Prospects of membrane catalysis in hydrogen energetics. Mini review

Keywords: Energy, Hydrogen, Ecology, Economy, Sustainable development, Membranes, Palladium, Catalysis, Water vapor

Abstract

Hydrogen energetics is undoubtedly highly relevant today as it not only allows solving the issue of energy production from a renewable water source but can also prevent the formation of greenhouse gases. They say that any new idea is a well forgotten old one. The paper is dedicated to an excellent but still unimplemented work of Sainte-Claire Deville who managed to obtain hydrogen from water vapor using membrane technology. He used a clay pipe as a membrane which selectively permeated hydrogen. This process occurred with heating up to 950 °C. Sainte-Claire Deville managed to obtain only a mixture of hydrogen and oxygen in a ratio of 4:1 and then to clean the product from oxygen using chemical reactions.

Modern membrane catalysts based on palladium or its alloys are selectively permeable only for hydrogen. This means that the membrane catalysis method with palladium membranes could allow to realize of hermal water disassociation more effectively and solve the issues of hydrogen energetics using only renewable raw materials.

The history of hydrogen discovery and methods of its production was also studied in this review. Different methods of energy production were analyzed, including mineral resources, wind turbines, solar panels, hydroenergetics, electrolysis, and nuclear power, and a forecast was presented based on them. The review should be considered as an invitation to further discussions regarding this highly relevant and important topic

Downloads

Download data is not yet available.

Author Biography

Vladimir A. Shaposhnik, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Dr. Sci. (Chem.), Full
Professor, Department of Analytical Chemistry,
Voronezh State University (Voronezh, Russian
Federation)

References

Cavendish H. Three papers, containing experiments on factitious air. Proceedings of the Royal Society of London, Philosophical Transactions of the Royal Society. 1766; 56: 141-184. / Three papers, containing experiments on factitious air. The Scientific Papers of the Honourable Henry Cavendish. 77–101. https://doi.org/10.1017/cbo9780511722424.005

Nicholson W., Carlisle A. V. Letter from Henry Moyes M. D. to Maxwell Garthshore M. D. containing an account of some interesting experiments in galvanic electricity. The Philosophical Magazine. 1800; 7(28), 347–350. https://doi.org/10.1080/14786440008562594

Saint-Claire Deville H. Sur la phenomenes de dissociation. Arch. Sci. Phys. Natur. 1859;6: 266–275.

Sainte-Claire Deville H. Recherches sur la decomposition. Arch. Sci. Phys. Natur. 1860;9: 51–68.

Sainte-Claire Deville H. De la dissociation ou decomposition spontanee des corps sous l’influence de la chaleur. Compt. Rend. 1867;45: 857–861.

Sainte-Claire Deville H. Lecons sur la dissociation professeesdevant la Societe Chimique de Paris en 1864 et 1865. Paris; 1866. p. 255–278.

Graham T. LVIII. On the law of the diffusion of gases. In: The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 1833;2(11): 351–358. https://doi.org/10.1080/14786443308648056

Girard J. Principles of environmental chemistry. Boston: Iones & Batrtlett Publishers; 2005. 677 p.

Yergin D. The Quest. Energy, security, and the remarking of the modern world. N.Y., London, Toronto, Sydney: Penguin Books; 2002. 832 p.

Liebig J. Die organische Chemie in ihrer Anwendung auf Agricultur und Phisiologie. Braunschweig, F. Vieweg;1840. https://doi.org/10.5962/bhl.title.42117

Strube W. Der historische Weg der Chemie Band 2. Leipzig, VEB Deutscher Verlag fuer Grundstoffindustry; 1976.

Kesore K., Ringer N., Gebert S., Rice D. Iron catalyst stands the test of time. Nitrogen+Syngas. 2009;300.

Delft van Y. V., Correia L. A., Overbeek J. P., … Jansen D. Hydrogen membrane reactor for industrial hydrogen. Available at: https://www.researchgate.net/publication/265665851_Hydrogen_membrane_reactor_for_industrial_hydrogen_production_and_power_generation

Chorkendorf I., Niemantsverdriet J. W. Concept of modern catalysis and kinetics. Weinheim, Wiley-VCH Verlag GmbH & Co. KGaA; 2007. 457 p.

Schmidt O., Gamphir A., Staffell I., Hawkes A., Nelson J., Few S. Future cost and performance of water electrolysis: An aspect elicitation study. International Journal of Hydrogen Energy. 2017; 42(52), 30470–30492. https://doi.org/10.1016/j.ijhydene.2017.10.045

Shiva Kumar S., Himabindu V. Hydrogen production by PEM water electrolysis - A. review. Material Science for Energy Technologies. 2019;2(3): 442–454. https://doi.org/10.1016/j.mset.2019.03.002

Shaposhnik V. A., Mazo A. A., Frölich P. Ecological aspects of the extreme purification of water. Russian Chemical Reviews. 1991;60(11): 1284–1292. https://doi.org/10.1070/rc1991v060n11abeh001146

Stiles D. A., Wells P. H. The production of ultrapure hydrogen. Platinum Metals Rev. 1972; 16(4); 124-128. Available at: https://technology.matthey.com/documents/496120/626258/pmr-v16-i4-124-128.pdf/493ff7f4-d447-2b5b-52e2-800a3fa501bb?version=1.0&t=1656009920233

Eisenberg D., Kauzmann W. The structure and properties of water. Oxford New York, University Press; 1969. 300 p. / Eisenberg D., Kauzmann W. The structure and properties of water. 2005. https://doi.org/10.1093/acprof:oso/9780198570264.001.0001

Maggio G., Nicita A., Squadrito G. How the hydrogen production from RES could change energy and fuel markets: A Review of recent literature. International Journal of Hydrogen Energy. 2019;44:11371–11384. https://doi.org/10.1016/j.ijhydene.2019.03.121

Shaposhnik V. A. Ab initio calculation of catalytical atomization reaction of water molecules on the surface of palladium membrane. Proceedings of the International Conference “Ion transport in organic and inorganic membranes”. Sochi; 2015. p. 265-266.

Lehn J.-M. Supramolecular chemistry. Conceps and perspectives. VCH: Weinheim, N.Y., Basel, Tokyo; 1995. 271 p.

Szent-Györgyi A. Oxidation, energy transfer and vitamin. Available at: https://www.nobelprize.org/prizes/medicine/1937/szent-gyorgyi/lecture/

Published
2024-01-31
How to Cite
Shaposhnik, V. A. (2024). Prospects of membrane catalysis in hydrogen energetics. Mini review. Condensed Matter and Interphases, 26(1), 37-44. https://doi.org/10.17308/kcmf.2024.26/11807
Section
Review