XPS Investigation of the Protective Layers of Nitrated Oil on the Armco-Iron Surface

  • Irina N. Shabanova Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation https://orcid.org/0000-0001-7896-0843
  • Sergey M. Reshetnikov Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation;Udmurt State University, 1, Universitetskaya str., bld. 1, off. 240, 426034 Izhevsk, Udmurt Republic, Russian Federation https://orcid.org/0000-0002-3072-2341
  • Ekaterina A. Naimushina Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation; T. M. Kalashnikov Izhevsk State Technical University, 7, Studencheskaya str., 426069 Izhevsk, Udmurt Republic, Russian Federation http://orcid.org/0000-0002-6023-4672
  • Nadezhda S. Terebova Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation https://orcid.org/0000-0001-7544-7884
  • Nikita Yu. Isupov Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation https://orcid.org/0000-0002-2515-8117
Keywords: XPS spectra, interatomic interaction, nitrated oil.

Abstract

Objectives. The XPS spectra of the adsorption layers of nitrated oil used as antirust inhibitor
on the surface of armco-iron were studied. The interatomic interaction between the components
of the nitrated oil and the armco-iron surface is revealed in the temperature range of room
temperature – 500 °C.
Purpose. The objective of the work is the interatomic interaction in the protective layers of
nitrated oils on the armco-iron surface.
Methods and methodology. The X-ray photoelectron spectroscopy studies were performed on
an X-ray electron magnetic spectrometer with resolution of 10–4 and luminosity – 0.085 % at
the excitation with AlKa line 1486.5 eV. In contrast to an electrostatic spectrometer, a magnetic
spectrometer has a number of advantages due to the constructive possibilities of X-ray electron
magnetic spectrometers which are the constancy of luminosity and resolution regardless of the
energy of electrons, the high contrast of spectra, and the possibility of external actions on a
sample (in the considered case, heating) during spectra taking.
Results. The comparison of the results of the investigation of the nitrated oil sample with those
obtained for the reference sample shows that:
1. In the protective surface layer between atoms of iron and nitrogen are formed the donoracceptor
bond Fe–N.
2. At heating to the temperatures above 200 °C the content of nitrogen, which is not strongly
bound to the substrate, decreases, i.e. nitrogen is partially evaporated; however the donoracceptor
bond Fe–N remains at heating to 500 °C.
Conclusions. The results should increase the effectiveness of the use of known inhibitors and
the technology for producing preservation compositions based on nitrated oils.

 

 

 

 

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Author Biographies

Irina N. Shabanova, Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation

Dr. Sci. (Phys.- Math.), Professor, Chief Researcher, Institution of Science «Udmurt
Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», Izhevsk, Udmurt Republic,
Russian Federation; e-mail: xps@udman.ru

Sergey M. Reshetnikov, Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation;Udmurt State University, 1, Universitetskaya str., bld. 1, off. 240, 426034 Izhevsk, Udmurt Republic, Russian Federation

Dr. Sci. (Chem.), Full Professor, Professor of the Department of Fundamental
and Applied Chemistry, Udmurt State University; Senior Researcher, Institution of Science «Udmurt Federal
Research Centre of the Ural Branch of the Russian Academy of Sciences», Izhevsk, Udmurt Republic,
Russian Federation; e-mail:smr41@mail.ru

Ekaterina A. Naimushina, Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation; T. M. Kalashnikov Izhevsk State Technical University, 7, Studencheskaya str., 426069 Izhevsk, Udmurt Republic, Russian Federation

Cand. Sci. (Phys.-Math.), Associate Professor, Associate Professor of the
Department of Physics and Optical Engineering, T. M. Kalashnikov Izhevsk State Technical University; Researcher, Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy
of Sciences», Izhevsk, Udmurt Republic, Russian Federation; e-mail: naimushina_ekaterina@mail.ru

Nadezhda S. Terebova, Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation

Cand. Sci. (Phys.- Math.), Senior Researcher, Institution of Science «Udmurt
Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», Izhevsk, Udmurt Republic,
Russian Federation; e-mail: terebova@udman.ru.

Nikita Yu. Isupov, Institution of Science «Udmurt Federal Research Centre of the Ural Branch of the Russian Academy of Sciences», 34 named after Tatyana Baramzina str., 426067 Izhevsk, Udmurt Republic, Russian Federation

graduate student, Leading Designer, Institution of Science «Udmurt Federal
Research Centre of the Ural Branch of the Russian Academy of Sciences», Izhevsk, Udmurt Republic,
Russian Federation; e-mail: inik@udman.ru


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Published
2019-12-19
How to Cite
Shabanova, I., Reshetnikov, S., Naimushina, E., Terebova, N., & Isupov, N. (2019). XPS Investigation of the Protective Layers of Nitrated Oil on the Armco-Iron Surface. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 21(4), 561-568. https://doi.org/https://doi.org/10.17308/kcmf.2019.21/2366
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