Физико-химическая модель поведения иттрия в профиле выветривания
Ключевые слова:
Иттрий, Y(ОH)63-, YCO3 , ∆fGo(298.15) Дж/моль, моделирование, ЭВМ, Селектор, профиль выветривания
Аннотация
Введение: Представлены авторские и литературные данные по стандартной свободной энергии Гиббса для 35 ионов и комплексов иттрия в водном растворе, а также для трёх возможных его минеральных фаз. Методика: По программе “Селектор” методом физико-химического моделирования на ЭВМ проведён анализ поведения иттрия в процессе выветривания филлитовидных сланцев. Результаты и обсуждение: Содержание Y в сланцах аналогично его среднему содержанию в земной коре и равно 10-3 вес. %. Установлено, что в профиле выветривания в окислительной зоне иттрий находится в растворе в виде гидроксокомплекса Y(ОH)63-. В восстановительной зоне преобладают карбонат-ионы – YCO3+ и Y(CO3)2-. Заключение: В отличие от большинства химических элементов иттрий не накапливается в бокситах, а выносится из них [1], поэтому его коэффициент концентрации равен 0.60.
Скачивания
Данные скачивания пока не доступны.
Литература
1. Bushinskii G. I. Geologiya boksitov [Geology of bauxite]. Moscow, Nedra publ., 1975. 416 p. (In Russ.)
2. Emsley J. Elementy [Elements]. Translation from English. Moscow, Mir publ., 1993. 256 p. (In Russ.)
3. Yaroshevskii A. A. Rasprostranennost' khimicheskikh elementov v zemnoi kore [Prevalence of chemical elements in the earth's crust]. Geokhimiya– Geochemistry, 2006, no. 1, pp. 54–62. (In Russ.)
4. Vinogradov A. P. Vvedenie v geokhimiyu okeana [An Introduction to Ocean Geochemistry]. Moscow, Nauka publ., 1967, 216 p. (In Russ.)
5. Latimer V. M. Okislitel'nye sostoyaniya elementov i ikh potentsialy v vodnykh rastvorakh [Oxidative states of elements and their potentials in aqueous solutions]. Moscow, Izd-vo inostr. Lit publ., 1954, 400 p. (In Russ.)
6. Lur'e Yu. Yu. Spravochnik po analiticheskoi khimii [Handbook of analytical chemistry]. Moscow, Khimiya publ., 1989. 448 p. (In Russ.)
7. Turova N. Ya. Neorganicheskaya khimiya v tablitsakh. Uchebnoe posobie [Inorganic chemistry in tables. Tutorial]. Moscow, «CheRo» publ., 2002, 140 p. (In Russ.)
8. Lidin R. A., Andreeva L. L., Molochko V. A. Konstanty neorganicheskikh veshchestv: spravochnik [Constants of inorganic substances: a reference book]. Moscow, Drofa publ., 2006. 685 p. (In Russ.)
9. Morozov I. V., Boltalin A. I., Karpova E. V. Okislitel'novosstanovitel'nye protsessy. Elektronnaya biblioteka khimicheskogo fakul'teta [Oxidation-reduction processes. Electronic library of the Faculty of Chemistry]. Moscow, Moscow State University publ., 2003. 64 p. (In Russ.)
10. Naumov G. B., Ryzhenko B. N., Khodakovskii I. L. Spravochnik termodinamicheskikh velichin (dlya geologov) [Handbook of thermodynamic quantities (for geologists)]. Moscow, Atomizdat publ., 1971. 240 p. (In Russ.)
11. Shock E. L., Helgeson H. C. Calculation of the thermodynamic and transport properties of aqueous species in high pressures and temperatures. Correlation algorithms for ionic species and equation of state predicthions to 5 kb and 1000 ̊C. Geochim. Cosmochim. Acta, 1988, vol. 52(2), pp. 2009–2036.
12. Termicheskie konstanty veshchestv: Spravochnik [Thermal constants of substances: Handbook.]. Ed. akad. V. P. Glushko (editor-in-chief) et.al. Vol. 1–10. Moscow, AN SSSR, VINITI publ., 1965, 26 p. (In Russ.)
13. Ryabchikov D. I, Ryabukhin V. A. Analiticheskaya khimiya redkozemel'nykh elementov i ittriya. Seriya: “Analiticheskaya khimiya elementov” [Analytical chemistry of rare earth elements and yttrium. Series: “Analytical chemistry of elements]. Moscow, Nauka publ., 1966, 382 p. (In Russ.)
14. Krainov S. R., Ryzhenko B. N., Shvets V. M. Geokhimiya podzemnykh vod. Teoreticheskie, prikladnye i ekologicheskie aspekty [Geochemistry of underground waters. Theoretical, applied and environmental aspects]. Moscow, TsentrLitNefteGaz publ., 2012. 672 p. (In Russ.)
15. Ivanov-Emin B. N., Egorov L. M., Romanyuk V. I., Siforova E. N Konstanty obrazovaniya anionnykh gidroksokompleksov nekotorykh elementov III gruppy periodicheskoi sistemy [Formation constants of anionic hydroxocomplexes of some elements of the III group of the periodic table.]. Zhurn. neor. Khimii – Journal of inorganic chemistry, 1970, vol. 15, no. 5, pp. 1224–1228. (In Russ.)
16. Karpov I. K. Fiziko-khimicheskoe modelirovanie na EVM v geokhimii [Physicochemical modeling on a computer in geochemistry]. Novosibirsk, Nauka publ., 248 p. (In Russ.)
17. Chudnenko K. V. Termodinamicheskoe modelirovanie v geokhimii: teoriya, algoritmy, programmnoe obespechenie, prilozheniya [Thermodynamic modeling in geochemistry: theory, algorithms, software, applications]. Novosibirsk, GEO publ., 2010, 287 p. (In Russ.)
18. Karzhavin V. K. Termodinamicheskie velichiny nekotorykh fosfatov kal'tsiya gruppy apatita [Thermodynamic values of some calcium phosphates of the apatite group. Zhurnal fizicheskoi khimii – Journal of physical chemistry. 1981, vol.LV, no. 8, pp. 1933–1936. (In Russ.)
19. Whitney D., Evans B.W. Abbreviations for names of rockforming minerals. Amer. Mineral, 2010, vol. 95, pp. 185–187.
20. Kopeikin V. A. Povedenie fosfora v protsesse vyvetrivaniya [Phosphorus behavior during weathering]. DAN SSSR – Reports of the USSR Academy of Sciences, 1983, vol.268, no. 2, pp. 432–435. (In Russ.)
21. Podporina E. K. Redkozemel'nye elementy v korakh vyvetrivaniya [Rare earth elements in weathering crusts]. Moscow, Nauka publ., 1985, 126 p. (In Russ.)
22. Bronevoi V. A., Zil'bermints A. V., Lipin V. M., Tenyakov V. A. Srednie koeffitsienty kontsentratsii khimicheskikh elementov v boksitakh [Average coefficients of concentration of chemical elements in bauxite]. DAN SSSR – Reports of the USSR Academy of Sciences, 1983, vol.270, no. 5, pp. 1167–1170. (In Russ.)
23. Likhachev V. V. Redkometal'nost' boksitonosnoi kory vyvetrivaniya Srednego Timana [The rare metal of the bauxitebearing weathering crust of Middle Timan]. Syktyvkar, Komi NTs UrO RAN publ., 1993, 224 p. (In Russ.)
24. Balashov Yu. A. Geokhimiya redkozemel'nykh elementov [Geochemistry of rare earth elements.]. Moscow, Nauka publ., 1976, 268 p. (In Russ.)
25. Yudovich Ya. E., Ketris M. P. Tsennye elementy-primesi v uglyakh [Valuable elements-impurities in coal]. Yekaterinburg, Ural Branch of the Russian Academy of Sciences publ., 2006. 538 p. (In Russ.)
2. Emsley J. Elementy [Elements]. Translation from English. Moscow, Mir publ., 1993. 256 p. (In Russ.)
3. Yaroshevskii A. A. Rasprostranennost' khimicheskikh elementov v zemnoi kore [Prevalence of chemical elements in the earth's crust]. Geokhimiya– Geochemistry, 2006, no. 1, pp. 54–62. (In Russ.)
4. Vinogradov A. P. Vvedenie v geokhimiyu okeana [An Introduction to Ocean Geochemistry]. Moscow, Nauka publ., 1967, 216 p. (In Russ.)
5. Latimer V. M. Okislitel'nye sostoyaniya elementov i ikh potentsialy v vodnykh rastvorakh [Oxidative states of elements and their potentials in aqueous solutions]. Moscow, Izd-vo inostr. Lit publ., 1954, 400 p. (In Russ.)
6. Lur'e Yu. Yu. Spravochnik po analiticheskoi khimii [Handbook of analytical chemistry]. Moscow, Khimiya publ., 1989. 448 p. (In Russ.)
7. Turova N. Ya. Neorganicheskaya khimiya v tablitsakh. Uchebnoe posobie [Inorganic chemistry in tables. Tutorial]. Moscow, «CheRo» publ., 2002, 140 p. (In Russ.)
8. Lidin R. A., Andreeva L. L., Molochko V. A. Konstanty neorganicheskikh veshchestv: spravochnik [Constants of inorganic substances: a reference book]. Moscow, Drofa publ., 2006. 685 p. (In Russ.)
9. Morozov I. V., Boltalin A. I., Karpova E. V. Okislitel'novosstanovitel'nye protsessy. Elektronnaya biblioteka khimicheskogo fakul'teta [Oxidation-reduction processes. Electronic library of the Faculty of Chemistry]. Moscow, Moscow State University publ., 2003. 64 p. (In Russ.)
10. Naumov G. B., Ryzhenko B. N., Khodakovskii I. L. Spravochnik termodinamicheskikh velichin (dlya geologov) [Handbook of thermodynamic quantities (for geologists)]. Moscow, Atomizdat publ., 1971. 240 p. (In Russ.)
11. Shock E. L., Helgeson H. C. Calculation of the thermodynamic and transport properties of aqueous species in high pressures and temperatures. Correlation algorithms for ionic species and equation of state predicthions to 5 kb and 1000 ̊C. Geochim. Cosmochim. Acta, 1988, vol. 52(2), pp. 2009–2036.
12. Termicheskie konstanty veshchestv: Spravochnik [Thermal constants of substances: Handbook.]. Ed. akad. V. P. Glushko (editor-in-chief) et.al. Vol. 1–10. Moscow, AN SSSR, VINITI publ., 1965, 26 p. (In Russ.)
13. Ryabchikov D. I, Ryabukhin V. A. Analiticheskaya khimiya redkozemel'nykh elementov i ittriya. Seriya: “Analiticheskaya khimiya elementov” [Analytical chemistry of rare earth elements and yttrium. Series: “Analytical chemistry of elements]. Moscow, Nauka publ., 1966, 382 p. (In Russ.)
14. Krainov S. R., Ryzhenko B. N., Shvets V. M. Geokhimiya podzemnykh vod. Teoreticheskie, prikladnye i ekologicheskie aspekty [Geochemistry of underground waters. Theoretical, applied and environmental aspects]. Moscow, TsentrLitNefteGaz publ., 2012. 672 p. (In Russ.)
15. Ivanov-Emin B. N., Egorov L. M., Romanyuk V. I., Siforova E. N Konstanty obrazovaniya anionnykh gidroksokompleksov nekotorykh elementov III gruppy periodicheskoi sistemy [Formation constants of anionic hydroxocomplexes of some elements of the III group of the periodic table.]. Zhurn. neor. Khimii – Journal of inorganic chemistry, 1970, vol. 15, no. 5, pp. 1224–1228. (In Russ.)
16. Karpov I. K. Fiziko-khimicheskoe modelirovanie na EVM v geokhimii [Physicochemical modeling on a computer in geochemistry]. Novosibirsk, Nauka publ., 248 p. (In Russ.)
17. Chudnenko K. V. Termodinamicheskoe modelirovanie v geokhimii: teoriya, algoritmy, programmnoe obespechenie, prilozheniya [Thermodynamic modeling in geochemistry: theory, algorithms, software, applications]. Novosibirsk, GEO publ., 2010, 287 p. (In Russ.)
18. Karzhavin V. K. Termodinamicheskie velichiny nekotorykh fosfatov kal'tsiya gruppy apatita [Thermodynamic values of some calcium phosphates of the apatite group. Zhurnal fizicheskoi khimii – Journal of physical chemistry. 1981, vol.LV, no. 8, pp. 1933–1936. (In Russ.)
19. Whitney D., Evans B.W. Abbreviations for names of rockforming minerals. Amer. Mineral, 2010, vol. 95, pp. 185–187.
20. Kopeikin V. A. Povedenie fosfora v protsesse vyvetrivaniya [Phosphorus behavior during weathering]. DAN SSSR – Reports of the USSR Academy of Sciences, 1983, vol.268, no. 2, pp. 432–435. (In Russ.)
21. Podporina E. K. Redkozemel'nye elementy v korakh vyvetrivaniya [Rare earth elements in weathering crusts]. Moscow, Nauka publ., 1985, 126 p. (In Russ.)
22. Bronevoi V. A., Zil'bermints A. V., Lipin V. M., Tenyakov V. A. Srednie koeffitsienty kontsentratsii khimicheskikh elementov v boksitakh [Average coefficients of concentration of chemical elements in bauxite]. DAN SSSR – Reports of the USSR Academy of Sciences, 1983, vol.270, no. 5, pp. 1167–1170. (In Russ.)
23. Likhachev V. V. Redkometal'nost' boksitonosnoi kory vyvetrivaniya Srednego Timana [The rare metal of the bauxitebearing weathering crust of Middle Timan]. Syktyvkar, Komi NTs UrO RAN publ., 1993, 224 p. (In Russ.)
24. Balashov Yu. A. Geokhimiya redkozemel'nykh elementov [Geochemistry of rare earth elements.]. Moscow, Nauka publ., 1976, 268 p. (In Russ.)
25. Yudovich Ya. E., Ketris M. P. Tsennye elementy-primesi v uglyakh [Valuable elements-impurities in coal]. Yekaterinburg, Ural Branch of the Russian Academy of Sciences publ., 2006. 538 p. (In Russ.)
Опубликован
2021-12-17
Как цитировать
Копейкин, В. А. (2021). Физико-химическая модель поведения иттрия в профиле выветривания. Вестник ВГУ. Серия: Геология, (4), 82-87. https://doi.org/10.17308/geology.2021.4/3793
Выпуск
Раздел
Краткие сообщения
