Separation of «MgCl2-HCl» and «CaCl2-HCl» mixtures by means of low basic anion exchangers such as AN-221, AN-251 in non-exchange conditions

Authors

  • Tatiana N. Nefedova engineer, department of Analytical Chemistry, faculty of Chemistry, Voronezh State University, Voronezh, e-mail: TNephedova@gmail.com
  • Vladimir Yu. Khokhlov professor, department of Analytical Chemistry, faculty of Chemistry, Voronezh State University, Voronezh
  • Oksana N. Khokhlova assistant professor, department of Analytical Chemistry, faculty of Chemistry, Voronezh State University, Voronezh
  • Vladimir F. Selemenev professor, the head of Analytical Chemistry department, faculty of Chemistry, Voronezh State University, Voronezh, e-mail: common@chem.vsu.ru

Keywords:

separation, non-exchange sorption, magnesium chloride, calcium chloride, hydrochloric acid, low basic anion exchangers.

Abstract

Separation of chloride-containing mixtures of electrolytes such as «MgCl2 - HCl» (0,01 M: 0.01
M) and the «CaCl2 - HCl» (0.01 M: 0.01 M) by means of the low basic anion exchangers (AN-221,
AN-251) in non-exchange conditions was carried out. Concentration of hydrochloric acid for the «CaCl2 -
HCl - AN - 251 in HCl-form» system in sorbent phase was detected. It was found that the using of
systems with the low basic anion exchangers in non-exchange conditions allows completely to separate
the chloride-containing mixtures of electrolytes such as «MgCl2 - HCl» (0,01 M: 0.01 M) and the «CaCl2
- HCl» (0,01 M: 0.01 M) on a thin sorbent layer .

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Published

2019-11-21

How to Cite

Separation of «MgCl2-HCl» and «CaCl2-HCl» mixtures by means of low basic anion exchangers such as AN-221, AN-251 in non-exchange conditions. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 13(5). https://journals.vsu.ru/sorpchrom/article/view/1680

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