Synthesis and study of graphene oxide obtained from waste transparent polythene bags using Modified Hummers method

Ключевые слова: Polythene bags, Carbon material, Graphene oxide, Modified Hummers method, Environment protection

Аннотация

Purpose: Plastic industry has seen explosive growth in previous decades over the world. Every sphere of day to day life revolves around plastic products. The used plastic gets accumulated on the Earth s surface and serves as a contaminant causing soil, land and water pollution. Waste plastic needs proper management and elimination from the biotic layer of the ecosystem. Most potent solution is conversion of plastic waste into a functional carbon material. Present workconcentrates on upcycling of waste plastic into economically crucial material that is graphene oxide. The waste polythene bags were successfully converted to graphitic carbon which in turn serves as the base for the synthesis of graphene oxide using modified Hummers method.

Experimental: The analysis was made by studying the FTIR spectra, SEM images and XRD graphs. The FTIR confirms the presence of hydroxyl and carbonyl groups along with carbon carbon interaction. Surface  orphology shows the porous and layered structure with an average particle size of 2.74 μm. X ray  iffractogram illustrates the crystal structure of the graphene oxide and interlayer spacing.

Conclusions: With the characterisation results, the synthesis of graphene oxide from plastic waste was erified

Скачивания

Данные скачивания пока не доступны.

Биографии авторов

Shireen Shukla, Department of Chemistry, Christ Church College, Mall Road, Bada Chauraha, Kanpur 208001, India

Research scholar, Department of Chemistry, Christ Church College (Kanpur, Uttar Pradesh, India)

Meet Kamal, Department of Chemistry, Christ Church College, Mall Road, Bada Chauraha, Kanpur 208001, India

Professor (Chemistry), Department of Chemistry, Christ Church College (Kanpur, Uttar Pradesh, India)

Литература

Bhattacharya R. R., Chandrasekhar K., Roy P., Khan A. Challenges and opportunities: plastic waste management in India. Available at: http://hdl.handle.net/2451/42242

Sandipan D. S. The concept of control and manage plastic pollution of India/world. The International Journal of Engineering and Science. 2016;5(6): 1–7. Available at: https://theijes.com/papers/v5-i6/version-2/A0506020107.pdf

Sruthy S., Ramasamy E. V. Microplastic pollution in Vembanad Lake, Kerala, India: the first report of microplastics in lake and estuarine sediments in India. Environmental pollution. 2017;222: 315–322. https://doi.org/10.1016/j.envpol.2016.12.038

Sunitha T. G., Monisha V., Sivanesan S., … Darchen A. Micro-plastic pollution along the Bay of Bengal coastal stretch of Tamil Nadu, South India. Science of the Total Environment. 2021;756: 144073. https://doi.org/10.1016/j.scitotenv.2020.144073

Verma R., Vinoda K. S., Papireddy M., Gowda A. N. Toxic pollutants from plastic waste-a review. Procedia Environmental Sciences. 2016;35: 701–708. https://doi.org/10.1016/j.proenv.2016.07.069

Schmaltz E., Melvin E. C., Diana Z., … Dunphy-Daly M. M. Plastic pollution solutions: emerging technologies to prevent and collect marine plastic pollution. Environment International. 20201;144: 106067. https://doi.org/10.1016/j.envint.2020.106067

Syamsiro M., Saptoadi H., Norsujianto T., … Yoshikawa K. Fuel oil production from municipal plastic wastes in sequential pyrolysis and catalytic reforming reactors. Energy Procedia. 2014;47: 180–188. https://doi.org/10.1016/j.egypro.2014.01.212

Faussone G. C. Transportation fuel from plastic: Two cases of study. Waste Management. 2018;73: 416–423. https://doi.org/10.1016/j.wasman.2017.11.027

Kumari M., Chaudhary G. R., Chaudhary S., Umar A. Transformation of solid plastic waste to activated carbon fibres for wastewater treatment. Chemosphere. 2022;294: 133692. https://doi.org/10.1016/j.chemosphere.2022.133692

da Silva E. P., Fragal V. H., Fragal E. H., … Muniz E. C. Sustainable energy and waste management: how to transform plastic waste into carbon nanostructures for electrochemical supercapacitors. Waste Management. 2023; 171: 71–85. https://doi.org/10.1016/j.wasman.2023.08.028

Shukla S., Kamal M. Plastic waste to functional carbon nanomaterials/graphene: a review. Essential Chem. 2024; 1(1): 1–2. https://doi.org/10.1080/28378083.2024.2407322

Berktas I., Hezarkhani M., Haghighi Poudeh L., Saner Okan B. Recent developments in the synthesis of raphene and graphene-like structures from waste sources by recycling and upcycling technologies: a review. Graphene Technology. 2020;5: 59–73. https://doi.org/10.1007/s41127-020-00033-1

Cooper D. R., D’Anjou B., Ghattamaneni N., … Yu V. Experimental review of graphene. ISRN Condensed Matter Physics. 2012: 1–56. https://doi.org/10.5402/2012/501686

Pei S., Cheng H. M. The reduction of graphene oxide. Carbon. 2012;50(9): 3210–3228. ttps://doi.org/10.1016/j.carbon.2011.11.010

Tiwari S. K., Mishra R. K., Ha S. K., Huczko A. Evolution of graphene oxide and graphene: from imagination to industrialization. ChemNanoMat. 2018;4(7): 598–620. https://doi.org/10.1002/cnma.201800089

Jiříčková A., Jankovský O., Sofer Z., Sedmidubský D. Synthesis and applications of graphene oxide. Materials. 2022;15(3): 920. https://doi.org/10.3390/ma15030920

Shahriary L., Athawale A. A. Graphene oxide synthesized by using modified hummers approach. International Journal of Renewable Energy and Environmental Engineering. 2014;2(01): 58-63.

Alam S. N., Sharma N., Kumar L. Synthesis of graphene oxide (GO) by modified hummers method and its thermal reduction to obtain reduced graphene oxide (rGO). Graphene. 2017;6(01): 1–18. https://doi.org/10.4236/graphene.2017.61001

Santamaría-Juárez G., Gómez-Barojas E., Quiroga-González E., Sánchez-Mora E., Quintana-Ruiz M., Santamaría-Juárez J. D. Safer modified Hummers’ method for the synthesis of graphene oxide with high quality and high yield. Materials Research Express. 2020;6(12): 125631. https://doi.org/10.1088/2053-1591/ab4cbf

Yoo M. J., Park H. B. Effect of hydrogen peroxide on properties of graphene oxide in Hummers method. arbon. 2019; 141: 515–22. https://doi.org/10.1016/j.carbon.2018.10.009

Sujiono E. H., Zabrian D., Dahlan M. Y., Amin B. D., Agus J. Graphene oxide based coconut shell waste: synthesis by modified Hummers method and characterization. Heliyon. 2020;6(8): e04568. https://doi.org/10.1016/j.heliyon.2020.e04568

Méndez-Lozano N., Pérez-Reynoso F., González-Gutiérrez C. Eco-friendly approach for graphene oxide synthesis by Modified Hummers method. Materials. 2022;15(20): 7228. https://doi.org/10.3390/ma15207228

Cao N., Zhang Y. Study of reduced graphene oxide preparation by Hummers’ method and related characterization. Journal of Nanomaterials. 2015;2015(1): 168125. https://doi.org/10.1155/2015/168125

Guerrero-Contreras J., Caballero-Briones F. Graphene oxide powders with different oxidation degree, prepared by synthesis variations of the Hummers method. Materials Chemistry and Physics. 2015;153: 209–220. https://doi.org/10.1016/j.matchemphys.2015.01.005

Alkhouzaam A., Qiblawey H., Khraisheh M., Atieh M., Al-Ghouti M. Synthesis of graphene oxides particle of igh oxidation degree using a modified Hummers method. Ceramics International. 2020;46(15): 23997–4007. https://doi.org/10.1016/j.ceramint.2020.06.177

Gul W., Akbar Shah R. S., Khan A., …Khan R. Synthesis of graphene oxide (GO) and reduced graphene oxide (rGO) and their application as nano-fillers to improve the physical and mechanical properties of medium density fibreboard. Frontiers in Materials. 2023;10. https://doi.org/10.3389/fmats.2023.1206918

Chen X., Qu Z., Liu Z., Ren G. Mechanism of oxidization of graphite to graphene oxide by the Hummers Method. ACS Omega. 2022;7(27): 23503–23510. https://doi.org/10.1021/acsomega.2c01963

Shamaila S., SajjadA. K. L., Iqbal A. Modifications in development of graphene oxide synthetic routes. Chemical Engineering Journal. 2016; 294: 458–477. https://doi.org/10.1016/j.cej.2016.02.109

Szabo T., Maroni P., Szilagyi I. Size-dependent aggregation of graphene oxide. Carbon. 2020;160: 145–55. https://doi.org/10.1016/j.carbon.2020.01.022

Hou Y., Lv S., Liu L., Liu X. High-quality preparation of graphene oxide via the Hummers' method: inderstanding the roles of the intercalator, oxidant, and graphite particle size. Ceramics International. 2020;46(2): 2392–2402. https://doi.org/10.1016/j.ceramint.2019.09.231

Marcano D. C., Kosynkin D. V., Berlin J. M., … Tour J. M. Improved synthesis of graphene oxide. ACS nano. 2010;4(8): 4806–4814. https://doi.org/10.1021/nn1006368

Surekha G., Krishnaiah K. V., Ravi N., Suvarna R. P. FTIR, Raman and XRD analysis of graphene oxide films prepared by modified Hummers method. Journal of Physics: Conference Series. 2020;1495(1): 012012). https://doi.org/10.1088/1742-6596/1495/1/012012

Zaaba N. I., Foo K. L., Hashim U., Tan S. J., Liu W. W., Voon C. H. Synthesis of graphene oxide using modified hummers method: solvent influence. Procedia Engineering. 2017; 184: 469–477. https://doi.org/10.1016/j.proeng.2017.04.118

Опубликован
2025-09-25
Как цитировать
Shukla, S., & Kamal, M. (2025). Synthesis and study of graphene oxide obtained from waste transparent polythene bags using Modified Hummers method. Конденсированные среды и межфазные границы, 27(3), 354-362. https://doi.org/10.17308/kcmf.2025.27/13011
Раздел
Оригинальные статьи