat production and geotherms for the continental lithosphere // Earth and Planetary Science Letters, 2011, vol. 307, no. 1, pp. 59−70.
14. Starikova A. Е., Prokopyev I. R., Doroshkevich A. G., Kargin A. V., Nosova A. A., Kovalev S. Melt inclusions in olivine as a source of information on the composition and evolution of deep melts of aillikites (ultramafic lamprophyres) of the Ilbokichi uplift, the SW Siberian platform. Geodynamics and Tectonophysics, 2022, vol. 13, no. 4.
15. Kamenetsky V. S., Golovin A. V., Maas R., Giuliani A., Kamenetsky M. B., Weiss Y. Towards a new model for kimberlite petrogenesis: Evidence from unaltered kimberlites and mantle minerals. Earth-Science Reviews, 2014, vol. 139, pp. 145−167.
16. Sharygin I. S., Litasov K. D., Shatskiy A., Safonov O. G., Golovin A. V., Ohtani E., Pokhilenko N. P. Experimental constraints on orthopyroxene dissolution in alkali-carbonate melts in the lithospheric mantle: Implications for kimberlite melt composition and magma ascent. Chemical Geology, 2017, vol. 455, pp. 44−56.
17. Nosova A. A., Kargin A. V., Sazonova L. V., Dubinina E. O., Chugaev A. V., Lebedeva N. M., Yudin D. S., Larionova Y. O., Abersteiner A., Gareev B. I., Batalin G. A. Sr-Nd-Pb isotopic systematic and geochronology of ultramafic alkaline magmatism of the southwestern margin of the Siberian Craton: Metasomatism of the sub-continental lithospheric mantle related to subduction and plume events. Lithos, 2020, vol. 365.
18. Prokopyev I. R., Starikova A. E, Doroshkevich A. G., Nugumanova Y., Potapov V. Petrogenesis of Ultramafic Lamprophyres from the Terina Complex (Chadobets Upland, Russia): Mineralogy and Melt Inclusion Composition. Minerals, 2020, vol. 10, no. 5, 419 p.
19. Starikova A. Е., Prokopyev I. R., Doroshkevich A. G., Ragozin A., Chervyakovsky V. Polygenic Nature of Olivines from the Ultramafic Lamprophyres of the Terina Complex (Chadobets Upland, Siberian Platform) Based on Trace Element Composition, Crystalline, and Melt Inclusion Data. Minerals, 2021, vol. 11, no. 4, 408 p.
20. Kamenetsky V. S., Yaxley G. M. Carbonate–silicate liquid immiscibility in the mantle propels kimberlite magma ascent. Geochimica et Cosmochimica Acta, 2015, vol. 158, pp. 48−56.
21. Sokol A. G., Kruk A. N. Role of CO2 in the evolution of Kimberlite Magma: Experimental constraints at 5.5 GPa and 1200–1450 °C. Lithos, 2021, vol. 386.
22. Girnis A. V., Bulatov V. K., Brey G. P., Gerdes A., Höfer H. E. Trace element partitioning between mantle minerals and silico-carbonate melts at 6–12 GPa and applications to mantle metasomatism and kimberlite genesis. Lithos, 2013, vol. 160, pp. 183−200.
23. McGetchin T. R., Silver L. T., Chodos A. A. Titanoclinohumite: A possible mineralogical site for water in the upper mantle. Journal of Geophysical Research, 1970, vol. 75, no. 2, pp. 255−259.
24. Engi M., Lindsley D. H. Stability of titanian clinohumite: Experiments and thermodynamic analysis. Contributions to Mineralogy and Petrology, 1980, vol.72, pp. 415−424.
25. Harlow G. E. Diopside F-rich phlogopite at high P and T: systematics, crystal chemistry and the stability of KMgF3, clinohumite and chondrodite. GeologicalMaterials Research, 2002, vol. 4, no. 3, pp. 1–28.
26. Yang. J.-J. Titanian clinohumite–garnet–pyroxene rock from the Su-Lu UHP metamorphic terrane, China: chemical evolution and tectonic implications. Lithos, 2003, 70, no. 3–4, pp. 359−379.
27. Aoki K., Fujino K., Akaogi M. Titanochondrodite and titanoclinohumite derived from the upper mantle in the Buell Park kimberlite, Arizona, USA. Conributions to Mineralogy and Petrology, 1976, vol. 56, pp. 243−253.
28. Rock N. M. S., Bowes D. R., Wright A.E. Lamprophyres: Glasgow. Blackie, 1991, 285 p.
29. Brey G. P., Bulatov V. K., Girnis A. V. Influence of water and fluorine on melting of carbonated peridotite at 6 and 10 GPa. Lithos, 2009, vol. 112, pp. 249–259.
30. Hermann J., Fitz Gerald J., Malaspina N., Berry A. J., Scambelluri M. OH-bearing planar defects in olivine produced by the breakdown of Ti-rich humite minerals from Dabie Shan (China). Contributions to Mineralogy and Petrology, 2007, vol. 153, pp. 417–428.
31. Stalder R., Ulmer P. Phase relations of a serpentine composition between 5 and 14 GPa: significance of clinohumite and phase E as water carriers into the transition zone. Contributions to Mineralogy and Petrology, 2021, vol. 140, pp. 670−679.
32. Dalton J. A., Presnall D. C. The Continuum of Primary Carbonatitic–Kimberlitic Melt Compositions in Equilibrium with Lherzolite: Data from the System CaO–MgO–Al2O3–SiO2–CO2 at 6 GPa. Journal of Petrology, 1998, vol. 39, no. 11−12, pp. 1953–1964.
33. Moore K. R, Wood B. J. The Transition from Carbonate to Silicate Melts in the CaO—MgO—SiO2—CO2 System. Journal of Petrology, 1998, vol. 39, no. 11−12, pp. 1943–1951. https://doi.org/10.1093/petroj/39.11-12.1943
34. Gudfinnsson G. H., Presnall D. C. Continuous Gradations among Primary Carbonatitic, Kimberlitic, Melilititic, Basaltic, Picritic, and Komatiitic Melts in Equilibrium with Garnet Lherzolite at 3–8 GPa. Journal of Petrology, 2005, vol. 46, no. 8, pp. 1645–1659.
35. Foley S. F., Yaxley G. M., Rosenthal A., Buhre S., Kiseeva E. S., Rapp R. P., Jacob D. E. The composition of near-solidus melts of peridotite in the presence of CO2 and H2O between 40 and 60 kbar. Lithos, 2009, vol. 112, no. 1, pp. 274−283.
36. Litasov K. D., Ohtani E. Solidus and phase relations of carbonated peridotite in the system CaO–Al2O3–MgO–SiO2–Na2O–CO2 to the lower mantle depths. Physics of the Earth and Planetary Interiors, 2009, vol. 177, no. 1–2, pp. 46−58.
Safonov O.G., Kamenetsky V. S., Perchuk L. L. Links between carbonatite and kimberlite melts in chloride-carbonate-silicate systems: experiments and application to natural assemblages. Journal of Petrology, 2011, vol. 52, no. 7−8, pp. 1307–1331.











