Планетарная центрифуга как хроматографический прибор
Ключевые слова:
жидкостная хроматография со свободной неподвижной фазой, планетарная центрифуга, вращающаяся спиральная колонка
Аннотация
Рассмотрены базовые факторы, определяющие действие планетарных центрифуг,
используемых в жидкостной хроматографии со свободной неподвижной фазой. Показано, что
предложенная физическая модель позволяет описывать как хроматографический эффект разделения
компонентов при их движении по спиральной колонке, так и появление неподвижной фазы,
удерживаемой в колонке возникающим при сложном вращении силовым полем.
Скачивания
Данные скачивания пока не доступны.
Литература
1.Ito Y., Weinstein M., Aoki I., Harada R. et
al. The Coil Planet Centrifuge // Nature, 1966,
V. 212, pp. 985-987.
2.Ito Y., Bowman R.L. Countercurrent
Chromatography: Liquid-Liquid Partition
Chromatography without Solid Support, Science,
1970, V. 167, No. 3916, pp. 281-283.
3.Ito Y., Bowman R.L. Countercurrent
Chromatography with Flow-Through Coil Planet
Centrifuge, Science, 1971, V. 173, No. 3995, pp.
420-422.
4.Berthod A., Maryutina T., Spivakov B. et al.
Countercurrent Chromatography in Analytical
Chemistry (IUPAC Technical Report), Pure and
Appl. Chem. 2009, V. 81, No. 2, pp. 355-387.
5.Countercurrent Chromatography: The
Support-Free Liquid Stationary Phase, Ed.
Berthod A. Comprehensive Analytical
Chemistry, 2002, V. 38, pp. 1-397.
6.Conway W.D. Countercurrent
Chromatography: Apparatus, Theory and
Applications. New York: VCH Publishers, 1990,
475 p.
7.Zolotov Yu.A., Spivakov B.Ya., Maryutina
T.A. et al. Partition countercurrent
chromatography in inorganic analysis, Fresenius
Z. Anal. Chem, 1989, V. 335, No. 8, P. 938-944.
8.Maryutina T.A., Spivakov B.Ya., Tschopel
P. Application of countercurrent
chromatography to purification of chemical
reagents, Fresenius J. Anal. Chem, 1996, V. 356,
No. 7, pp. 430-434.
9.Ignatova S.N., Maryutina T.A., Spivakov
B.Ya. et al. Group separation of trace rare
earth elements by countercurrent chromatography
for their determination in high-purity
calcium chloride, Fresenius J. Anal. Chem.,
2001, V. 370, No. 8, P. 1109-1113.
10. Maryutina T.A., Fedotov P.S., Spivakov
B.Ya. Application of Countercurrent
Chromatography in Inorganic Analysis,
Countercurrent Chromatography. Eds. Menet J.-
M., Thiébaut D. Chromatographic Science
Series, 1999, V. 82, pp. 171-221.
11. Fedotov P.S. Untraditional Applications
of Countercurrent Chromatography, J. Liq.
Chrom. & Rel. Tech., 2002. V. 25, No. 13-15,
pp. 2065-2078.
12. Fedotov P.S., Spivakov B.Ya., Shkinev
V.M. Possibility of field-flow fractionation
of macromolecules and particles in a rotating
coiled tube, Anal. Sci., 2000, V. 16, No. 4,
pp. 535-536.
13. Katasonova O.N., Fedotov P.S.,
Spivakov B.Ya. et al. Behavior of Solid
Microparticles in Their Fractionation on a
Rotating Coiled Column, J. Anal. Chem., 2003,
V. 58, No. 5, pp. 473-477.
14. Katasonova O.N., Fedotov P.S.,
Karandashev V.K. et al. Application of rotating
coiled columns to the fractionation of soil
particles and to the sequential extraction of
heavy-metal species from silty, dusty, and sandy
fractions, J. Anal. Chem., 2005, V. 60, No. 7,
pp. 684-690.
15. Fedotov P.S., Ermolin M.S., Savonina
E.Yu. et al. Fractionation of nano- and
microparticles in a rotating conoidal coiled
column, J. Anal. Chem., 2010, V. 65, No. 12,
pp. 1209-1214.
16. Fedotov P.S. Rotating coiled columns in
the speciation analysis of natural samples:
Dynamic fractionation of element forms in soils,
sludges, and bottom sediments, J. Anal. Chem.,
2012, V. 67, No. 5, pp. 399-413.
17. Fedotov P.S., Savonina E.Yu., Spivakov
B.Ya. et al. Possibilities for the harmonization
of methods of the dynamic fractionation
of elements in soils and bottom sediments, J.
Anal. Chem., 2012, V. 67, No. 10, pp. 851-861.
18. Ito Y. Development of high-speed
countercurrent chromatography, Advances in
Chromatogr., 1984, V. 24, pp. 181-226.
19. Ito Y. Cross-Axis Synchronous FlowThrough
Coil Planet Centrifuge Free of Rotary
Грибов и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
18
Seals for Preparative Countercurrent Chromatography.
Part I. Apparatus and Analysis of
Acceleration, Separation Science and Technology,
1987, V. 22, No. 8-10, pp. 1971-1987.
20. Mandava N.B., Ito Y. Principles and
instrumentation of countercurrent chromatography,
Countercurrent Chromatography. Theory
and Practice. Eds. Mandava N.B., Ito Y. Chromatographic
Science Series., 1988, V. 44,
pp. 79-442.
21. Ito Y. Speculation on the Mechanism of
Unilateral Hydrodynamic Distribution of Two
Immiscible Solvent Phases in the Rotating Coil,
J. Liq. Chromatogr., 1992, V. 15, No. 15-16,
pp. 2639-2675.
22. Ito Y. High-Speed Countercurrent Chromatography.
New York: Wiley, 1996, 477 p.
23. Wood P.L., Hawes D., Janaway L. et al.
Stationary Phase Retention in CCC: Modelling
the J-Type Centrifuge as a Constant Pressure
Drop Pump, J. Liq. Chrom. & Rel. Tech., 2003,
V. 26, No.9-10, pp. 1373-1396.
24. Fedotov P.S., Kronrod V.A., Maryutina
T.A. et al. Simulation of the Mechanism of
Liquid Stationary Phase Retention in a Rotating
Coil Column: Hydrophobic Liquid Systems, J.
Anal. Chem., 2002, V. 57, No. 1, pp. 24-30.
25. Fedotov P.S., Kronrod V.A., Kasatonova
O.N. Simulation of the motion of solid
particles in the carrier liquid flow in a rotating
coiled column, J. Anal. Chem., 2005, V. 60,
No. 4, pp. 310-316.
26. Zhukovsky N.E. Teoreticheskaya
mehanika [Theoretical Mechanics]. M.-L.:
GITTL, 1952, 107 p.
al. The Coil Planet Centrifuge // Nature, 1966,
V. 212, pp. 985-987.
2.Ito Y., Bowman R.L. Countercurrent
Chromatography: Liquid-Liquid Partition
Chromatography without Solid Support, Science,
1970, V. 167, No. 3916, pp. 281-283.
3.Ito Y., Bowman R.L. Countercurrent
Chromatography with Flow-Through Coil Planet
Centrifuge, Science, 1971, V. 173, No. 3995, pp.
420-422.
4.Berthod A., Maryutina T., Spivakov B. et al.
Countercurrent Chromatography in Analytical
Chemistry (IUPAC Technical Report), Pure and
Appl. Chem. 2009, V. 81, No. 2, pp. 355-387.
5.Countercurrent Chromatography: The
Support-Free Liquid Stationary Phase, Ed.
Berthod A. Comprehensive Analytical
Chemistry, 2002, V. 38, pp. 1-397.
6.Conway W.D. Countercurrent
Chromatography: Apparatus, Theory and
Applications. New York: VCH Publishers, 1990,
475 p.
7.Zolotov Yu.A., Spivakov B.Ya., Maryutina
T.A. et al. Partition countercurrent
chromatography in inorganic analysis, Fresenius
Z. Anal. Chem, 1989, V. 335, No. 8, P. 938-944.
8.Maryutina T.A., Spivakov B.Ya., Tschopel
P. Application of countercurrent
chromatography to purification of chemical
reagents, Fresenius J. Anal. Chem, 1996, V. 356,
No. 7, pp. 430-434.
9.Ignatova S.N., Maryutina T.A., Spivakov
B.Ya. et al. Group separation of trace rare
earth elements by countercurrent chromatography
for their determination in high-purity
calcium chloride, Fresenius J. Anal. Chem.,
2001, V. 370, No. 8, P. 1109-1113.
10. Maryutina T.A., Fedotov P.S., Spivakov
B.Ya. Application of Countercurrent
Chromatography in Inorganic Analysis,
Countercurrent Chromatography. Eds. Menet J.-
M., Thiébaut D. Chromatographic Science
Series, 1999, V. 82, pp. 171-221.
11. Fedotov P.S. Untraditional Applications
of Countercurrent Chromatography, J. Liq.
Chrom. & Rel. Tech., 2002. V. 25, No. 13-15,
pp. 2065-2078.
12. Fedotov P.S., Spivakov B.Ya., Shkinev
V.M. Possibility of field-flow fractionation
of macromolecules and particles in a rotating
coiled tube, Anal. Sci., 2000, V. 16, No. 4,
pp. 535-536.
13. Katasonova O.N., Fedotov P.S.,
Spivakov B.Ya. et al. Behavior of Solid
Microparticles in Their Fractionation on a
Rotating Coiled Column, J. Anal. Chem., 2003,
V. 58, No. 5, pp. 473-477.
14. Katasonova O.N., Fedotov P.S.,
Karandashev V.K. et al. Application of rotating
coiled columns to the fractionation of soil
particles and to the sequential extraction of
heavy-metal species from silty, dusty, and sandy
fractions, J. Anal. Chem., 2005, V. 60, No. 7,
pp. 684-690.
15. Fedotov P.S., Ermolin M.S., Savonina
E.Yu. et al. Fractionation of nano- and
microparticles in a rotating conoidal coiled
column, J. Anal. Chem., 2010, V. 65, No. 12,
pp. 1209-1214.
16. Fedotov P.S. Rotating coiled columns in
the speciation analysis of natural samples:
Dynamic fractionation of element forms in soils,
sludges, and bottom sediments, J. Anal. Chem.,
2012, V. 67, No. 5, pp. 399-413.
17. Fedotov P.S., Savonina E.Yu., Spivakov
B.Ya. et al. Possibilities for the harmonization
of methods of the dynamic fractionation
of elements in soils and bottom sediments, J.
Anal. Chem., 2012, V. 67, No. 10, pp. 851-861.
18. Ito Y. Development of high-speed
countercurrent chromatography, Advances in
Chromatogr., 1984, V. 24, pp. 181-226.
19. Ito Y. Cross-Axis Synchronous FlowThrough
Coil Planet Centrifuge Free of Rotary
Грибов и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
18
Seals for Preparative Countercurrent Chromatography.
Part I. Apparatus and Analysis of
Acceleration, Separation Science and Technology,
1987, V. 22, No. 8-10, pp. 1971-1987.
20. Mandava N.B., Ito Y. Principles and
instrumentation of countercurrent chromatography,
Countercurrent Chromatography. Theory
and Practice. Eds. Mandava N.B., Ito Y. Chromatographic
Science Series., 1988, V. 44,
pp. 79-442.
21. Ito Y. Speculation on the Mechanism of
Unilateral Hydrodynamic Distribution of Two
Immiscible Solvent Phases in the Rotating Coil,
J. Liq. Chromatogr., 1992, V. 15, No. 15-16,
pp. 2639-2675.
22. Ito Y. High-Speed Countercurrent Chromatography.
New York: Wiley, 1996, 477 p.
23. Wood P.L., Hawes D., Janaway L. et al.
Stationary Phase Retention in CCC: Modelling
the J-Type Centrifuge as a Constant Pressure
Drop Pump, J. Liq. Chrom. & Rel. Tech., 2003,
V. 26, No.9-10, pp. 1373-1396.
24. Fedotov P.S., Kronrod V.A., Maryutina
T.A. et al. Simulation of the Mechanism of
Liquid Stationary Phase Retention in a Rotating
Coil Column: Hydrophobic Liquid Systems, J.
Anal. Chem., 2002, V. 57, No. 1, pp. 24-30.
25. Fedotov P.S., Kronrod V.A., Kasatonova
O.N. Simulation of the motion of solid
particles in the carrier liquid flow in a rotating
coiled column, J. Anal. Chem., 2005, V. 60,
No. 4, pp. 310-316.
26. Zhukovsky N.E. Teoreticheskaya
mehanika [Theoretical Mechanics]. M.-L.:
GITTL, 1952, 107 p.
Опубликован
2015-02-06
Как цитировать
Михайлов, И. В., & Грибов, Л. А. (2015). Планетарная центрифуга как хроматографический прибор. Сорбционные и хроматографические процессы, 15(1), 8-18. https://doi.org/10.17308/sorpchrom.2015.15/249
Раздел
Статьи
