Liquid chromatography of water-soluble homopolymers and copolymers of N-vinylpyrrolidone

Authors

  • Valerii D. Krasikov Dr.Sc.Chem., leading researcher, Institute of Macromolecular Compounds Russian Academy of Sciences, St.Petersburg, lenchrom@hq.macro.ru
  • Nikolay I. Gorshkov PhD, senior researcher, Institute of Macromolecular Compounds Russian Academy of Sciences, St.Petersburg
  • Irina I. Malakhova PhD, senior researcher, Institute of Macromolecular Compounds Russian Academy of Sciences, St.Petersburg
  • Andrei Yu. Murko student, St.Petersburg State Technological Institute, St.Petersburg
  • Yurii V. Pohvoschev researcher, Institute of Macromolecular Compounds Russian Academ, St.Petersburg

Keywords:

water-soluble polymers, copolymers, hydrodynamic size, size exclusion chromatography, molecular weight characteristics, universal calibration.

Abstract

In present publication the complexing properties of N-vinylpyrrolidone homopolymers and Nvinyl
or N-allyliminodiacetic acids copolymers are studied. The factors responsible for hydrodynamic
behavior of these polymers (copolymer) in dilute solution - eluent in high performance exclusion liquid
chromatography (HPELC) are considered. The workability of Benoit universal calibration curve for
molecular characteristics of N-vinyl amide copolymers with amine comonomers by HPELC is
demonstrated

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Published

2019-11-20

Issue

Vol. 13 No. 1 (2013): Sorbtsionnye i Khromatograficheskie Protsessy

Section

Статьи

How to Cite

Liquid chromatography of water-soluble homopolymers and copolymers of N-vinylpyrrolidone. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 13(1). https://journals.vsu.ru/sorpchrom/article/view/1596

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