Competitive sorption parameter for description of retention in liquid chromatography

Authors

  • Anatoly M. Dolgonosov Dr.Sc.Chem., Lead. research sci., Lab. of sorption methods, GEOKHI RAS, Moscow, e-mail: amdolgo@mail.ru

Keywords:

physical adsorption, competitive sorption, liquid chromatography, Henry law constant, multicomponent mobile phase, capacity coefficient.

Abstract

Adsorption model based on physical adsorption characteristics is proposed. Equilibrium
equations for liquid chromatography are deduced. Effects difficult for experimental investigation are
found by study of sorption system behavior under transition from adsorption to competitive sorption.
Theoretical analysis of some features of experimental dependences is carried out.

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Published

2019-11-25

Issue

Vol. 11 No. 1 (2011): Sorbtsionnye i Khromatograficheskie Protsessy

Section

Статьи

How to Cite

Competitive sorption parameter for description of retention in liquid chromatography. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 11(1). https://journals.vsu.ru/sorpchrom/article/view/1896

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