Synthesis and physicochemical properties of 1-carboxy-2-/perhydro(1,3,5-dithiazine)/-5-ylethane during the sorption of heavy, no-ble, and rare earth elements
Abstract
This study proposes a laboratory procedure for the synthesis of the 1-carboxy-2-/perhydro(1,3,5-dithiazine)/-5-ylethane (CPDE) sorbent. The IR spectrum of the resulting compound was recorded using various methods. Spectral features were revealed for the identification of the structure of 1-carboxy-2-/perhydro(1,3,5-dithiazine)/-5-ylethane in the synthesis products. The composition of the target compound was also confirmed by 13C and 15N NMP-spectroscopy. An X-ray powder diffraction pattern of 1-carboxy-2-/perhydro(1,3,5-dithiazine)/-5-ylethane was obtained. Based on the sorption experiments, the possibility of effective use of the synthesized sorbent in the processes of selective extraction of heavy, noble, and rare earth metals from model and real multicomponent solutions was shown. The possibility of using the synthesized sorption material for the adsorption of noble metals from real waste solutions of refining production was assessed. The significant selectivity of the synthesized material was proven, since the concentrations of heavy metals (for example, nickel and lead) during sorption at different temperatures changed slightly, while, for example, gold, palladium and platinum were sorbed with almost 100% efficiency.
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