Perfluorinated membranes in pd-sensors for determination of components in dosage forms
Ключевые слова:
потенциометрические сенсоры, потенциал Доннана, перфторированные мембраны, витамины, лекарственные вещества.
Аннотация
Исследовано влияние ионной формы перфторированных сульфокатионообменных
мембран на чувствительность ПД-сенсоров (сенсоров, аналитическим сигналом которых является
потенциал Доннана на границе мембрана / исследуемый раствор) в растворах никотиновой
кислоты и гидрохлоридов пиридоксина, новокаина, лидокаина. Перекрестно чувствительные ПД-
сенсоры вместе со стеклянным электродом для измерения рН и хлоридсеребряным электродом
сравнения использованы для определения витаминов и лекарственных веществ в
фармацевтических формах. Для многомерной градуировки ПД-сенсоров в полиионных растворах
использовали неортогональные схемы эксперимента. Калибровочные уравнения учитывали
влияние на величину отклика ПД-сенсоров как концентрации органических электролитов, так и
рН растворов. Относительная ошибка определения компонентов в фармацевтических формах не
превышала 8%.
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Литература
1.Mimendia A., Gutierrez J.M., Leija L., Hernandez P.R., Favari L., Munoz R., M. del
Valle A review of the use of the potentiometric electronic tongue in the monitoring of
environmental systems //Environmental Modelling and Software 25 (2010) 1023-1030
2.Escuder-Gilabert L., Peris M. Review: highlights in recent applications of electronic
tongues in food analysis //Anal. Chim. Acta 665 (2010) 15-25.
3.Bratov A., Abramova N., Ipatov A. Recent trends in potentiometric sensor arrays – A
review //Anal. Chim. Acta 678 (2010) 149-159.
4.Legin A.V., Rudnitskaya A.M., Vlasov Yu.G., Di Natale C., D'Amico A. The
features of the electronic tongue in comparison with characteristics of the discrete ionselective
sensors // Sensors and Actuators B 58 (1999) 464-468.
5.Legin A.V., Bychkov E.A., Vlasov Yu.G. Analytical applications of chalcogenide
glass chemical sensors in environmental monitoring and process control // Sensors and
Actuators B 24 (1995) 309-311.
6.Legin A.V., Bychkov E.A., Vlasov Yu.G. Cross-sensitivity evaluation of chemical
sensors for electronic tongue: determination of heavy metal ions // Sensors and Actuators
B (1995) 309-311.
7.Rudnitskaya A., Ehlert A., Legin A., Vlasov Yu., Buttgenbach S. Multisensor system
on the basis of an array of non-specific chemical sensors and artificial neural networks for
determination of inorganic pollutants in model groundwater // Talanta 55 (2001) 425-431.
8.Legin A.V., Kirsanov D.O., Babain V.A., Borovoy A.V., Herbst R.S. Cross-sensitive
rare-earth metal sensors based on bidentate neutral organophosphorus compounds and
chlorinated cobalt dicarbollide // Anal. Chim.Acta 572 (2006) 243-247.
9.Bobreshova O.V., Agupova M.V., Parshina A.V., Polumestnaya K.A. Determination of
amino acids, vitamins, and drug substances in aqueous solutions using new potentiometric
sensors with Donnan potential as analytical signal // Russian J. of Electrochem. 46 (2010)
1252-1262.
10. Bobreshova O.V., Parshina A.V., Polumestnaya K.A., Тimofeev S.V. A new type of
potentiometric sensors based on perfluorinated, sulfonated cation-exchange membranes for
quantitative analysis of multicomponent aqueous solutions Petroleum Chemistry 51
(2011) 496-505.
11. Zabolotskii V.I., Nikonenko V.V. Ion Transport in Membranes (Nauka,
Moscow,1996) [in Russian].
12. Perel'man Ya.M. Analysis of Pharmaceuticals (Practice Guidelines) (Medgiz,
Leningrad, 1961) [in Russian].
13. Bobreshova O.V., Parshina A.V., Ryzhkova E.A. A potentiometric multisensor
system for determining lysine in aqueous solutions containing potassium and sodium
chloride // Russian J. of Anal. Chem. 65(2010) 866-872.
14. Bobreshova O.V., Parshina A.V., Polumestnaya K.A. Potentiometric Multisensory
Systems with Novel Ion-Exchange Polymer-Based Sensors for Analysis of Drugs //
International J. of Electrochem. 2012. Article ID 392735, 10 pages.
doi:10.1155/2012/392735
15. Vetter K.J. Electrochemische Kinetik (Springer-Verlag, Berlin, 1961).
16. Vershinin V.I., Pertsev N.V. Experimental Design and Mathematical Data
Processing in Chemistry: A Tutorial (Omsk. Gos. Univ., Omsk, 2005) [in Russian].
Valle A review of the use of the potentiometric electronic tongue in the monitoring of
environmental systems //Environmental Modelling and Software 25 (2010) 1023-1030
2.Escuder-Gilabert L., Peris M. Review: highlights in recent applications of electronic
tongues in food analysis //Anal. Chim. Acta 665 (2010) 15-25.
3.Bratov A., Abramova N., Ipatov A. Recent trends in potentiometric sensor arrays – A
review //Anal. Chim. Acta 678 (2010) 149-159.
4.Legin A.V., Rudnitskaya A.M., Vlasov Yu.G., Di Natale C., D'Amico A. The
features of the electronic tongue in comparison with characteristics of the discrete ionselective
sensors // Sensors and Actuators B 58 (1999) 464-468.
5.Legin A.V., Bychkov E.A., Vlasov Yu.G. Analytical applications of chalcogenide
glass chemical sensors in environmental monitoring and process control // Sensors and
Actuators B 24 (1995) 309-311.
6.Legin A.V., Bychkov E.A., Vlasov Yu.G. Cross-sensitivity evaluation of chemical
sensors for electronic tongue: determination of heavy metal ions // Sensors and Actuators
B (1995) 309-311.
7.Rudnitskaya A., Ehlert A., Legin A., Vlasov Yu., Buttgenbach S. Multisensor system
on the basis of an array of non-specific chemical sensors and artificial neural networks for
determination of inorganic pollutants in model groundwater // Talanta 55 (2001) 425-431.
8.Legin A.V., Kirsanov D.O., Babain V.A., Borovoy A.V., Herbst R.S. Cross-sensitive
rare-earth metal sensors based on bidentate neutral organophosphorus compounds and
chlorinated cobalt dicarbollide // Anal. Chim.Acta 572 (2006) 243-247.
9.Bobreshova O.V., Agupova M.V., Parshina A.V., Polumestnaya K.A. Determination of
amino acids, vitamins, and drug substances in aqueous solutions using new potentiometric
sensors with Donnan potential as analytical signal // Russian J. of Electrochem. 46 (2010)
1252-1262.
10. Bobreshova O.V., Parshina A.V., Polumestnaya K.A., Тimofeev S.V. A new type of
potentiometric sensors based on perfluorinated, sulfonated cation-exchange membranes for
quantitative analysis of multicomponent aqueous solutions Petroleum Chemistry 51
(2011) 496-505.
11. Zabolotskii V.I., Nikonenko V.V. Ion Transport in Membranes (Nauka,
Moscow,1996) [in Russian].
12. Perel'man Ya.M. Analysis of Pharmaceuticals (Practice Guidelines) (Medgiz,
Leningrad, 1961) [in Russian].
13. Bobreshova O.V., Parshina A.V., Ryzhkova E.A. A potentiometric multisensor
system for determining lysine in aqueous solutions containing potassium and sodium
chloride // Russian J. of Anal. Chem. 65(2010) 866-872.
14. Bobreshova O.V., Parshina A.V., Polumestnaya K.A. Potentiometric Multisensory
Systems with Novel Ion-Exchange Polymer-Based Sensors for Analysis of Drugs //
International J. of Electrochem. 2012. Article ID 392735, 10 pages.
doi:10.1155/2012/392735
15. Vetter K.J. Electrochemische Kinetik (Springer-Verlag, Berlin, 1961).
16. Vershinin V.I., Pertsev N.V. Experimental Design and Mathematical Data
Processing in Chemistry: A Tutorial (Omsk. Gos. Univ., Omsk, 2005) [in Russian].
Опубликован
2019-11-21
Как цитировать
Bobreshova, O. V., & Parshina, A. V. (2019). Perfluorinated membranes in pd-sensors for determination of components in dosage forms. Сорбционные и хроматографические процессы, 13(6). извлечено от https://journals.vsu.ru/sorpchrom/article/view/1702
Раздел
Статьи
