Парофазный газохроматографический анализ водных растворов с селективным поглощением газа-экстрагента
Ключевые слова:
газовая хроматография, алифатические и ароматические углеводороды, парофазный анализ, концентрирование, газовая экстракция, диоксид углерода, поглощение газа- экстрагента.
Аннотация
Предложен новый вариант парофазного газохроматографического анализа, основанный на
концентрировании экстрагируемых аналитов в газовой фазе за счёт селективного поглощения газа-
экстрагента. В качестве последнего использован диоксид углерода, который практически мгновенно
поглощается твердым гидроксидом натрия. Аналитические возможности предложенного метода
проиллюстрированы на примере определения алифатических и ароматических углеводородов.
Установлено, что при отсутствии химического взаимодействия аналитов с поглотителем газа-
экстрагента, разработанный метод позволяет, как минимум на порядок увеличить концентрацию
аналитов в газовой фазе и во столько же раз снизить пределы их обнаружения.
Скачивания
Данные скачивания пока не доступны.
Литература
1. Vitenberg A.G., Konopel'ko L.A.,
Dobrjakov Ju.G. et al. Problemy kontrolja
soderzhanija primesej letuchih
galogenproizvodnyh uglevodorodov v vodoprovodnoj
i stochnyh vodah, ZhAH., 2011, V.
66, No 8, pp. 859-869.
2. Kirichenko V.E., Pervova M.G.,
Pashkevich K.I. Galogenorganicheskie
soedinenija v pit'evoj vode i metody ih
opredelenija, Ros. him. zh., 2002, V. 16, No 4,
pp. 18-27.
3. Demeestere K., Dewulf J. Sample
preparation for the analysis of volatile organic
compounds in air and water matrices, J.
Chromatogr. A, 2007, V. 1153, pp. 130-144.
4. Chen Y., Guo Z. Sample preparation, J.
Chromatogr. A, 2008, V. 1184, pp. 191-219.
5. Chary N., Fernandez-Alba A.
Determination of volatile organic compounds in
drinking and environmental waters, Trends in
Analytical Chemistry, 2012, V. 32, pp. 60-75.
6. Antoniou C., Koukouraki E. Determination
of chlorinated volatile organic compounds in
water and municipal wastewater using
headspace-solid phase microextraction-gas
chromatography, J. Chromatogr. A, 2006, V.
1132, pp. 310-314.
7. Cai M., Huang P. A purge and trap gas
chromatographic method for detection of
chlorofluorocarbons in seawater, Chinese
Journal of Analytical Chemistry, 2013, V. 41,
pp. 268-272.
8. Farré M., Pérez S. Green analytical
chemistry in the determination of organic
pollutants in the aquatic environment, TrAC
Trends in Analytical Chemistry, 2010, V. 29,
pp. 1347-1362.
9. Vitenberg A.G. Staticheskij parofaznyj
gazohromatograficheskij analiz: Fizikohimicheskie
osnovy i oblasti primenenija, Ros.
him. zh., 2003, V. 47, No 1, pp. 7-22.
10. Khahenberg Kh., Shmidt A.
Gazohromatograficheskij analiz parovoj fazy,
M. Mir, 1977, 160 p.
11. Snow N.H., Slack G.C. Head-space
analysis in modern gas chromatography, Trend.
Anal. Chem., 2002, V. 21, pp. 608-617.
12. Lambropoulou D.A., Konstantinou I.K.,
Albanis T.A. Recent developments in headspace
microextraction techniques for the analysis of
environmental contaminants in different
matrices, J. Chromatogr. A, 2007, V. 1152,
pp. 70-96.
Родинков и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
125
13. Gonzalo A.L., Urıa J.E.S., Garcıa E.S. et
al. Critical comparison of automated purge and
trap and solid-phase microextraction for routine
determination of volatile organic compounds in
drinking waters by GC-MS, Talanta, 2008, V.
74, pp. 1455-1462.
14. Snow N.H., Bullock G.P. Novel
techniques for enhancing sensitivity in static
headspace extraction-gas chromatography, J.
Chromatogr. A, 2010, V. 1217, pp. 2726-2735.
15. Martínez C., Ramírez N. Simultaneous
determination of 76 micropollutants in water
samples by headspace solid phase
microextraction and gas chromatography-mass
spectrometry, Talanta, 2013, V. 116,
pp. 937-945.
16. Ueta I., Razaka N.A., Mizuguchia A. et al.
Needle-type extraction device for the purge and
trap analysis of 23 volatile organic compounds
in tap water, J. Chromatogr. A, 2013, V. 1317,
pp. 211-216.
17. Brown M.A., Miller S., Emmert G.L. Online
purge and trap gas chromatography for
monitoring of trihalomethanes in drinking water
distribution systems, Anal. Chem. Acta, 2007,
V. 592, pp. 154-161.
18. Saridara C., Brukh R., Mitra S.
Development of continuous on-line purge and
trap analysis, J. Sep. Sci., 2006, V. 29,
pp. 446-454.
19. Auer N.R., Manzke B.U., Schulz-Bull
D.E. Development of a purge and trap
continuous flow system for the stable carbon
isotope analysis of volatile halogenated organic
compounds in water, J. Chromatogr. A, 2006,
V. 1131, pp. 24-36.
20. Hyötyläinen T. Principles, developments
and applications of on-line coupling of
extraction with chromatography, J. Chromatogr.
A, 2007, V. 1153, pp. 14-28.
21. Hyötyläinen T. On-line coupling of
extraction with gas chromatography, J.
Chromatogr. A, 2008, V. 1186, pp. 39-50.
22. Ramos L. Critical overview of selected
contemporary sample preparation techniques, J.
Chromatogr. A, 2012, V. 1221, pp. 84-98.
23. Berezkin V.G. Himicheskie metody v gazovoj
hromatografii, M. Khimija, 1980, 256 p.
24. Berezkin V.G. Tatarinskij V.S. Gazokhromatograficheskie
metody analiza primesej,
M. Nauka, 1970, 213 p.
25. Ikem A. Measurement of volatile organic
compounds in bottled and tap waters by purge
and trap GC-MS: Are drinking water types
different?, Journal of Food Composition and
Analysis, 2010, V. 23, pp. 70-77.
26. Li H., Zhan H., Fu S., Liu M. et al. Rapid
determination of methanol in black liquors by
full evaporation headspace gas chromatography,
J. Chromatogr. A, 2007, V. 1175, pp. 133-136.
27. Jewell L.L., Davis B.H. Review of
absorption and adsorption in the hydrogenpalladium
system, Applied Catalysis A:
General, 2006, V. 310, pp. 1-15.
28. Moskvin L.N. Chromatomembrane
method for the continuous separation of
substances, J. Chromatogr. A, 1994, V. 669,
pp. 81-87.
29. Moskvin L.N., Rodinkov O.V.
Continuous chromatomembrane headspace
analysis, J. Chromatogr. A, 1996, V. 725,
pp. 351-359.
30. Moskvin L.N., Rodinkov O.V.
Chromatomembrane methods: physicochemical
principles, analytical and technological
possibilities, Russ. Chem. Bull., 2012, V. 61,
pp. 723-740.
31. Leeuwende S.P.J., Boer J. Advances in the
gas chromatographic determination of persistent
organic pollutants in the aquatic environment, J.
Chromatogr. A, 2008, V. 1186, pp. 161-182.
32. Kozlowska K., Polkowska Z. Investigation
of stability of aqueous solutions
containing trace amounts of volatile organic
analytes, Trends in Analytical Chemistry, 2006,
V. 25, No 6, pp. 608-620.
33. Płotka J., Tobiszewski M.. Green
chromatography, J. Chromatogr. A, 2013,
V. 1307, pp. 1-20.
34. Tobiszewski M., Mechlińska A. Green
analytical chemistry in sample preparation for
determination of trace organic pollutants, TrAC
Trends in Analytical Chemistry, 2009, V. 28,
No 8, pp. 943.
Dobrjakov Ju.G. et al. Problemy kontrolja
soderzhanija primesej letuchih
galogenproizvodnyh uglevodorodov v vodoprovodnoj
i stochnyh vodah, ZhAH., 2011, V.
66, No 8, pp. 859-869.
2. Kirichenko V.E., Pervova M.G.,
Pashkevich K.I. Galogenorganicheskie
soedinenija v pit'evoj vode i metody ih
opredelenija, Ros. him. zh., 2002, V. 16, No 4,
pp. 18-27.
3. Demeestere K., Dewulf J. Sample
preparation for the analysis of volatile organic
compounds in air and water matrices, J.
Chromatogr. A, 2007, V. 1153, pp. 130-144.
4. Chen Y., Guo Z. Sample preparation, J.
Chromatogr. A, 2008, V. 1184, pp. 191-219.
5. Chary N., Fernandez-Alba A.
Determination of volatile organic compounds in
drinking and environmental waters, Trends in
Analytical Chemistry, 2012, V. 32, pp. 60-75.
6. Antoniou C., Koukouraki E. Determination
of chlorinated volatile organic compounds in
water and municipal wastewater using
headspace-solid phase microextraction-gas
chromatography, J. Chromatogr. A, 2006, V.
1132, pp. 310-314.
7. Cai M., Huang P. A purge and trap gas
chromatographic method for detection of
chlorofluorocarbons in seawater, Chinese
Journal of Analytical Chemistry, 2013, V. 41,
pp. 268-272.
8. Farré M., Pérez S. Green analytical
chemistry in the determination of organic
pollutants in the aquatic environment, TrAC
Trends in Analytical Chemistry, 2010, V. 29,
pp. 1347-1362.
9. Vitenberg A.G. Staticheskij parofaznyj
gazohromatograficheskij analiz: Fizikohimicheskie
osnovy i oblasti primenenija, Ros.
him. zh., 2003, V. 47, No 1, pp. 7-22.
10. Khahenberg Kh., Shmidt A.
Gazohromatograficheskij analiz parovoj fazy,
M. Mir, 1977, 160 p.
11. Snow N.H., Slack G.C. Head-space
analysis in modern gas chromatography, Trend.
Anal. Chem., 2002, V. 21, pp. 608-617.
12. Lambropoulou D.A., Konstantinou I.K.,
Albanis T.A. Recent developments in headspace
microextraction techniques for the analysis of
environmental contaminants in different
matrices, J. Chromatogr. A, 2007, V. 1152,
pp. 70-96.
Родинков и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
125
13. Gonzalo A.L., Urıa J.E.S., Garcıa E.S. et
al. Critical comparison of automated purge and
trap and solid-phase microextraction for routine
determination of volatile organic compounds in
drinking waters by GC-MS, Talanta, 2008, V.
74, pp. 1455-1462.
14. Snow N.H., Bullock G.P. Novel
techniques for enhancing sensitivity in static
headspace extraction-gas chromatography, J.
Chromatogr. A, 2010, V. 1217, pp. 2726-2735.
15. Martínez C., Ramírez N. Simultaneous
determination of 76 micropollutants in water
samples by headspace solid phase
microextraction and gas chromatography-mass
spectrometry, Talanta, 2013, V. 116,
pp. 937-945.
16. Ueta I., Razaka N.A., Mizuguchia A. et al.
Needle-type extraction device for the purge and
trap analysis of 23 volatile organic compounds
in tap water, J. Chromatogr. A, 2013, V. 1317,
pp. 211-216.
17. Brown M.A., Miller S., Emmert G.L. Online
purge and trap gas chromatography for
monitoring of trihalomethanes in drinking water
distribution systems, Anal. Chem. Acta, 2007,
V. 592, pp. 154-161.
18. Saridara C., Brukh R., Mitra S.
Development of continuous on-line purge and
trap analysis, J. Sep. Sci., 2006, V. 29,
pp. 446-454.
19. Auer N.R., Manzke B.U., Schulz-Bull
D.E. Development of a purge and trap
continuous flow system for the stable carbon
isotope analysis of volatile halogenated organic
compounds in water, J. Chromatogr. A, 2006,
V. 1131, pp. 24-36.
20. Hyötyläinen T. Principles, developments
and applications of on-line coupling of
extraction with chromatography, J. Chromatogr.
A, 2007, V. 1153, pp. 14-28.
21. Hyötyläinen T. On-line coupling of
extraction with gas chromatography, J.
Chromatogr. A, 2008, V. 1186, pp. 39-50.
22. Ramos L. Critical overview of selected
contemporary sample preparation techniques, J.
Chromatogr. A, 2012, V. 1221, pp. 84-98.
23. Berezkin V.G. Himicheskie metody v gazovoj
hromatografii, M. Khimija, 1980, 256 p.
24. Berezkin V.G. Tatarinskij V.S. Gazokhromatograficheskie
metody analiza primesej,
M. Nauka, 1970, 213 p.
25. Ikem A. Measurement of volatile organic
compounds in bottled and tap waters by purge
and trap GC-MS: Are drinking water types
different?, Journal of Food Composition and
Analysis, 2010, V. 23, pp. 70-77.
26. Li H., Zhan H., Fu S., Liu M. et al. Rapid
determination of methanol in black liquors by
full evaporation headspace gas chromatography,
J. Chromatogr. A, 2007, V. 1175, pp. 133-136.
27. Jewell L.L., Davis B.H. Review of
absorption and adsorption in the hydrogenpalladium
system, Applied Catalysis A:
General, 2006, V. 310, pp. 1-15.
28. Moskvin L.N. Chromatomembrane
method for the continuous separation of
substances, J. Chromatogr. A, 1994, V. 669,
pp. 81-87.
29. Moskvin L.N., Rodinkov O.V.
Continuous chromatomembrane headspace
analysis, J. Chromatogr. A, 1996, V. 725,
pp. 351-359.
30. Moskvin L.N., Rodinkov O.V.
Chromatomembrane methods: physicochemical
principles, analytical and technological
possibilities, Russ. Chem. Bull., 2012, V. 61,
pp. 723-740.
31. Leeuwende S.P.J., Boer J. Advances in the
gas chromatographic determination of persistent
organic pollutants in the aquatic environment, J.
Chromatogr. A, 2008, V. 1186, pp. 161-182.
32. Kozlowska K., Polkowska Z. Investigation
of stability of aqueous solutions
containing trace amounts of volatile organic
analytes, Trends in Analytical Chemistry, 2006,
V. 25, No 6, pp. 608-620.
33. Płotka J., Tobiszewski M.. Green
chromatography, J. Chromatogr. A, 2013,
V. 1307, pp. 1-20.
34. Tobiszewski M., Mechlińska A. Green
analytical chemistry in sample preparation for
determination of trace organic pollutants, TrAC
Trends in Analytical Chemistry, 2009, V. 28,
No 8, pp. 943.
Опубликован
2018-02-19
Как цитировать
Писарев, А. Ю., Родинков, О. В., & Москвин, Л. Н. (2018). Парофазный газохроматографический анализ водных растворов с селективным поглощением газа-экстрагента. Сорбционные и хроматографические процессы, 15(1), 116-126. https://doi.org/10.17308/sorpchrom.2015.15/262
Раздел
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