Hydration of heterogeneous cation-exchange membranes in hydrogen and amino acids forms. I. Study by IR-spectroscopy

Authors

  • Elena V. Lantsuzskaya Ph.D., Senior Researcher, Department of Analytical Chemistry, Voronezh State University, Voronezh
  • Tatiana V. Eliseeva Ph.D., Lecturer, Department of Analytical Chemistry, Voronezh State University, Voronezh, tatyanaeliseeva@yandex.ru
  • Galina Yu. Oros Ph. D., Senior Researcher, Department of Analytical Chemistry, Voronezh State University, Voronezh
  • Mikhail A. Chernikov Postgraduate Student, Department of Analytical Chemistry, Voronezh State University, Voronezh
  • Vladimir F. Selemenev Dr. Sc., Prof., Head of Analytical Chemistry Department, Voronezh State University, Voronezh
  • Anastasiya Yu. Sholokhova student of the Anaalytical Сhemistry departmentt, Voronezh State University, Voronezh

Keywords:

arginine, histidine, cation-exchange membrane, hydration, IR-spectrum.

Abstract

Hydration characteristics of heterogeneous sulfocation-exchange membranes MK-40 and
FTCM-E in hydrogen and amino acid’s forms are studied by IR-spectroscopy. Energy of hydrogen bonds
in ion-exchange membrane is calculated on the basis of absorption strips displacement in the IRspectrum.
Basic amino acids sorption by the membrane leads to a decrease of total water content in the
membrane phase and to an increase of water molecules fraction having high values of hydrogen bonds
energy.

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Published

2019-11-18

How to Cite

Hydration of heterogeneous cation-exchange membranes in hydrogen and amino acids forms. I. Study by IR-spectroscopy. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 14(1). https://journals.vsu.ru/sorpchrom/article/view/1440

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