Effect of the morphology and composition of trimetallic PtCuAu/C catalysts on the activity and stability of the methanol oxidation reaction

  • Vldislav S. Menshikov Southern Federal University, 105/42 Bolshaya Sadovaya str., Rostov-on-Don 344006, Russian Federation https://orcid.org/0000-0002-0531-2156
  • Sergey V. Belenov Southern Federal University, 105/42 Bolshaya Sadovaya str., Rostov-on-Don 344006, Russian Federation https://orcid.org/0000-0003-2980-7089
  • Aleksey Y. Nikulin Southern Federal University, 105/42 Bolshaya Sadovaya str., Rostov-on-Don 344006, Russian Federation
Keywords: methanol fuel cells, catalysis, trimetallic catalysts, galvanic replacement

Abstract

       A study on the influence of the method for obtaining trimetallic PtCuAu/C catalysts on their activity in the oxidation of methanol has been carried out.
     The structural characteristics of the obtained trimetallic catalysts have been studied by X-ray diffraction and transmission electron microscopy. The nanoparticles of the material obtained by the galvanic synthesis method had a size twice as large (~ 6 nm) than the nanoparticles of the material obtained by the co-deposition of metal precursors. According to the results from the accelerated stress testing of catalysts, it was found that the material obtained by the galvanic method of substitution of copper atoms with gold had a higher residual activity in the oxidation of methanol than the commercial Pt/C analogue.
        This study shows the potential of obtaining and using multicomponent platinum-containing nanoparticles deposited on a carbon carrier as effective catalysts for use in methanol fuel cells.

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Author Biographies

Vldislav S. Menshikov, Southern Federal University, 105/42 Bolshaya Sadovaya str., Rostov-on-Don 344006, Russian Federation

PhD student, Researcher at
the Department of Electrochemistry, Southern Federal
University (Rostov-on-Don, Russian Federation).

Sergey V. Belenov, Southern Federal University, 105/42 Bolshaya Sadovaya str., Rostov-on-Don 344006, Russian Federation

PhD in Chemistry, Research
Fellow at the Department of Electrochemistry,
Southern Federal University (Rostov-on-Don, Russian
Federation).

Aleksey Y. Nikulin, Southern Federal University, 105/42 Bolshaya Sadovaya str., Rostov-on-Don 344006, Russian Federation

Researcher at the Department
of Electrochemistry, Southern Federal University
(Rostov-on-Don, Russian Federation;).

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Published
2022-03-15
How to Cite
Menshikov, V. S., Belenov, S. V., & Nikulin, A. Y. (2022). Effect of the morphology and composition of trimetallic PtCuAu/C catalysts on the activity and stability of the methanol oxidation reaction. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 24(1), 76-87. https://doi.org/10.17308/kcmf.2022.24/9057
Section
Original articles