Adsorption, competition sorption and solvation characteristics for description of retention in liquid chromatography. I. Model of system with monocomponent eluent

Authors

  • Anatoly M. Dolgonosov Dr.Sc.Chem., Lead. research sci., Lab. of sorption methods, GEOKHI RAS, Moskow, e-maol: amdolgo@mail.ru

Keywords:

high performance liquid chromatography, physical-chemical model of equilibrium, competition sorption parameter, adsorption, solvation.

Abstract

A theoretical approach, which unifies the basic features of various retention mechanisms in high
performance liquid chromatography, is developed. An expression for retention factor (distribution
coefficient) of an analyte, special cases of which are described in literature, is deduced

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Published

2019-11-26

Issue

Vol. 11 No. 4 (2011): Sorbtsionnye i Khromatograficheskie Protsessy

Section

Статьи

How to Cite

Adsorption, competition sorption and solvation characteristics for description of retention in liquid chromatography. I. Model of system with monocomponent eluent. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 11(4). https://journals.vsu.ru/sorpchrom/article/view/1946

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