Unsymmetrical diaryltelluroxides investigation by RP HPLC-MS method

Authors

  • Tatyana A. Rodina senior scientist, Russian academy of sciences A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, E-mail: rodina@front.ru
  • Vitaliy P. Gar`kin Vice Rector for Academic Affairs, State educational institution of higher education Samara State University, Samara, tel. (8462) 334-54-05
  • Nikolay A. Red`kin assistant department of analytical chemistry, State educational institution of higher education Samara State University, Samara
  • Aleksey K. Buryak head of laboratory, Russian academy of sciences A.N. Frumkin Institute of Physical Chemistry and Electrochemistry

Keywords:

diaryltelluroxides mixture analysis, reserved phase high performance liquid chromatography with mass spectrometry detection, electrospray and APCI ionization.

Abstract

The diaryltelluroxides with various substitutions in benzene rings, “unsymmetrical”, yielded by
heating of the corresponding symmetrical substances, was investigated by RP HPLC-MS method. It was
found, that chromatographic retention of the corresponding “unsymmetrical” substances had intermediate
value between retention of the symmetrical analogs. A research ability of similar unresolved mixtures by
characteristic ions was shown. Mass spectral data interpretation of the investigated compounds forming in
mass spectra of the overlapped chromatographic peaks was studied. The isomeric dimmers, allowing to
reliably identify presence of “unsymmetrical” compounds was found

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Published

2019-11-27

Issue

Vol. 10 No. 2 (2010): Sorbtsionnye i Khromatograficheskie Protsessy

Section

Статьи

How to Cite

Unsymmetrical diaryltelluroxides investigation by RP HPLC-MS method. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 10(2). https://journals.vsu.ru/sorpchrom/article/view/2035

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