Transport properties of hybrid perfluorinated membranes MF-4SC volumetrically modified using halloysite nanotubes

Authors

  • Д. С. Афонин Afonin Denis S. – senior engineer, Department of Physical and Colloid Chemistry, Gubkin Russian State University of Oil and Gas, Moscow
  • А. Н. Филиппов Filippov Anatoly N. – Prof., Department of Higher Mathematics, Dr. Sci. (Physics and Mathematics), Gubkin Russian State University of Oil and Gas, Moscow, e-mail: filippov.a@gubkin.ru
  • Н. А. Кононенко Kononenko Natalia А. – Prof., Dr. Sci. (Chemistry), Department of Physical Chemistry, Kuban State University, Krasnodar
  • С. А. Шкирская Shkirskaya Svetlana А. - Associate Prof., Ph.D. (Chemistry), Department of Physical Chemistry, Kuban State University, Krasnodar

DOI:

https://doi.org/10.17308/sorpchrom.2015.15/342

Keywords:

perfluorinated membranes, halloysite nanotubes, volumetric modification, diffusion permeability, electric conductivity

Abstract

The transport properties of new hybrid materials for fuel cells and catalysis based on sulfacationic
membrane MF-4SC and halloysite nanotubes are studied. Physico-chemical characteristics of hybrid
membranes were calculated from the experimental data of NaCl solutions diffusion through the membrane
into the water using the Nernst-Planck approach and the least square method. To clarify the results of
calculations we can take into account both the diffusion layers. It is shown that adding halloysite nanotube
into a bulk matrix of the perfluorinated membrane markedly affects their exchange capacity as well as
structural and transport properties of modified membranes.

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Published

2018-02-20

How to Cite

Transport properties of hybrid perfluorinated membranes MF-4SC volumetrically modified using halloysite nanotubes. (2018). Sorbtsionnye I Khromatograficheskie Protsessy, 15(6), 867-873. https://doi.org/10.17308/sorpchrom.2015.15/342