Analysis of 1-acyl-2,2,5-trimethyl-4,4-dichlorocyclopropan[c]quinolines by the method of mass spectrometry

Authors

  • Khidmet S. Shikhaliev professor, head of Department of Organic Chemistry, Voronezh State University, Voronezh
  • Vladimir F. Selemenev professor, head of Department of Analytical Chemistry, Voronezh State University, Voronezh
  • Svetlana M. Medvedeva assistant professor Chair of Organic Chemistry Voronezh State University; Voronezh
  • Lyudmila F. Ponomaryova assistant professor Chair of Organic Chemistry Voronezh State University; Voronezh
  • Nataliya I. Kopteva assistant professor Chair of Organic Chemistry Voronezh State University; Voronezh

Keywords:

quinolines, mass spectrometry, columnar chromatography, cyclopropyl-allyl regrouping.

Abstract

Individual 1-acyl-2,2,5-trimethyl-4,4-dichlorocyclopropan[c]quinolines are received by method of a
column chromatography. Effective the mixtures of eluents are picked up. The structure of the obtained
compounds is established and the main directions of fragmentation is determined by the method of mass
spectrometry. Three routes of disintegration of a molecule 1-acyl-2,2,5-trimethyl-4,4-
dichlorocyclopropan[c]quinoline under the action of electronic impact are found. Realization of one of them
is caused by course of a cyclopropyl-allyl rearrangement.

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Published

2019-11-19

Issue

Vol. 14 No. 2 (2014): Sorbtsionnye i Khromatograficheskie Protsessy

Section

Статьи

How to Cite

Analysis of 1-acyl-2,2,5-trimethyl-4,4-dichlorocyclopropan[c]quinolines by the method of mass spectrometry. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 14(2). https://journals.vsu.ru/sorpchrom/article/view/1482

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