THERMODYNAMIC PROPERTIES OF Pb6Sb6Se17
Keywords:
lead-antimony selenides, Pb6Sb6Se17, EMF method, thermodynamic properties
Abstract
The Pb-Sb-Se system was investigated in the PbSe-Pb6Sb6Se17-Sb2Se3-Se composition area and temperature range 300–450 K using EMF measurements on reversible concentration cells of the type
(–) PbSe(s) | liquid electrolyte, Pb2+ | (Pb–Sb–Se)(s)(+).
It was shown that this subsystem consists of two three-phase regions, limited by the Pb6Sb6Se17-Sе tie-line. Partial thermodynamic functions of PbSe and lead in tree-phase Pb6Sb6Se17–Sb2Se3–Se region are calculated from the equations for the EMF temperature dependences. The standard Gibbs energy of formation, standard enthalpy of formation and standard entropy of the Pb6Sb6Se17 compound were calculated based these data and using the thermodynamic functions for PbSe and Sb2Se3.
ACKNOWLEDGMENT
The work has been carried out within the framework of the international joint research laboratory “Advanced Materials for Spintronics and Quantum Computing” (AMSQC) established between Institute of Catalysis and Inorganic Chemistry of ANAS (Azerbaijan) and Donostia International Physics Center (Basque Country, Spain).
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References
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23. Emsley J. The Elements. Third ed., Clarendon Press, 1998, 292 p.
24. Кubaschewski O., Alcock C. B., Spenser P. J. Materials Thermochemistry. 6-th edition, Pergamon Press, England, 1993, 363 p.
25. Data base of thermal constants of substances. Digital version, in: V. S. Iorish, V. S. Yungman, (Eds.), 2006. Available at: http://www.chem.msu.ru/cgi-bin/tkv.pl
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28. Babanly M. B., Yusibov Yu. A., and Abishev V. T. EMF Measurements in Thermodynamic Studies of Complex Semiconductors. Baku, Bak. State. Univ. Publ., 1992, 317 p.
