Вещественный состав битума Оренбургского Приуралья
Ключевые слова:
битум, карбонаты, металлы, Волго-Уральская нефтегазоносная провинция, микроскопия, рентгенофазовый анализ, Рамановская спектроскопия
Аннотация
Введени: Статья посвящена особенностям вещественного состава битума из его проявления в Оренбургском Приуралье. При изучении закономерностей распределения металлов, в том числе благородных, в нефтегазовых месторождениях Оренбургской части Волго-Уральской нефтегазоносной провинции проводились и исследования образцов битумов с различных площадей и месторождений платформенного Оренбуржья. Особый интерес вызвал образец твердой черной породы, содержащей битум, обнаруженной в Предуральском краевом прогибе. Цель данной работы - изучение вещественного состава образца твердой черной породы, содержащей битум, обнаруженной в Оренбургском Приуралье. Методика: Вещественный состав битума был изучен методами рентгенофазового и спектрального анализов, микроскопическими методами, методом Рамановской спектроскопии. Результаты и обсуждение: По данным микроскопических методов образец представляет собой обломочную породу черного цвета с битумом и минеральными включениями преимущественно карбонатного состава. Также битум содержит обломки кварца, идиоморфные кристаллы кварца и мелкозернистую кварцевую породу. По данным порошковой рентгенографии минеральная составляющая битума представлена смесью доломита, кальцита и кварца. Наличие углистого вещества разной степени метаморфизма (от слабо измененного органического вещества до антрацитоподобного угля) в битуме выявлено методом Рамановской спектроскопии. Определение металлов в битуме выполняли спектральным анализом. Содержания обнаруженных металлов сравнивали с кларками этих металлов в карбонатных породах. Сравнительный анализ показал, что повышенные содержания обнаруживают следующие металлы: Cu, Pb, Ni, Co, Cr, Mo, Sn, Be, Ag, Ga, Ba, Zn, Mn, Sc, La, Nb. Заключение: Минеральный состав природного битума представлен, в основном, доломитом, кальцитом, кварцем. В этом битуме также фиксируются различные формы углеродистого вещества – углистое вещество разной степени метаморфизма. В битуме установлены повышенные содержания следующих металлов по сравнению со средними содержаниями этих металлов в карбонатных породах: Co, Nb, Cu, Be, Ba, Zr, Ag, Mn и другие.
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Литература
1. Ponomareva G.A. Prostranstvenny`e zakonomernosti raspredeleniya platinoidov v mestorozhdeniyax uglevodorodov Orenburgskoj oblasti [Spatial patterns of distribution of platinoids in hydrocarbon deposits of the Orenburg region]. Geologiya, geoe`kologiya i resursny`j potencial Urala i sopredel`ny`x territorij: materialy` X Vserossijskoj molodezhnoj konferencii. Ufa, Respublika Bashkortostan. [Geology, Geoecology and Resource Potential of the Urals and Adjacent Territories: materials of the X All-Russian Youth Conference.]. Ufa, Republic of Bashkortostan, Moscow, «Pero» publ., 2022, pp. 156−160 (In Russ.)
2. Ponomareva G.A., Ponomarev A.A. Zakonomernosti raspredeleniya platinoidov v galogenny`x formaciyax Yuzhnogo Predural`ya [Distribution patterns of platinoids in halogen rock masses in the Southern Urals] Gornyi Zhurnal − Mining Journal, 2021, no. 12, pp. 10–14 (In Russ.)
3. Ovchinnikov V.V., Ponomareva G.A. K voprosu o genezise Sadkinskogo mestorozhdeniya asfal'tita [To the question of the genesis of the Sadkinsky asphaltite deposit]. Vestnik Orenburgskogo gosudarstvennogo universiteta. – Vestnik of the Orenburg State University, 2015, no. 3, pp. 171–176 (In Russ.)
4. Ponomareva G.A., Ovchinnikov V.V., Sergeeva O.V., Selina T.V. Proyavlenie prirodnogo asfal'tita v Orenburgskoj oblasti [The manifestation of natural asphaltite in the Orenburg region]. Universitetskij kompleks kak regional'nyj centr obrazovaniya, nauki i kul'tury: materialy` Vserossijskoj nauchno-metodicheskoj konferencii. Orenburgskij gos. un-t. E`lektron. dan [University complex as a regional center of education, science and culture: materials of the All-Russian Scientific and Methodological Conference. Orenburg
State University. Electron. Dan]. Orenburg publ., 2017, pp. 1328–1332 (In Russ.)
5. Gorozhanin V.M., Gorozhanina E.N. Sledy migracii uglevodorodov i pereraspredelenie zalezhej po razrezu (YUzhnyj Ural i vostok platformy) [Traces of hydrocarbon migration and redistribution of deposits along the section (South Urals and the east of the platform)]. Genezis, migraciya i formirovanie mestorozhdenij uglevodorodnogo syr'ya v kontekste ih poiska, razvedki i razrabotki: materialy` Vserossijskoj nauchno-prakticheskoj konferencii [Genesis, migration and formation of hydrocarbon deposits in the context
of their search, exploration and development: materials of the All-Russian scientific and practical conference]. Orenburg, OOO «TI-POGRAFIYA «AGENTSTVO PRESSA» publ., 2018, pp. 17–21 (In Russ.)
6. Fedorov S.F., Diment K.E., Kulakov A.I., Makhonkov O.M., Shpilman I.A. Zakonomernosti razmeshcheniya nefti i gaza Orenburgskoj oblasti [Patterns of oil and gas distribution in the Orenburg region]. Tektonika i razmeshchenie neftegazovyh mestorozhdenij vostoka Russkoj platformy [Tectonics and distribution of oil and gas fields in the east of the Russian platform]. Moscow, Nauka publ., 1968, pp. 81–105 (In Russ.)
7. Yushkin N.P. Teoriya i metody mineralogii (izbrannye problemy) [Theory and methods of mineralogy (selected problems)]. Leningrad, Nauka publ., 1977, 291 p. (In Russ.)
8. Silaev V.I., Brockmans M.A.T.M., Petrovsky V.A., Sukharev A.E., Khazov A.F. Mineralogo-geohimicheskie svojstva tverdyh bitumov v kontekste prognoza neftegazonosnosti (na primere Minusinskogo mezhgornogo progiba) [Mineralogical and geochemical properties of solid bitumen in the context of forecasting oil and gas content (on the example of the Minusinsk intermountain trough)]. Vestnik instituta geologii Komi nauchnogo centra Ural`skogo otdeleniya Rossijskoj Akademii Nauk. – Bulletin of the Institute of Geology of the Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences, 2017, no. 6 (270), pp. 3–12 (In Russ.)
9. Martirosyan O.V. K voprosu o meste organicheskih mineralov i mineraloidov v obshchej sistematike mineralov [On the question of the place of organic minerals and mineraloids in the general taxonomy of minerals]. Zapiski Rossijskogo mineralogicheskogo obshhestva – Proceedings of the Russian Mineralogical Society, 2021, no 2, pp. 106–111 (In Russ.)
10. Baranov V.K., Galimov A.G., Dentskevich I.A. et ol. Geologicheskoe stroenie i neftegazonosnost' Orenburgskoj oblasti [Geological structure and oil and gas content of the Orenburg region]. Orenburg, Orenburg book publishing house publ., 1997, 272 p. (In Russ.)
11. Bazhenova T.K., Kushmar I.A. Osnovnye cherty geologii i geohimii prirodnyh bitumov domezozojskogo megabassejna Sibirskoj platformy [The main features of the geology and geochemistry of natural bitumens of the pre-Mesozoic megabasin of the Siberian platform]. Leningrad, Nedra publ., 2006, pp. 132–145 (In Russ.)
12. Spravochnik po geohimii [Handbook of Geochemistry]. Ed. by G.V. Voitkevich, A.V. Kokina, A.E. Miroshnikova, V.G. Prokhorov. Moscow, Nedra publ., 1990, 490 p. (In Russ.)
13. Skibitskaya N.A., Efimov A.G., Kapustin V.M., Chernysheva E.A., Politykina M.A., Burkhanova I.O., Bolshakov M.N., Navrotsky O.A., Marutyan O.O. Uvelichenie resursnogo potenciala Orenburgskogo NGKM v rezul'tate ocenki prognoznyh resursov poputnyh komponentov matrichnoj nefti – metallov (redkih i redkozemel'nyh, cvetnyh i blagorodnyh) [Increasing the resource potential of the Orenburg oil and gas condensate field as a result of assessing the predicted resources of associated components of matrix oilmetals (rare and rare earth, non-ferrous and precious)]. Novye napravleniya rabot na neft' i gaz, innovacionnye tekhnologii razrabotki ih mestorozhdenij, perspektivy dobychi netradicionnogo uglevodorodnogo syr'ya: materialy` Vserossijskoj nauchno-prakticheskoj konferencii [New directions of work on oil and gas, innovative technologies for the development of their fields, prospects for the production of unconventional hydrocarbon raw materials: materials of the All-Russian scientific and practical conference]. Orenburg, OOO «TIPOGRAFIYa «AGENTSTVO PRESSA» publ., 2019, pp. 98–102 (In Russ.)
14. Gottikh R.P., Pisotsky B.I., Zhuravlev D.Z. Geohimicheskie osobennosti nefti razlichnyh regionov i vozmozhnyj istochnik metallov v nej [Geochemical features of oil from different regions and a possible source of metals in it]. Doklady` Rossijskoj akademii
nauk. – Reports of the Russian Academy of Sciences, 2008, vol. 422, no. 1, pp. 88–92 (In Russ.)
15. Punanova S. Geochemical Peculiarities of the distribution of trace elements in caustobioliths. Geophysical Research: Abstracts. EGU General Assembly 2016. Austria. Vienna, 2016, Vol. 18, 1 р.
16. Punanova S. Trace elements’ features of mature hydrocarbon systems. 28-th International Meeting on Organic Geochemistry (IMOG). Italy. Florence, 2017, 2 р.
17. Mzhachikh K.I. K voprosu o genezise sernistyh asfal'tovasfal'titov Orenburgskoj oblasti [On the question of the genesis of sulfurous asphalts and asphaltites of the Orenburg region]. Geologiya i razrabotka neftyanyh mestorozhdenij (Trudy Giprovostokneft'. Vyp. 2) [Geology and development of oil fields (Proceedings of Giprovostokneft. Issue 2)]. Moscow, Gostoptekhizdat publ., 1959, рр. 178–200. (In Russ.)
18. Musikhin G.D. Mineraly Orenburgskoj oblasti: V serii «Prirodnoe raznoobrazie YUzhnogo Urala» [Minerals of the Orenburg region: In the series «Natural diversity of the Southern Urals»]. Yekaterinburg, Ural Branch of the Russian Academy of Sciences publ., 1996, 96 p. (In Russ.)
19. Likhoman O.A. Geologicheskie zakonomernosti razmeshcheniya rtutnoj mineralizacii na territorii yugo-vostoka Vostochno-Evropejskoj platformy [Geological patterns of the distribution of mercury mineralization in the southeast of the East European platform]. Litologiya osadochnyh kompleksov Evrazii i shel'fovyh oblastej: materialy` IX Vserossijskogo litologicheskogo soveshhaniya (s mezhdunarodny`m uchastiem) [Lithology of sedimentary complexes of Eurasia and shelf areas: materials of the IX All-Russian Lithological Conference (with international participation)]. Kazan, Izdatel`stvo Kazanskogo universiteta publ., 2019, pp. 260–262 (In Russ.)
2. Ponomareva G.A., Ponomarev A.A. Zakonomernosti raspredeleniya platinoidov v galogenny`x formaciyax Yuzhnogo Predural`ya [Distribution patterns of platinoids in halogen rock masses in the Southern Urals] Gornyi Zhurnal − Mining Journal, 2021, no. 12, pp. 10–14 (In Russ.)
3. Ovchinnikov V.V., Ponomareva G.A. K voprosu o genezise Sadkinskogo mestorozhdeniya asfal'tita [To the question of the genesis of the Sadkinsky asphaltite deposit]. Vestnik Orenburgskogo gosudarstvennogo universiteta. – Vestnik of the Orenburg State University, 2015, no. 3, pp. 171–176 (In Russ.)
4. Ponomareva G.A., Ovchinnikov V.V., Sergeeva O.V., Selina T.V. Proyavlenie prirodnogo asfal'tita v Orenburgskoj oblasti [The manifestation of natural asphaltite in the Orenburg region]. Universitetskij kompleks kak regional'nyj centr obrazovaniya, nauki i kul'tury: materialy` Vserossijskoj nauchno-metodicheskoj konferencii. Orenburgskij gos. un-t. E`lektron. dan [University complex as a regional center of education, science and culture: materials of the All-Russian Scientific and Methodological Conference. Orenburg
State University. Electron. Dan]. Orenburg publ., 2017, pp. 1328–1332 (In Russ.)
5. Gorozhanin V.M., Gorozhanina E.N. Sledy migracii uglevodorodov i pereraspredelenie zalezhej po razrezu (YUzhnyj Ural i vostok platformy) [Traces of hydrocarbon migration and redistribution of deposits along the section (South Urals and the east of the platform)]. Genezis, migraciya i formirovanie mestorozhdenij uglevodorodnogo syr'ya v kontekste ih poiska, razvedki i razrabotki: materialy` Vserossijskoj nauchno-prakticheskoj konferencii [Genesis, migration and formation of hydrocarbon deposits in the context
of their search, exploration and development: materials of the All-Russian scientific and practical conference]. Orenburg, OOO «TI-POGRAFIYA «AGENTSTVO PRESSA» publ., 2018, pp. 17–21 (In Russ.)
6. Fedorov S.F., Diment K.E., Kulakov A.I., Makhonkov O.M., Shpilman I.A. Zakonomernosti razmeshcheniya nefti i gaza Orenburgskoj oblasti [Patterns of oil and gas distribution in the Orenburg region]. Tektonika i razmeshchenie neftegazovyh mestorozhdenij vostoka Russkoj platformy [Tectonics and distribution of oil and gas fields in the east of the Russian platform]. Moscow, Nauka publ., 1968, pp. 81–105 (In Russ.)
7. Yushkin N.P. Teoriya i metody mineralogii (izbrannye problemy) [Theory and methods of mineralogy (selected problems)]. Leningrad, Nauka publ., 1977, 291 p. (In Russ.)
8. Silaev V.I., Brockmans M.A.T.M., Petrovsky V.A., Sukharev A.E., Khazov A.F. Mineralogo-geohimicheskie svojstva tverdyh bitumov v kontekste prognoza neftegazonosnosti (na primere Minusinskogo mezhgornogo progiba) [Mineralogical and geochemical properties of solid bitumen in the context of forecasting oil and gas content (on the example of the Minusinsk intermountain trough)]. Vestnik instituta geologii Komi nauchnogo centra Ural`skogo otdeleniya Rossijskoj Akademii Nauk. – Bulletin of the Institute of Geology of the Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences, 2017, no. 6 (270), pp. 3–12 (In Russ.)
9. Martirosyan O.V. K voprosu o meste organicheskih mineralov i mineraloidov v obshchej sistematike mineralov [On the question of the place of organic minerals and mineraloids in the general taxonomy of minerals]. Zapiski Rossijskogo mineralogicheskogo obshhestva – Proceedings of the Russian Mineralogical Society, 2021, no 2, pp. 106–111 (In Russ.)
10. Baranov V.K., Galimov A.G., Dentskevich I.A. et ol. Geologicheskoe stroenie i neftegazonosnost' Orenburgskoj oblasti [Geological structure and oil and gas content of the Orenburg region]. Orenburg, Orenburg book publishing house publ., 1997, 272 p. (In Russ.)
11. Bazhenova T.K., Kushmar I.A. Osnovnye cherty geologii i geohimii prirodnyh bitumov domezozojskogo megabassejna Sibirskoj platformy [The main features of the geology and geochemistry of natural bitumens of the pre-Mesozoic megabasin of the Siberian platform]. Leningrad, Nedra publ., 2006, pp. 132–145 (In Russ.)
12. Spravochnik po geohimii [Handbook of Geochemistry]. Ed. by G.V. Voitkevich, A.V. Kokina, A.E. Miroshnikova, V.G. Prokhorov. Moscow, Nedra publ., 1990, 490 p. (In Russ.)
13. Skibitskaya N.A., Efimov A.G., Kapustin V.M., Chernysheva E.A., Politykina M.A., Burkhanova I.O., Bolshakov M.N., Navrotsky O.A., Marutyan O.O. Uvelichenie resursnogo potenciala Orenburgskogo NGKM v rezul'tate ocenki prognoznyh resursov poputnyh komponentov matrichnoj nefti – metallov (redkih i redkozemel'nyh, cvetnyh i blagorodnyh) [Increasing the resource potential of the Orenburg oil and gas condensate field as a result of assessing the predicted resources of associated components of matrix oilmetals (rare and rare earth, non-ferrous and precious)]. Novye napravleniya rabot na neft' i gaz, innovacionnye tekhnologii razrabotki ih mestorozhdenij, perspektivy dobychi netradicionnogo uglevodorodnogo syr'ya: materialy` Vserossijskoj nauchno-prakticheskoj konferencii [New directions of work on oil and gas, innovative technologies for the development of their fields, prospects for the production of unconventional hydrocarbon raw materials: materials of the All-Russian scientific and practical conference]. Orenburg, OOO «TIPOGRAFIYa «AGENTSTVO PRESSA» publ., 2019, pp. 98–102 (In Russ.)
14. Gottikh R.P., Pisotsky B.I., Zhuravlev D.Z. Geohimicheskie osobennosti nefti razlichnyh regionov i vozmozhnyj istochnik metallov v nej [Geochemical features of oil from different regions and a possible source of metals in it]. Doklady` Rossijskoj akademii
nauk. – Reports of the Russian Academy of Sciences, 2008, vol. 422, no. 1, pp. 88–92 (In Russ.)
15. Punanova S. Geochemical Peculiarities of the distribution of trace elements in caustobioliths. Geophysical Research: Abstracts. EGU General Assembly 2016. Austria. Vienna, 2016, Vol. 18, 1 р.
16. Punanova S. Trace elements’ features of mature hydrocarbon systems. 28-th International Meeting on Organic Geochemistry (IMOG). Italy. Florence, 2017, 2 р.
17. Mzhachikh K.I. K voprosu o genezise sernistyh asfal'tovasfal'titov Orenburgskoj oblasti [On the question of the genesis of sulfurous asphalts and asphaltites of the Orenburg region]. Geologiya i razrabotka neftyanyh mestorozhdenij (Trudy Giprovostokneft'. Vyp. 2) [Geology and development of oil fields (Proceedings of Giprovostokneft. Issue 2)]. Moscow, Gostoptekhizdat publ., 1959, рр. 178–200. (In Russ.)
18. Musikhin G.D. Mineraly Orenburgskoj oblasti: V serii «Prirodnoe raznoobrazie YUzhnogo Urala» [Minerals of the Orenburg region: In the series «Natural diversity of the Southern Urals»]. Yekaterinburg, Ural Branch of the Russian Academy of Sciences publ., 1996, 96 p. (In Russ.)
19. Likhoman O.A. Geologicheskie zakonomernosti razmeshcheniya rtutnoj mineralizacii na territorii yugo-vostoka Vostochno-Evropejskoj platformy [Geological patterns of the distribution of mercury mineralization in the southeast of the East European platform]. Litologiya osadochnyh kompleksov Evrazii i shel'fovyh oblastej: materialy` IX Vserossijskogo litologicheskogo soveshhaniya (s mezhdunarodny`m uchastiem) [Lithology of sedimentary complexes of Eurasia and shelf areas: materials of the IX All-Russian Lithological Conference (with international participation)]. Kazan, Izdatel`stvo Kazanskogo universiteta publ., 2019, pp. 260–262 (In Russ.)
Опубликован
2023-03-23
Как цитировать
Пономарева, Г. А., & Петрищев, В. П. (2023). Вещественный состав битума Оренбургского Приуралья. Вестник ВГУ. Серия: Геология, (1), 80-88. https://doi.org/10.17308/geology/1609-0691/2023/1/80-88
Выпуск
Раздел
Петрология, вулканология, геохимия
