Сорбция водорастворимых витаминов на сорбентах различной природы
Ключевые слова:
сорбция, твёрдофазная экстракция, водорастворимые витамины, витамины В1, В2, В3, В6, В12, высокоэффективная жидкостная хроматография, концентрирование, динамическая емкость сорбента
Аннотация
Исследование связано с проблемой анализа витаминизированных продуктов питания и
фармацевтических препаратов методами обращено фазовой высокоэффективной хроматографии.
Исследованы физико-химические закономерности адсорбции водорастворимых витаминов группы В
(В1, В2, В3, В6 и В12) из модельных водных растворов на сорбентах на основе силикагеля и
сверхсшитого полистирола. Из динамических выходных кривых измерена сорбционная емкость
сорбентов по отношению к каждому витамину. Показано, что достаточно высокой динамической
емкостью по отношению к водорастворимым витаминам обладают сорбенты на основе сверхсшитого
полистирола. Помимо природы сорбента адсорбция исследованных водорастворимых витаминов
сильно зависит от рН раствора.
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Литература
1.Rudenko A.O., Kartsova L.A., Davankov
V.A. Vyjavlenie vozmozhnostej sorbenta
Purosep-200 na osnove sverhsshitogo polistirola
pri analize vodo- i zhirorastvorimyh vitaminov
[Elicitation of opportunities of sorbent Purosep200
on the basis of super cross-linked
polystyrene in the analysis of water - and fatsoluble
vitamins], Sorbcionnye i
khromatograficheskie processy, 2009, Vol. 9,
No 6, pp. 766-773.
2.. Luque-García J.L., Luque de Castro M.D.
Extraction of fat-soluble vitamins, J.
Chromatogr. A, 2001, Vol. 935, pp. 3-11.
3.. Rychkova S.A., Lanin S.N., Shatalov I.A.
et al. Zakonomernosti sorbcii zhirorastvorimyh
vitaminov na sorbente Strata Traditional C18-E,
Sorbcionnye i khromatograficheskie processy,
2014, Vol. 14, No 3, pp. 397-405.
4.. http://www.phenomenex.com/
5.. Timin A., Rumyantsev E., Lanin S.N. et
al. Preparation and surface properties of
mesoporous silica particles modified with
poly(N-vinyl-2-pyrrolidone) as a potential
adsorbent for bilirubin removal, Materials
Chemistry and Physics, 2014, Vol. 147, No 3,
pp. 673-683.
6.. Pavlova L.A., Tsjurupa M.P., Davankov
V.A. et al. Ispol'zovanie sverhsshityh
polistirol'nyh sorbentov dlja ochistki
tehnologicheskih rastvorov sul'fata ammonija
proizvodstva kaprolaktama [Application of
super cross-linked polystyrene sorbents for
purification of technological solutions of
ammonium sulphate in the process of
caprolactam production], Sorbcionnye i
khromatograficheskie processy, 2009, Vol. 9,
No 1, pp. 89-98.
7.. Platonov I.A., Novikova E.A., Onuchak
L.A. Izuchenie sorbcii nitrobenzola na
sverhsshityh polistirol'nyh sorbentah [Study of
adsorption of nitrobenzene on super crosslinked
polystyrene sorbents], Sorbcionnye i
Ланин и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 2
194
khromatograficheskie processy, 2010, Vol. 10,
No 1, pp. 25-34.
8.. Zolotov Yu.A. Osnovy analiticheskoj
himii [Fundamentals of analytical chemistry).
V. 1. Obshhie voprosy. Metody razdelenija:
Uchebnik dlja vuzov (Common questions.
Separation methods: the Textbook for high
schools] / Yu.A. Zolotov, E.N. Dorohova, V.I.
Fadeeva et al. Moscow: Vyssh. shk. Publ,
2004, 361 p.
9.. Sychev K.S., Davankov V.A. Materialy i
metody probopodgotovki v chromatografii:
tverdofaznoe koncentrirovanie i adsorbcionnaja
ochistka [Materials and methods for sample
preparation in chromatography: solid-phase
concentration and adsorption], Sorbcionnye i
khromatograficheskie processy, 2004, Vol. 4,
No 1, pp. 5-28.
10. Lanin S.N., Nikitin Yu.S.
Prognozirovanie uderzhivanija v
vysokojeffektivnoj zhidkostoj hromatografii.
Mezhmolekuljarnye vzaimodejstvija v
podvizhnoj faze [Predicting of retention in highperformance
liquid chromatography.
Intermolecular interactions in the mobile phase],
Zhurn. analit. Chimii, 1991, Vol. 46, No 10, pp.
1971-1980.
11. . Lanin S.N., Ledenkova M.Ju., Nikitin
Yu.S. Chromatograficheskoe issledovanie
adsorbcii iz binarnyh i trojnyh rastvorov
[Chromatographic study of the adsorption from
binary and ternary solutions], Izv. AN. Ser.
Chim, 2001, No 2, pp. 220-224.
12. . Davankov V.A., Sychev K.S., Il'in M.M.
Primenenie sverhsshityh polistirol'nyh
sorbentov v vysokojeffektivnoj zhidkostnoj
hromatografii [Application of super cross-linked
polystyrene sorbents in high-performance liquid
chromatography], Zavodskaja laboratorija,
2003, Vol. 69, No 4, pp. 3-7.
13. . Davankov V.A., Sychov C.S., Ilyin
M.M. et al. Hypercrosslinked polystyrene as a
novel type of high-performance liquid
chromatography column packing material.
Mechanisms of retention, J. Chromatogr. A,
2003, Vol. 987, pp. 67-75.
14. . Davankov V.A., Tsyurupa M.P.
Structure and properties of hypercrosslinked
polystyrene the 1st representative of a new class
of polymer networks, Reactive Polymers, 1990,
Vol. 13, pp. 27-42.
15. . Ajvazov B.V. Praktikum po chimii
poverhnostnyh javlenij i adsorbcii [Workshop
on the chemistry of surface phenomena and
adsorption], Moscow: Vysshaja shkola Publ.,
1973, 208 p.
16. . Ivashhenko A.L., Bojchenko A.P.,
Loginova L.P. Pervoe soobshhenie o
vozmozhnosti odnovremennogo
izokraticheskogo razdelenija vodo- i
zhirorastvorimyh vitaminov metodom VJeZhCh
[The first message about the possibility of the
simultaneous isocratic separation of water - and
fat-soluble vitamins by HPLC], Vіsnik
Harkіvs'kogo nacіonal'nogo unіversitetu, 2007,
Vol. 770, No 15(38), pp. 82-89.
17. . Dmitrienko S.G., Smirnova S.V.,
Hatunceva L.N. et al. Metody razdelenija i
koncentrirovanija [Methods of separation and
concentration], Moscow: Moscow State
university Publ, 2008, 197 p.
V.A. Vyjavlenie vozmozhnostej sorbenta
Purosep-200 na osnove sverhsshitogo polistirola
pri analize vodo- i zhirorastvorimyh vitaminov
[Elicitation of opportunities of sorbent Purosep200
on the basis of super cross-linked
polystyrene in the analysis of water - and fatsoluble
vitamins], Sorbcionnye i
khromatograficheskie processy, 2009, Vol. 9,
No 6, pp. 766-773.
2.. Luque-García J.L., Luque de Castro M.D.
Extraction of fat-soluble vitamins, J.
Chromatogr. A, 2001, Vol. 935, pp. 3-11.
3.. Rychkova S.A., Lanin S.N., Shatalov I.A.
et al. Zakonomernosti sorbcii zhirorastvorimyh
vitaminov na sorbente Strata Traditional C18-E,
Sorbcionnye i khromatograficheskie processy,
2014, Vol. 14, No 3, pp. 397-405.
4.. http://www.phenomenex.com/
5.. Timin A., Rumyantsev E., Lanin S.N. et
al. Preparation and surface properties of
mesoporous silica particles modified with
poly(N-vinyl-2-pyrrolidone) as a potential
adsorbent for bilirubin removal, Materials
Chemistry and Physics, 2014, Vol. 147, No 3,
pp. 673-683.
6.. Pavlova L.A., Tsjurupa M.P., Davankov
V.A. et al. Ispol'zovanie sverhsshityh
polistirol'nyh sorbentov dlja ochistki
tehnologicheskih rastvorov sul'fata ammonija
proizvodstva kaprolaktama [Application of
super cross-linked polystyrene sorbents for
purification of technological solutions of
ammonium sulphate in the process of
caprolactam production], Sorbcionnye i
khromatograficheskie processy, 2009, Vol. 9,
No 1, pp. 89-98.
7.. Platonov I.A., Novikova E.A., Onuchak
L.A. Izuchenie sorbcii nitrobenzola na
sverhsshityh polistirol'nyh sorbentah [Study of
adsorption of nitrobenzene on super crosslinked
polystyrene sorbents], Sorbcionnye i
Ланин и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 2
194
khromatograficheskie processy, 2010, Vol. 10,
No 1, pp. 25-34.
8.. Zolotov Yu.A. Osnovy analiticheskoj
himii [Fundamentals of analytical chemistry).
V. 1. Obshhie voprosy. Metody razdelenija:
Uchebnik dlja vuzov (Common questions.
Separation methods: the Textbook for high
schools] / Yu.A. Zolotov, E.N. Dorohova, V.I.
Fadeeva et al. Moscow: Vyssh. shk. Publ,
2004, 361 p.
9.. Sychev K.S., Davankov V.A. Materialy i
metody probopodgotovki v chromatografii:
tverdofaznoe koncentrirovanie i adsorbcionnaja
ochistka [Materials and methods for sample
preparation in chromatography: solid-phase
concentration and adsorption], Sorbcionnye i
khromatograficheskie processy, 2004, Vol. 4,
No 1, pp. 5-28.
10. Lanin S.N., Nikitin Yu.S.
Prognozirovanie uderzhivanija v
vysokojeffektivnoj zhidkostoj hromatografii.
Mezhmolekuljarnye vzaimodejstvija v
podvizhnoj faze [Predicting of retention in highperformance
liquid chromatography.
Intermolecular interactions in the mobile phase],
Zhurn. analit. Chimii, 1991, Vol. 46, No 10, pp.
1971-1980.
11. . Lanin S.N., Ledenkova M.Ju., Nikitin
Yu.S. Chromatograficheskoe issledovanie
adsorbcii iz binarnyh i trojnyh rastvorov
[Chromatographic study of the adsorption from
binary and ternary solutions], Izv. AN. Ser.
Chim, 2001, No 2, pp. 220-224.
12. . Davankov V.A., Sychev K.S., Il'in M.M.
Primenenie sverhsshityh polistirol'nyh
sorbentov v vysokojeffektivnoj zhidkostnoj
hromatografii [Application of super cross-linked
polystyrene sorbents in high-performance liquid
chromatography], Zavodskaja laboratorija,
2003, Vol. 69, No 4, pp. 3-7.
13. . Davankov V.A., Sychov C.S., Ilyin
M.M. et al. Hypercrosslinked polystyrene as a
novel type of high-performance liquid
chromatography column packing material.
Mechanisms of retention, J. Chromatogr. A,
2003, Vol. 987, pp. 67-75.
14. . Davankov V.A., Tsyurupa M.P.
Structure and properties of hypercrosslinked
polystyrene the 1st representative of a new class
of polymer networks, Reactive Polymers, 1990,
Vol. 13, pp. 27-42.
15. . Ajvazov B.V. Praktikum po chimii
poverhnostnyh javlenij i adsorbcii [Workshop
on the chemistry of surface phenomena and
adsorption], Moscow: Vysshaja shkola Publ.,
1973, 208 p.
16. . Ivashhenko A.L., Bojchenko A.P.,
Loginova L.P. Pervoe soobshhenie o
vozmozhnosti odnovremennogo
izokraticheskogo razdelenija vodo- i
zhirorastvorimyh vitaminov metodom VJeZhCh
[The first message about the possibility of the
simultaneous isocratic separation of water - and
fat-soluble vitamins by HPLC], Vіsnik
Harkіvs'kogo nacіonal'nogo unіversitetu, 2007,
Vol. 770, No 15(38), pp. 82-89.
17. . Dmitrienko S.G., Smirnova S.V.,
Hatunceva L.N. et al. Metody razdelenija i
koncentrirovanija [Methods of separation and
concentration], Moscow: Moscow State
university Publ, 2008, 197 p.
Опубликован
2018-02-19
Как цитировать
Рычкова, С. А., Ланин, С. Н., Виноградов, А. Е., Вирясов, М. Б., Востров, И. А., & Шаталов, И. А. (2018). Сорбция водорастворимых витаминов на сорбентах различной природы. Сорбционные и хроматографические процессы, 15(2), 179-195. https://doi.org/10.17308/sorpchrom.2015.15/267
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