THERMODYNAMIC PROPERTIES OF Pb6Sb6Se17
Keywords:
lead-antimony selenides, Pb6Sb6Se17, EMF method, thermodynamic properties
Abstract
The Pb-Sb-Se system was investigated in the PbSe-Pb6Sb6Se17-Sb2Se3-Se composition area and temperature range 300–450 K using EMF measurements on reversible concentration cells of the type
(–) PbSe(s) | liquid electrolyte, Pb2+ | (Pb–Sb–Se)(s)(+).
It was shown that this subsystem consists of two three-phase regions, limited by the Pb6Sb6Se17-Sе tie-line. Partial thermodynamic functions of PbSe and lead in tree-phase Pb6Sb6Se17–Sb2Se3–Se region are calculated from the equations for the EMF temperature dependences. The standard Gibbs energy of formation, standard enthalpy of formation and standard entropy of the Pb6Sb6Se17 compound were calculated based these data and using the thermodynamic functions for PbSe and Sb2Se3.
ACKNOWLEDGMENT
The work has been carried out within the framework of the international joint research laboratory “Advanced Materials for Spintronics and Quantum Computing” (AMSQC) established between Institute of Catalysis and Inorganic Chemistry of ANAS (Azerbaijan) and Donostia International Physics Center (Basque Country, Spain).
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References
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3. Poudeu P. F. P., Angelo J. D., Kong H., Downey A., Short J. L., Pcionek R., Hogan T. P., Uher C., Kanatzidis M. G. J. Am. Chem. Soc., 2006, vol. 128, pp. 14347 - 14355. DOI: 10.1021/ja0647811
4. Chen Y., Zhu T. J., Yang S. H., Yu C., Zhao X. B. J. Phys. D: Appl. Phys. 43 (2010), 035405. Available at: http://iopscience.iop.org/article/10.1088/0022-3727/43/3/035405/pdf
5. Zemskov V. S., Shelimova L. E., Konstantinov P. P., Avilov E. S., Kretova M. A., Nikhezina I. Yu. Inorg. Mater.: Appl. Res., 2012, vol. 3, pp. 61–69. DOI: 10.1134/S2075113314010158
6. Niesner D., Otto S., Hermann V., Fauster Th., et al. Phys. Rev. B, 2014, vol. 89, pp. 081404-081404-5. DOI: https://doi.org/10.1103/PhysRevB.89.081404
7. Papagno M., Eremeev S., Fujii J., Aliev Z. S., et al. ACS Nano, 2016, vol. 10, pp. 3518-3524. DOI: 10.1021/acsnano.5b07750
8. Okuda T., Maegawa T., Ye M., Shirai K., et al. Phys. Rev. Lett., 2013, vol. 111, pp. 205803-5. DOI: https://doi.org/10.1103/PhysRevLett.111.206803
9. Guseinov F. N., Babanly K. N., Aliev I. I. and Babanly M. B. Russ. J. Inorg. Chem., 2012, vol. 57, no. 1, pp. 101–103. DOI: 10.1134/S003602361201010X
10. Guseinov F. N., Seidzade A. E., Yusibov Yu. A., and Babanly M. B. Inorg. Mater., 2017, vol. 53, no. 4, pp. 354–357. DOI: 10.1134/S00201685170 40057
11. Babanly M. B., Guseinov F. N., Dashdiyeva G. B., Yusibov Y. A. Inorg.Mater., 2011, vol. 47, no. 3, pp. 284–288. DOI: 10.1134/S0020168511030022
12. Babanly M. B., Shevelkov A. V., Guseinov F. N., Babanly D. M. Inorg.Mater., 2011, vol. 47, no. 7, pp. 712-716. DOI: 10.1134/S002016851107003X
13. Morachevskii, A. G., Voronin, G. F., Geiderikh, V. A. and Kutsenok, I. B. Electrochemical Characterization Techniques in Thermodynamic Studies of Metallic Systems. Moscow, Akademkniga Publ., 2003. (in Russian)
14. Babanly M. B. and Yusibov Yu. A. Electrochemical Characterization Techniques in Thermodynamic Studies of Inorganic Systems. Baku, ELM Publ., 2011.
15. Shelimova L. E., Tomashik V. N., and Grytsiv V. I. Phase Diagrams in Semiconductor Materials Research: Systems Based on Chalcogenides of Si, Ge, Sn, and Pb. Moscow, Nauka Publ., 1991. (in Russian)
16. Olekseyuk I. D., Ostapyuk T. A., Viskynets L. M., Zmiy O. F. Scientific Journal Volyn National University, 2010, no. 16, pp. 38-42.
17. Chang J., Chen S. J. Alloys Compd., 2016, vol. 666, pp. 159-169. https://doi.org/10.1016/j.jallcom.2016.01.051
18. Skovrov A., Bosvel F. W., Corbet J. M., Taylor N. J. J. Solid State Chem., 1994, vol. 112, pp. 251–254. https://doi.org/10.1006/jssc.1994.1300
19. Skowron A., Brown I. D. Acta Cryst. Section C, 1990, vol. 46, no. 12, pp. 2287–2291. DOI: 10.1107/S010827019000405X
20. Derakhshan S., Assound A., Taylor N. J., Kleinke H. Intermetallics, 2006, vol. 14, no. 2, pp. 198-207. https://doi.org/10.1016/j.intermet.2005.05.008
21. Emirdag-Eanes M, Kolis J. W. Z. Anorg. Allg. Chem., 2002, vol. 628, no. 1, pp. 10-11. DOI: 10.1002/1521-3749(200201)628:1<10::AID-ZAAC10>3.0.CO;2-1
22. Binary Alloys Phase Diagrams. Ed. by T. B. Massalski, second edition. ASM International, Materials park, Ohio, 1990, 3589 p.
23. Emsley J. The Elements. Third ed., Clarendon Press, 1998, 292 p.
24. Кubaschewski O., Alcock C. B., Spenser P. J. Materials Thermochemistry. 6-th edition, Pergamon Press, England, 1993, 363 p.
25. Data base of thermal constants of substances. Digital version, in: V. S. Iorish, V. S. Yungman, (Eds.), 2006. Available at: http://www.chem.msu.ru/cgi-bin/tkv.pl
26. Gerasimov Ya. I., Krestovnikov A. N, and Gorbov S. I., Chemical Thermodynamics in Nonferrous Metallurgy: A Handbook. Moscow, Metallurgiya Publ., 1974, vol. 6, 312 p. (in Russian)
27. Melekh B. T., Semenkovich S. A., and Andreev A. A. Thermodynamic Properties of Intermetallic Phases. Kiev, Inst. Problem Materialovedeniya Publ., 1982, pp. 73–87. (in Russian)
28. Babanly M. B., Yusibov Yu. A., and Abishev V. T. EMF Measurements in Thermodynamic Studies of Complex Semiconductors. Baku, Bak. State. Univ. Publ., 1992, 317 p.
Published
2017-12-27
How to Cite
Mansimova, S. H., Orujlu, E. N., Sultanova, S. G., & Babanly, M. B. (2017). THERMODYNAMIC PROPERTIES OF Pb6Sb6Se17. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 19(4), 536-541. https://doi.org/10.17308/kcmf.2017.19/234
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