The role of polymeric surfactants in enhanced oil recovery: a review

  • Gulnara A. Ahmadova Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan https://orcid.org/0009-0003-7199-6087
  • Ravan A. Rahimov Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan; Department of Chemical Engineering, Baku Engineering University, 120 Hasan Aliyev st., Baku, Absheron AZ0101, Azerbaijan; Department of Chemical Engineering, School of Engineering and Applied Science, Khazar University, 41 Mahsati st., Baku AZ 1096, Azerbaijan https://orcid.org/0000-0001-5619-4041
  • Aygul Z. Abilova Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan https://orcid.org/0009-0001-3453-5770
  • Shafiga M. Nasibova Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan https://orcid.org/0009-0009-1446-7270
  • Khuraman A. Mammadova Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan https://orcid.org/0009-0000-0612-5160
Keywords: Enhanced oil recovery, Polymer surfactant, Ionic liquid, Surface tension, Wettability

Abstract

Objective of the article: The continuously increasing demand for oil and petroleum products necessitates the further development of enhanced oil recovery (EOR) methods, including physicochemical techniques such as polymer flooding. Currently, billions of tons of oil remain dispersed and scattered within water-flooded reservoirs. This article provides a review of the literature on the synthesis and application of surfactant solutions and their mixtures with various components (polymers, salts, acids, etc.) in EOR processes.

Experimental section: The use of surfactants contributes to reducing interfacial tension and increasing wettability. Polymeric surfactants represent a promising alternative to modern systems employed in chemical EOR. They can combine the necessary rheological and interfacial properties in a single component, whereas typically, this requires mixtures of several chemical substances. Improved flooding properties using polymeric surfactants are essential for recovering residual oil. In addition to their unique characteristics, it is important to ensure synergy between the surfactant or polymer and other components that meet strict technical requirements. Furthermore, EOR based on polymeric surfactant systems is technologically compatible with conventional water flooding and does not require significant capital investment.

Conclusions: It should be noted that numerous studies have been devoted to the processes of EOR. The presented article emphasizes the efficiency and feasibility of using surfactants based on the results of tests studying the physicochem.

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Author Biographies

Gulnara A. Ahmadova, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan

Dr. Sci. (Chem.), Associate Professor, Head of the Laboratory “Surface-active reagents and preparations”, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan (Baku, Azerbaijan)

Ravan A. Rahimov, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan; Department of Chemical Engineering, Baku Engineering University, 120 Hasan Aliyev st., Baku, Absheron AZ0101, Azerbaijan; Department of Chemical Engineering, School of Engineering and Applied Science, Khazar University, 41 Mahsati st., Baku AZ 1096, Azerbaijan

Dr. Sci. (Chem.), Associate Professor, Chief Researcher of the Laboratory “Surface-active reagents and preparations”, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan (Baku, Azerbaijan)

Aygul Z. Abilova, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan

Cand. Sci. (Chem.), Leading Researcher of the Laboratory “Surface-active reagents and preparations”,
Institute of Petrochemical Processes of he Ministry of Science and Education of Azerbaijan (Baku, Azerbaijan)

Shafiga M. Nasibova, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan

Cand. Sci. (Chem.), Associate Professor, Leading Researcher of the laboratory “Surfaceactive reagents and preparations”, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan (Baku, Azerbaijan)

Khuraman A. Mammadova, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan, 30 Hojaly ave., AZ 1025, Baku, Azerbaijan

Cand. Sci. (Chem.), Associate Professor, Chief Researcher of the Laboratory “Surface-active reagents and preparations”, Institute of Petrochemical Processes of the Ministry of Science and Education of Azerbaijan (Baku, Azerbaijan)

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Published
2025-12-25
How to Cite
Ahmadova, G. A., Rahimov, R. A., Abilova, A. Z., Nasibova, S. M., & Mammadova, K. A. (2025). The role of polymeric surfactants in enhanced oil recovery: a review. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 27(4), 533-546. https://doi.org/10.17308/kcmf.2025.27/13252
Section
Review