Sorption of water-soluble vitamins in various sorbents
Keywords:
sorption, solid phase extraction, water-soluble vitamins, vitamins В1, В2, В3, В6, В12, high performance liquid chromatography, concentration, dynamic capacity of sorbent.
Abstract
In connection with the problem of the analysis of vitaminised food and pharmaceutical products by
the reversed phase high performance chromatography , there were investigated the physico-chemical
regularities of adsorption of water-soluble b vitamins (B1, B2, B3, B6 and B12) from model aqueous
solutions on the sorbents based on silica gel and supersewn polystyrene. From the dynamic output curves the
sorption capacity of sorbents with respect to each vitamin were measured. It has been shown that a
sufficiently high dynamic capacity in relation to water-soluble vitamins have sorbents on the basis of super
cross-linked polystyrene. In addition to the nature of the sorbent adsorption of the investigated water-soluble
vitamins is strongly dependent on the pH of the solution.
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References
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zhirorastvorimyh vitaminov metodom VJeZhCh
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fat-soluble vitamins by HPLC], Vіsnik
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Hatunceva L.N. et al. Metody razdelenija i
koncentrirovanija [Methods of separation and
concentration], Moscow: Moscow State
university Publ, 2008, 197 p.
V.A. Vyjavlenie vozmozhnostej sorbenta
Purosep-200 na osnove sverhsshitogo polistirola
pri analize vodo- i zhirorastvorimyh vitaminov
[Elicitation of opportunities of sorbent Purosep200
on the basis of super cross-linked
polystyrene in the analysis of water - and fatsoluble
vitamins], Sorbcionnye i
khromatograficheskie processy, 2009, Vol. 9,
No 6, pp. 766-773.
2.. Luque-García J.L., Luque de Castro M.D.
Extraction of fat-soluble vitamins, J.
Chromatogr. A, 2001, Vol. 935, pp. 3-11.
3.. Rychkova S.A., Lanin S.N., Shatalov I.A.
et al. Zakonomernosti sorbcii zhirorastvorimyh
vitaminov na sorbente Strata Traditional C18-E,
Sorbcionnye i khromatograficheskie processy,
2014, Vol. 14, No 3, pp. 397-405.
4.. http://www.phenomenex.com/
5.. Timin A., Rumyantsev E., Lanin S.N. et
al. Preparation and surface properties of
mesoporous silica particles modified with
poly(N-vinyl-2-pyrrolidone) as a potential
adsorbent for bilirubin removal, Materials
Chemistry and Physics, 2014, Vol. 147, No 3,
pp. 673-683.
6.. Pavlova L.A., Tsjurupa M.P., Davankov
V.A. et al. Ispol'zovanie sverhsshityh
polistirol'nyh sorbentov dlja ochistki
tehnologicheskih rastvorov sul'fata ammonija
proizvodstva kaprolaktama [Application of
super cross-linked polystyrene sorbents for
purification of technological solutions of
ammonium sulphate in the process of
caprolactam production], Sorbcionnye i
khromatograficheskie processy, 2009, Vol. 9,
No 1, pp. 89-98.
7.. Platonov I.A., Novikova E.A., Onuchak
L.A. Izuchenie sorbcii nitrobenzola na
sverhsshityh polistirol'nyh sorbentah [Study of
adsorption of nitrobenzene on super crosslinked
polystyrene sorbents], Sorbcionnye i
Ланин и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 2
194
khromatograficheskie processy, 2010, Vol. 10,
No 1, pp. 25-34.
8.. Zolotov Yu.A. Osnovy analiticheskoj
himii [Fundamentals of analytical chemistry).
V. 1. Obshhie voprosy. Metody razdelenija:
Uchebnik dlja vuzov (Common questions.
Separation methods: the Textbook for high
schools] / Yu.A. Zolotov, E.N. Dorohova, V.I.
Fadeeva et al. Moscow: Vyssh. shk. Publ,
2004, 361 p.
9.. Sychev K.S., Davankov V.A. Materialy i
metody probopodgotovki v chromatografii:
tverdofaznoe koncentrirovanie i adsorbcionnaja
ochistka [Materials and methods for sample
preparation in chromatography: solid-phase
concentration and adsorption], Sorbcionnye i
khromatograficheskie processy, 2004, Vol. 4,
No 1, pp. 5-28.
10. Lanin S.N., Nikitin Yu.S.
Prognozirovanie uderzhivanija v
vysokojeffektivnoj zhidkostoj hromatografii.
Mezhmolekuljarnye vzaimodejstvija v
podvizhnoj faze [Predicting of retention in highperformance
liquid chromatography.
Intermolecular interactions in the mobile phase],
Zhurn. analit. Chimii, 1991, Vol. 46, No 10, pp.
1971-1980.
11. . Lanin S.N., Ledenkova M.Ju., Nikitin
Yu.S. Chromatograficheskoe issledovanie
adsorbcii iz binarnyh i trojnyh rastvorov
[Chromatographic study of the adsorption from
binary and ternary solutions], Izv. AN. Ser.
Chim, 2001, No 2, pp. 220-224.
12. . Davankov V.A., Sychev K.S., Il'in M.M.
Primenenie sverhsshityh polistirol'nyh
sorbentov v vysokojeffektivnoj zhidkostnoj
hromatografii [Application of super cross-linked
polystyrene sorbents in high-performance liquid
chromatography], Zavodskaja laboratorija,
2003, Vol. 69, No 4, pp. 3-7.
13. . Davankov V.A., Sychov C.S., Ilyin
M.M. et al. Hypercrosslinked polystyrene as a
novel type of high-performance liquid
chromatography column packing material.
Mechanisms of retention, J. Chromatogr. A,
2003, Vol. 987, pp. 67-75.
14. . Davankov V.A., Tsyurupa M.P.
Structure and properties of hypercrosslinked
polystyrene the 1st representative of a new class
of polymer networks, Reactive Polymers, 1990,
Vol. 13, pp. 27-42.
15. . Ajvazov B.V. Praktikum po chimii
poverhnostnyh javlenij i adsorbcii [Workshop
on the chemistry of surface phenomena and
adsorption], Moscow: Vysshaja shkola Publ.,
1973, 208 p.
16. . Ivashhenko A.L., Bojchenko A.P.,
Loginova L.P. Pervoe soobshhenie o
vozmozhnosti odnovremennogo
izokraticheskogo razdelenija vodo- i
zhirorastvorimyh vitaminov metodom VJeZhCh
[The first message about the possibility of the
simultaneous isocratic separation of water - and
fat-soluble vitamins by HPLC], Vіsnik
Harkіvs'kogo nacіonal'nogo unіversitetu, 2007,
Vol. 770, No 15(38), pp. 82-89.
17. . Dmitrienko S.G., Smirnova S.V.,
Hatunceva L.N. et al. Metody razdelenija i
koncentrirovanija [Methods of separation and
concentration], Moscow: Moscow State
university Publ, 2008, 197 p.
Published
2018-02-19
How to Cite
Рычкова, С. А., Ланин, С. Н., Виноградов, А. Е., Вирясов, М. Б., Востров, И. А., & Шаталов, И. А. (2018). Sorption of water-soluble vitamins in various sorbents. Sorbtsionnye I Khromatograficheskie Protsessy, 15(2), 179-195. https://doi.org/10.17308/sorpchrom.2015.15/267
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