Polarity characterization of gas-chromatographic stationary phase on base of theoretical description of intermolecular interactions. I. H-bond absence case

Authors

  • Anatoly M. Dolgonosov Dr.Sci.(Chem.), Leading scientific researcher, Lab of Sorption Methods, GEOKHI RAS; Prof. of Chemistry Department, new technologies and materials, Dubna International University for Nature, Society and Man
  • Elena A. Zaytseva Bachelor of Chemistry Department, new technologies and materials, Dubna International University for Nature, Society and Man

Keywords:

intermolecular interactions, the polarity of the stationary phase, gas chromatography, adsorption energy.

Abstract

Ideas about the polar and non-polar intermolecular interactions are developed on the basis of
quantum-mechanical approaches, in particular the theory of generalized charges. The theoretical description
is extended to the phenomena in a gas chromatography. A new method of polarity characterization for
chromatographic phases by retention indices of arbitrary molecules with use the theoretical description is
created; it does not require special experiments with special substances

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Published

2019-11-19

Issue

Vol. 14 No. 4 (2014): Sorbtsionnye i Khromatograficheskie Protsessy

Section

Статьи

How to Cite

Polarity characterization of gas-chromatographic stationary phase on base of theoretical description of intermolecular interactions. I. H-bond absence case. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 14(4). https://journals.vsu.ru/sorpchrom/article/view/1519

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