Синтез и физико-химические свойства 1-карбокси-2-/пергидро(1,3,5-дитиазин)/-5-илэтана при сорбции тяжелых, благородных и редкоземельных элементов
Аннотация
В работе предложена лабораторная методика синтеза сорбента 1-карбокси-2-/пергидро(1,3,5-дитиазин)/-5-илэтана (КПДЭ). С использованием различных методов зарегистрирован ИК-спектр полученного соединения. Выявлены спектральные признаки для идентификации структуры 1-карбокси-2-/пергидро(1,3,5-дитиазин)/-5-илэтана в продуктах синтеза. Состав целевого соединения подтвержден также методом ЯМР-спектроскопии на ядрах 13С и 15N. Получена порошковая рентгенограмма 1-карбокси-2-/пергидро(1,3,5-дитиазин)/-5-илэтана. На основе проведенных сорбционных экспериментов показана возможность эффективного применения синтезированного сорбента в процессах селективного извлечения тяжелых, благородных и редкоземельных металлов из модельных и реальных многокомпонентных растворов. Проведена оценка возможности применения синтезированного сорбционного материала при адсорбции благородных металлов из реальных отработанных растворов аффинажного производства. Доказано, что присутствует выраженная селективность синтезированного материала, так как концентрации тяжелых металлов (например, никеля и свинца) в процессе сорбции при различных температурах изменяются незначительно, в то время как например золото, палладий и платина сорбируются практически со 100% эффективностью.
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