Structure and polarity of modified by uracile derivatives porous polymers

Authors

  • Vladimir Yu. Guskov post-graduated student, Bashkir State University, Ufa, E-mail: guscov@mail.ru
  • Sergey P. Ivanov Ph. D.; Institute of Organic Chemistryof Ufa Scientific Centre of Russian Academy of Science, Ufa, ivanov_sp@anrb.ru
  • Florida K. Kudasheva professor, Bashkir State University, Ufa, E-mail: KudashevaFKh@mail.ru

Keywords:

6-methyluracil, 5-hydroxy-6-methyluracil, net supramolecular structure, porous polymer sorbent, inverse gas chromatography, polarity.

Abstract

Influence of 6-methyluracil and 5-hydroxy-6-methyluracil deposition quantity to properties of
supramolecular structure was investigated. It is shown, that 6-methyluracil net structure formation
occurred only when 10% of modifier was inflicted, while 1% of 5-hydroxy-6-methyluracil was enough to
form supramolecular net. Surface polarity was investigated by linear decomposition of retention
parameters method. It is shown, that after modification by 6-methyluracil polarity was significantly
increaseв due to donor-acceptor interaction, while modification by 5-hydroxy-6-methyluracil wasn’t
influence on the surface polarity

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Published

2019-11-25

How to Cite

Structure and polarity of modified by uracile derivatives porous polymers. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 12(6). https://journals.vsu.ru/sorpchrom/article/view/1879

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