Formation during glycine-nitrate combustion and magnetic properties of YFe1–xNixO3 nanoparticles

Keywords: Nanocrystals, Yttrium orthoferrite, Nickel, Doping, Glycine-nitrate combustion

Abstract

     The synthesis of FeO3 and YFe1–xNixO3 (x = 0.1; 0.15; 0.2; 0.3; 0.5) nanocrystals was performed under the conditions of a self-propagating wave of glycine-nitrate combustion and their characterization and determination of the effect of Ni2+ doping of yttrium ferrite on the magnetic properties of nanopowders.
     The technology for the synthesis of yttrium orthoferrite nanoparticles (with and without doping with Ni2+ ions) by the glycine-nitrate combustion method at a ratio of G/N = 1 and 1.5 without adding a gelling agent to the reaction mixture and using ethylene glycol/glycerol is described. For the characterization of nanopowders based on YFeO3, the following were determined: phase composition and crystal structure (X-ray diffraction (XRD) method); size and structure of nanocrystal particles (transmission electron microscopy (TEM)); elemental composition of the samples (local X-ray spectral microanalysis (LXSMA)); magnetic characteristics (field dependences of specific magnetization).
      Thermal annealing of the synthesized samples at 800°C for 60 min led to the formation of the о-YFeO3 main phase. Undoped samples of yttrium orthoferrite were characterized by a particle diameter in the range of 5-185 nm, depending on the gelling agent used. YFe1-xNixO3 particles had a predominantly round shape with a size of 24 to 31 nm; the non-monotonic dependence of the average particle diameter on the dopant content was revealed: as the amount of dopant added increased, the average crystallite size tended to decrease. Nanopowders of undoped yttrium orthoferrite exhibit antiferromagnetic behaviour of magnetic susceptibility with temperature. The change in the magnetic properties of the nickel-doped YFeO3 nanocrystalline powders was due to the incorporation of Ni2+ into the Fe3+position, which led to the formation of a material with more pronounced soft magnetic properties at a substitution degree of 0.1. Samples with high degrees of substitution (x = 0.15 and 0.3) were also characterized by paramagnetic behaviour at temperatures above 100 K.

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Author Biographies

Evgenia I. Lisunova, Voronezh State University, 1 Universitetskaya pl., Voronezh, 394018, Russian Federation

PhD student of the Department
of Materials Science and the Industry of Nanosystems,
Voronezh State University (Voronezh, Russian
Federation).

Nikolai S. Perov, Lomonosov Moscow State University 1, building 2 Leninskie Gory, Moscow 119991, Russian Federation

Dr. Sci. (Phys.–Math.), Professor,
Head of the Department of Magnetism, Faculty of
Physics, Lomonosov Moscow State University (Moscow,
Russian Federation).

Valentina O. Mittova, Teaching University Geomedi 4 st. King Solomon II str. 0114, Tbilisi, Georgia

PhD, Professor of the
Scientific-Research Institute of Experimental and
Clinical Medicine, Laboratory of Molecular Medicine,
Teaching University Geomedi (Tbilisi, Georgia).

Boris V. Sladkopevtsev, Voronezh State University, 1 Universitetskaya pl., Voronezh, 394018, Russian Federation

Cand. Sci. (Chem.), Associate
Professor of the Department of Materials Science and
Nanosystem Technologies, Voronezh State University
(Voronezh, Russian Federation).

Vuong Bui Xuan, Faculty of Natural Sciences Education, Saigon University, 273 An Duong Vuong St., Ward 3, District 5, Ho Chi Minh City, Vietnam

PhD in Chemistry, Lecturer of the
Faculty of Natural Sciences Education, Saigon
University (Ho Chi Minh City, Vietnam).

Tien Nguyen Anh, Faculty of Chemistry, Ho Chi Minh City University of Education, Ho Chi Minh City 700000, Vietnam

PhD in Chemistry, Chief of
Inorganic Chemistry Department, Ho Chi Minh City
University of Education (Ho Chi Minh City, Vietnam).

Yulia A. Alekhina, Lomonosov Moscow State University 1, building 2 Leninskie Gory, Moscow 119991, Russian Federation

Researcher of the Department
of Magnetism, Faculty of Physics, Lomonosov Moscow
State University n (Moscow, Russian Federation).

Viktor F. Kostryukov, Voronezh State University, 1 Universitetskaya pl., Voronezh, 394018, Russian Federation

Dr. Sci. (Chem.), Associate
Professor, Associate Professor of the Department of
Materials Science and the Industry of Nanosystems,
Voronezh State University (Voronezh, Russian
Federation).

Irina Ya. Mittova, Voronezh State University, 1 Universitetskaya pl., Voronezh, 394018, Russian Federation

Dr. Sci. (Chem.), Professor of the
Department of Materials Science and the Industry of
Nanosystems, Voronezh State University (Voronezh,
Russian Federation).

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Published
2023-03-09
How to Cite
Lisunova, E. I., Perov, N. S., Mittova, V. O., Sladkopevtsev, B. V., Xuan, V. B., Anh, T. N., Alekhina, Y. A., Kostryukov, V. F., & Mittova, I. Y. (2023). Formation during glycine-nitrate combustion and magnetic properties of YFe1–xNixO3 nanoparticles. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 25(1), 61-71. https://doi.org/10.17308/kcmf.2023.25/10975
Section
Original articles