Влияние термической дегидратации полигидроксиалюминиевого монтмориллонита на адсорбцию четыреххлористого углерода
Ключевые слова:
адсорбция, изотерма, изостера адсорбции, теплота адсорбции, монтмориллонит.
Аннотация
Исследованы изменения поверхностных свойств и пористой структуры монтмориллонита при
замене обменного катиона минерала на полигидроксиалюминиевые. Предварительное
термовакуумирование оказывает существенное влияние на адсорбционные свойства
полигидроксиалюминиевого монтмориллонита (ПГАМ) по отношению к четыреххлористому
углероду. По данным серий изостер адсорбции CCl4 на дегидратированных ПГАМ, установлены
зависимости теплот адсорбции от количества адсорбированного вещества.
Скачивания
Данные скачивания пока не доступны.
Литература
1. Pribylov A.A., Muminov S.Z., Kalinnikova
I.I. et al. Adsorbtsiya gazov na sloistykh
silikatakh pri vysokikh davleniyakh [Adsorption
of gases in lamellar silicates under high
pressures], Izv. Akademii nauk. Ser.khim, 2013,
No 10, pp.2102-2107.
2. Muminov S.Z., Gulyamova D.B. Teplota
adsorbtsii parov piridina na
poligidroksialyuminievom montmorillonite
[Heat Adsorption of Pyridine Vapors on
Polyhydroxyaluminum Montmorillonite],
Russian Journal of Physical Chem. A, 2000, V.
74, No 6, pp.1085-1089.
3. Muminov S.Z., Pribylov A.A., Gulyamova
D.B. et al. Equilibrium Adsorption of n-Hexane
and Carbon Tetrachloride vapors on sodium and
polyhydroxyaluminum Montmorillonites,
Colloid journal, 2009, V. 71, No 5, pp.672-677.
4. Muminov S.Z., Gulyamova D.B., Pribylov
A.A. Adsorption of Acetonitrile Vapor on
Sodium and Polyhydroxyaluminum
Montmorillonites, Colloid Journal, 2006, V. 68,
No 5, pp.584-587.
5. Muminov S.Z., Khandamov D.A.,
Rakhimova G.B. Heats of n-Hexane and n-
Heptane Vapor Adsorption Montmorillonite,
Russian Journal of Physical Chem. A, 2011, V.
85., No 1, pp.112-116.
6. Muminov S.Z., Gulyamova D.B., Aripov
E.A. Adsorbtsiya parov benzola na
termoobrabotannom montmorillonite s
poligidroksialyuminievymi kationami
[Adsorption of Benzene Vapors on Thermal
Processing Montmorillonite With
Polyhydroxyaluminum Cations], Russian Journal of Physical Chem. A, 1993, V. 67, No
12, pp.2436-2438.
7. Muminov S.Z., Gulyamova D.B. Teplota
adsorbtsii parov metilovogo spirta na
mikroporistom montmorillonite [Heat
Adsorption of Methanol Vapor on Microporous
Montmorillonite], Russian Journal of Physical
Chem. A, 1997, V. 71, No 10, pp.1834-1836.
8. Pribylov A.A., Muminov S.Z., Kalinnikova
I.I., Shchekhovtsova L.G. Adsorbtsiya dioksida
ugleroda na montmorillonitakh razlichnykh
kationo-obmennykh form, Kolloidn. Zhurn,
2010, T.72, No 3. pp. 409-411.
9. Stacey M.H. Alumina-Pillared clays and
their adsorptive properties, Catalysis today.
1988. V. 2/3. pp. 621-631.
10. Pinnavaia T.S. Intercalated clay catalysts,
Science, 1983 V. 220, No 4595, pp. 365-369.
11. Fomkin A.A., Muminov S.Z., Pulin A.L.
et al. Adsorbtsionnaya deformatsiya
mikroporistykh adsorbentov/Sovremennye
problemy teorii adsorbtsii [Modern Problems
Theory of Adsorption], M., 1995, V. 2, pp.172-
179.
12. Fomkin A.A. Adsorbtsiya v
mikroporistykh adsorbentakh/Adsorbtsiya,
adsorbenty i sorbtsionnye protsessy v
nanoporistykh materialakh [Adsorption,
Adsorbents and Sorption Processes at
Microporous Materials], M., 2011, pp. 133-161.
13. Matsumoto M., Shinoda S., Takahashi H.,
Saito Y. Adsorption properties of pillar
intercalated montmorillonite, Bull Chem.
Soc.Jpn, 1987, V. 57, No 1, pp. 1795-1801.
14. Vargaftik N.B. Spravochnik po
teplofizicheskim svoistvam gazov i zhidkostei
[Handbook for Heat Physics Properties of
Liquids and Gases], M., Nauka, 1972, 720 p.
15. Muminov S.Z. Ustanovka dlya
neposredstvennogo izmereniya izoster
adsorbtsii [Plant for Direct Measure of Isosters
Adsorption] Uzbekskii khim.zhurn, 1965, No 6,
pp. 58-62.
16. Muminov S.Z., Aripov E.A., Issledovanie
v oblasti termodinamiki i termokhimii adsorbtsii
na glinistykh mineralakh [Studies in
Thermodynamics and Thermochemistry of
Adsorption on Clay Minerals], Tashkent, Fan.
1987, 144 p.
17. De Boer J.H. The structure and properties
of porous materials, London, Butterworth, 1958,
pp. 68.
18. Muminov S.Z., Aripov E.A., Rakhimov
A.A./Adsorbtsiya i poristost'. Pod red
[Adsorption and Porosity], M., Nauka, 1976, pp.
71-72.
19. Barrer R.M., Reay J.S.S. Sorption and
intercalation by montmorillonites, Trans.
Faraday Soc, 1957, V. 53, pp. 1253-1258.
20. Dubinin M.M. Fundamentals of the
Theory of physical adsorption of Gases and
Vapours in Micropores, In Adsorption-
Desorption Phenomena, London-New York,
Acad. Press, 1972, pp. 3-11.
21. Muminov S.Z., Gulyamova D.B., Seitova
E.A. Temperature Dependence of the
Adsorption of Carbon Tetrachloride on a
Microporous Clay adsorbent, Colloid Journal,
2001, V. 63, No. 6, pp.746-749.
22. Kiselev A.V., Kovaleva N.V., Korolev
A.Ya. et al. Khimicheskoe modifitsirovanie
poverkhnosti adsorbentov i ego vliyanie na
adsorbtsionnye svoistva [Chemical
Modification of Adsorbents Surface and its
Influence on Adsorption Properties], Dokl. AN
SSSR, 1959, V. 124, No 3, pp. 617-622.
I.I. et al. Adsorbtsiya gazov na sloistykh
silikatakh pri vysokikh davleniyakh [Adsorption
of gases in lamellar silicates under high
pressures], Izv. Akademii nauk. Ser.khim, 2013,
No 10, pp.2102-2107.
2. Muminov S.Z., Gulyamova D.B. Teplota
adsorbtsii parov piridina na
poligidroksialyuminievom montmorillonite
[Heat Adsorption of Pyridine Vapors on
Polyhydroxyaluminum Montmorillonite],
Russian Journal of Physical Chem. A, 2000, V.
74, No 6, pp.1085-1089.
3. Muminov S.Z., Pribylov A.A., Gulyamova
D.B. et al. Equilibrium Adsorption of n-Hexane
and Carbon Tetrachloride vapors on sodium and
polyhydroxyaluminum Montmorillonites,
Colloid journal, 2009, V. 71, No 5, pp.672-677.
4. Muminov S.Z., Gulyamova D.B., Pribylov
A.A. Adsorption of Acetonitrile Vapor on
Sodium and Polyhydroxyaluminum
Montmorillonites, Colloid Journal, 2006, V. 68,
No 5, pp.584-587.
5. Muminov S.Z., Khandamov D.A.,
Rakhimova G.B. Heats of n-Hexane and n-
Heptane Vapor Adsorption Montmorillonite,
Russian Journal of Physical Chem. A, 2011, V.
85., No 1, pp.112-116.
6. Muminov S.Z., Gulyamova D.B., Aripov
E.A. Adsorbtsiya parov benzola na
termoobrabotannom montmorillonite s
poligidroksialyuminievymi kationami
[Adsorption of Benzene Vapors on Thermal
Processing Montmorillonite With
Polyhydroxyaluminum Cations], Russian Journal of Physical Chem. A, 1993, V. 67, No
12, pp.2436-2438.
7. Muminov S.Z., Gulyamova D.B. Teplota
adsorbtsii parov metilovogo spirta na
mikroporistom montmorillonite [Heat
Adsorption of Methanol Vapor on Microporous
Montmorillonite], Russian Journal of Physical
Chem. A, 1997, V. 71, No 10, pp.1834-1836.
8. Pribylov A.A., Muminov S.Z., Kalinnikova
I.I., Shchekhovtsova L.G. Adsorbtsiya dioksida
ugleroda na montmorillonitakh razlichnykh
kationo-obmennykh form, Kolloidn. Zhurn,
2010, T.72, No 3. pp. 409-411.
9. Stacey M.H. Alumina-Pillared clays and
their adsorptive properties, Catalysis today.
1988. V. 2/3. pp. 621-631.
10. Pinnavaia T.S. Intercalated clay catalysts,
Science, 1983 V. 220, No 4595, pp. 365-369.
11. Fomkin A.A., Muminov S.Z., Pulin A.L.
et al. Adsorbtsionnaya deformatsiya
mikroporistykh adsorbentov/Sovremennye
problemy teorii adsorbtsii [Modern Problems
Theory of Adsorption], M., 1995, V. 2, pp.172-
179.
12. Fomkin A.A. Adsorbtsiya v
mikroporistykh adsorbentakh/Adsorbtsiya,
adsorbenty i sorbtsionnye protsessy v
nanoporistykh materialakh [Adsorption,
Adsorbents and Sorption Processes at
Microporous Materials], M., 2011, pp. 133-161.
13. Matsumoto M., Shinoda S., Takahashi H.,
Saito Y. Adsorption properties of pillar
intercalated montmorillonite, Bull Chem.
Soc.Jpn, 1987, V. 57, No 1, pp. 1795-1801.
14. Vargaftik N.B. Spravochnik po
teplofizicheskim svoistvam gazov i zhidkostei
[Handbook for Heat Physics Properties of
Liquids and Gases], M., Nauka, 1972, 720 p.
15. Muminov S.Z. Ustanovka dlya
neposredstvennogo izmereniya izoster
adsorbtsii [Plant for Direct Measure of Isosters
Adsorption] Uzbekskii khim.zhurn, 1965, No 6,
pp. 58-62.
16. Muminov S.Z., Aripov E.A., Issledovanie
v oblasti termodinamiki i termokhimii adsorbtsii
na glinistykh mineralakh [Studies in
Thermodynamics and Thermochemistry of
Adsorption on Clay Minerals], Tashkent, Fan.
1987, 144 p.
17. De Boer J.H. The structure and properties
of porous materials, London, Butterworth, 1958,
pp. 68.
18. Muminov S.Z., Aripov E.A., Rakhimov
A.A./Adsorbtsiya i poristost'. Pod red
[Adsorption and Porosity], M., Nauka, 1976, pp.
71-72.
19. Barrer R.M., Reay J.S.S. Sorption and
intercalation by montmorillonites, Trans.
Faraday Soc, 1957, V. 53, pp. 1253-1258.
20. Dubinin M.M. Fundamentals of the
Theory of physical adsorption of Gases and
Vapours in Micropores, In Adsorption-
Desorption Phenomena, London-New York,
Acad. Press, 1972, pp. 3-11.
21. Muminov S.Z., Gulyamova D.B., Seitova
E.A. Temperature Dependence of the
Adsorption of Carbon Tetrachloride on a
Microporous Clay adsorbent, Colloid Journal,
2001, V. 63, No. 6, pp.746-749.
22. Kiselev A.V., Kovaleva N.V., Korolev
A.Ya. et al. Khimicheskoe modifitsirovanie
poverkhnosti adsorbentov i ego vliyanie na
adsorbtsionnye svoistva [Chemical
Modification of Adsorbents Surface and its
Influence on Adsorption Properties], Dokl. AN
SSSR, 1959, V. 124, No 3, pp. 617-622.
Опубликован
2019-11-20
Как цитировать
Muminov, S. Z., Kurbonov, S. D., & Ergashev, O. K. (2019). Влияние термической дегидратации полигидроксиалюминиевого монтмориллонита на адсорбцию четыреххлористого углерода. Сорбционные и хроматографические процессы, 14(6). извлечено от https://journals.vsu.ru/sorpchrom/article/view/1582
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