Influence of the method of formation a nanosized CoFe2O4/nontronite composite on its structure and properties

Keywords: Nanocomposite, Citrate combustion method, Cobalt ferrite, Aluminosilicate

Abstract

       The aim of the study was to establish the influence of the method of formation of the CoFe2O4/nontronite nanocomposite on its structure and properties.
       Impurity-free nanoparticles of cobalt ferrite CoFe2O4 (XRD), close to spherical in shape, with a predominant particle fraction in the range of 8-20 nm (TEM), were synthesized using the citrate combustion method. The formation of the CoFe2O4/nontronite nanocomposite was carried out by two methods: mechanical mixing of available precursors followed by annealing and combustion of iron-cobalt citrate with the formation of spinel in the presence of nontronite in the reactor.
        The CoFe2O4/nontronite nanocomposite formed by the first method is characterized by the decomposition of natural aluminosilicate aggregates and a higher sorption activity with respect to formaldehyde than the original clay mineral and spinel. The second method of composite formation leads to the formation of coarse-grained silica structures with worse sorption activity in comparison with natural aluminosilicate and CoFe2O4.

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Author Biographies

Elena V. Tomina, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation; Voronezh State University of Forestry and Technologies named after G. F. Morozov 8 Timiryazeva str., Voronezh 394087, Russian Federation

Dr. Sci. (Chem.), Head of the
Department of Chemistry, Voronezh State University
of Forestry and Technologies named after G. F.
Morozov (Voronezh, Russian Federation).

Nataliya A. Khodosova, Voronezh State University of Forestry and Technologies named after G. F. Morozov 8 Timiryazeva str., Voronezh 394087, Russian Federation

Cand. Sci. (Chem.),
Associate Professor at the Department of Chemistry,
Voronezh State University of Forestry and Technologies
named after G. F. Morozov (Voronezh, Russian
Federation).

Alexander A. Sinelnikov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Phys.–Math.),
Head of Laboratory, Department of Materials Science
and Industry of Nanosystems, Voronezh State
University (Voronezh, Russian Federation).

Aleksandr V. Zhabin, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Geologo-
Mineralogical), Associate Professor at the Department
of General Geology and Geodynamics, Voronezh State
University (Voronezh, Russian Federation).

Nikolay A. Kurkin, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

PhD student, Department of
Materials Science and Industry of Nanosystems,
Voronezh State University (Voronezh, Russian
Federation).

Lyudmila A. Novikova, Voronezh State University of Forestry and Technologies named after G. F. Morozov 8 Timiryazeva str., Voronezh 394087, Russian Federation

Cand. Sci. (Chem.), Associate
Professor at the Department of Chemistry, Voronezh
State University of Forestry and Technologies named
after G. F. Morozov (Voronezh, Russian Federation).

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Published
2022-08-26
How to Cite
Tomina, E. V., Khodosova, N. A., Sinelnikov, A. A., Zhabin, A. V., Kurkin, N. A., & Novikova, L. A. (2022). Influence of the method of formation a nanosized CoFe2O4/nontronite composite on its structure and properties. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 24(3), 379-386. https://doi.org/10.17308/kcmf.2022.24/9861
Section
Original articles

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