Headspace analysis of aqueous solutions coupled with a selective absorption of the gas-extractant
Keywords:
gas chromatography, aromatic and aliphatic hydrocarbons, headspace analysis, concentrating, gas extraction, carbon dioxide, gas-extractant sorption
Abstract
A new headspace gas chromatographic technique was developed, involving analyte concentrating
through selective sorbtion of gas-extractant. Carbon dioxide was used as a gas-extractant due to opportunity
to be sorbed selectively by solid sodium hydroxide. In instance of aromatic and aliphatic hydrocarbons is
shown possibility to increase analyte concentration in gas phase and, thus, sensitivity by a factor of at least
ten in case of no reaction between analytes and sorbent.
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References
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Determination of volatile organic compounds in
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Needle-type extraction device for the purge and
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full evaporation headspace gas chromatography,
J. Chromatogr. A, 2007, V. 1175, pp. 133-136.
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absorption and adsorption in the hydrogenpalladium
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pp. 351-359.
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Chromatomembrane methods: physicochemical
principles, analytical and technological
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pp. 723-740.
31. Leeuwende S.P.J., Boer J. Advances in the
gas chromatographic determination of persistent
organic pollutants in the aquatic environment, J.
Chromatogr. A, 2008, V. 1186, pp. 161-182.
32. Kozlowska K., Polkowska Z. Investigation
of stability of aqueous solutions
containing trace amounts of volatile organic
analytes, Trends in Analytical Chemistry, 2006,
V. 25, No 6, pp. 608-620.
33. Płotka J., Tobiszewski M.. Green
chromatography, J. Chromatogr. A, 2013,
V. 1307, pp. 1-20.
34. Tobiszewski M., Mechlińska A. Green
analytical chemistry in sample preparation for
determination of trace organic pollutants, TrAC
Trends in Analytical Chemistry, 2009, V. 28,
No 8, pp. 943.
Dobrjakov Ju.G. et al. Problemy kontrolja
soderzhanija primesej letuchih
galogenproizvodnyh uglevodorodov v vodoprovodnoj
i stochnyh vodah, ZhAH., 2011, V.
66, No 8, pp. 859-869.
2. Kirichenko V.E., Pervova M.G.,
Pashkevich K.I. Galogenorganicheskie
soedinenija v pit'evoj vode i metody ih
opredelenija, Ros. him. zh., 2002, V. 16, No 4,
pp. 18-27.
3. Demeestere K., Dewulf J. Sample
preparation for the analysis of volatile organic
compounds in air and water matrices, J.
Chromatogr. A, 2007, V. 1153, pp. 130-144.
4. Chen Y., Guo Z. Sample preparation, J.
Chromatogr. A, 2008, V. 1184, pp. 191-219.
5. Chary N., Fernandez-Alba A.
Determination of volatile organic compounds in
drinking and environmental waters, Trends in
Analytical Chemistry, 2012, V. 32, pp. 60-75.
6. Antoniou C., Koukouraki E. Determination
of chlorinated volatile organic compounds in
water and municipal wastewater using
headspace-solid phase microextraction-gas
chromatography, J. Chromatogr. A, 2006, V.
1132, pp. 310-314.
7. Cai M., Huang P. A purge and trap gas
chromatographic method for detection of
chlorofluorocarbons in seawater, Chinese
Journal of Analytical Chemistry, 2013, V. 41,
pp. 268-272.
8. Farré M., Pérez S. Green analytical
chemistry in the determination of organic
pollutants in the aquatic environment, TrAC
Trends in Analytical Chemistry, 2010, V. 29,
pp. 1347-1362.
9. Vitenberg A.G. Staticheskij parofaznyj
gazohromatograficheskij analiz: Fizikohimicheskie
osnovy i oblasti primenenija, Ros.
him. zh., 2003, V. 47, No 1, pp. 7-22.
10. Khahenberg Kh., Shmidt A.
Gazohromatograficheskij analiz parovoj fazy,
M. Mir, 1977, 160 p.
11. Snow N.H., Slack G.C. Head-space
analysis in modern gas chromatography, Trend.
Anal. Chem., 2002, V. 21, pp. 608-617.
12. Lambropoulou D.A., Konstantinou I.K.,
Albanis T.A. Recent developments in headspace
microextraction techniques for the analysis of
environmental contaminants in different
matrices, J. Chromatogr. A, 2007, V. 1152,
pp. 70-96.
Родинков и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
125
13. Gonzalo A.L., Urıa J.E.S., Garcıa E.S. et
al. Critical comparison of automated purge and
trap and solid-phase microextraction for routine
determination of volatile organic compounds in
drinking waters by GC-MS, Talanta, 2008, V.
74, pp. 1455-1462.
14. Snow N.H., Bullock G.P. Novel
techniques for enhancing sensitivity in static
headspace extraction-gas chromatography, J.
Chromatogr. A, 2010, V. 1217, pp. 2726-2735.
15. Martínez C., Ramírez N. Simultaneous
determination of 76 micropollutants in water
samples by headspace solid phase
microextraction and gas chromatography-mass
spectrometry, Talanta, 2013, V. 116,
pp. 937-945.
16. Ueta I., Razaka N.A., Mizuguchia A. et al.
Needle-type extraction device for the purge and
trap analysis of 23 volatile organic compounds
in tap water, J. Chromatogr. A, 2013, V. 1317,
pp. 211-216.
17. Brown M.A., Miller S., Emmert G.L. Online
purge and trap gas chromatography for
monitoring of trihalomethanes in drinking water
distribution systems, Anal. Chem. Acta, 2007,
V. 592, pp. 154-161.
18. Saridara C., Brukh R., Mitra S.
Development of continuous on-line purge and
trap analysis, J. Sep. Sci., 2006, V. 29,
pp. 446-454.
19. Auer N.R., Manzke B.U., Schulz-Bull
D.E. Development of a purge and trap
continuous flow system for the stable carbon
isotope analysis of volatile halogenated organic
compounds in water, J. Chromatogr. A, 2006,
V. 1131, pp. 24-36.
20. Hyötyläinen T. Principles, developments
and applications of on-line coupling of
extraction with chromatography, J. Chromatogr.
A, 2007, V. 1153, pp. 14-28.
21. Hyötyläinen T. On-line coupling of
extraction with gas chromatography, J.
Chromatogr. A, 2008, V. 1186, pp. 39-50.
22. Ramos L. Critical overview of selected
contemporary sample preparation techniques, J.
Chromatogr. A, 2012, V. 1221, pp. 84-98.
23. Berezkin V.G. Himicheskie metody v gazovoj
hromatografii, M. Khimija, 1980, 256 p.
24. Berezkin V.G. Tatarinskij V.S. Gazokhromatograficheskie
metody analiza primesej,
M. Nauka, 1970, 213 p.
25. Ikem A. Measurement of volatile organic
compounds in bottled and tap waters by purge
and trap GC-MS: Are drinking water types
different?, Journal of Food Composition and
Analysis, 2010, V. 23, pp. 70-77.
26. Li H., Zhan H., Fu S., Liu M. et al. Rapid
determination of methanol in black liquors by
full evaporation headspace gas chromatography,
J. Chromatogr. A, 2007, V. 1175, pp. 133-136.
27. Jewell L.L., Davis B.H. Review of
absorption and adsorption in the hydrogenpalladium
system, Applied Catalysis A:
General, 2006, V. 310, pp. 1-15.
28. Moskvin L.N. Chromatomembrane
method for the continuous separation of
substances, J. Chromatogr. A, 1994, V. 669,
pp. 81-87.
29. Moskvin L.N., Rodinkov O.V.
Continuous chromatomembrane headspace
analysis, J. Chromatogr. A, 1996, V. 725,
pp. 351-359.
30. Moskvin L.N., Rodinkov O.V.
Chromatomembrane methods: physicochemical
principles, analytical and technological
possibilities, Russ. Chem. Bull., 2012, V. 61,
pp. 723-740.
31. Leeuwende S.P.J., Boer J. Advances in the
gas chromatographic determination of persistent
organic pollutants in the aquatic environment, J.
Chromatogr. A, 2008, V. 1186, pp. 161-182.
32. Kozlowska K., Polkowska Z. Investigation
of stability of aqueous solutions
containing trace amounts of volatile organic
analytes, Trends in Analytical Chemistry, 2006,
V. 25, No 6, pp. 608-620.
33. Płotka J., Tobiszewski M.. Green
chromatography, J. Chromatogr. A, 2013,
V. 1307, pp. 1-20.
34. Tobiszewski M., Mechlińska A. Green
analytical chemistry in sample preparation for
determination of trace organic pollutants, TrAC
Trends in Analytical Chemistry, 2009, V. 28,
No 8, pp. 943.
Published
2018-02-19
How to Cite
Писарев, А. Ю., Родинков, О. В., & Москвин, Л. Н. (2018). Headspace analysis of aqueous solutions coupled with a selective absorption of the gas-extractant. Sorbtsionnye I Khromatograficheskie Protsessy, 15(1), 116-126. https://doi.org/10.17308/sorpchrom.2015.15/262
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