Optimization of conditions for potentiometric determination of citrate ions

Authors

  • Sergey V. Tkachenko Ph.D., assistant professor, chemistry department, agrochemical faculty, Voronezh State Agrarian University, Voronezh, e-mail: sergey07@box.vsi.ru
  • Ludmila Ph. Naumenko Ph.D., assistant professor, chemistry department, agrochemical faculty, Voronezh State Agrarian University, Voronezh
  • Raisa N. Korneeva senior researcher, analytical chemistry department, chemical faculty, Voronezh State University, Voronezh
  • Natalya M. Buneeva senior researcher, analytical chemistry department, chemical faculty, Voronezh State University, Voronezh
  • Vladimir F. Selemenev D.Sc., professor, head of the analytical chemistry department, chemical faculty, Voronezh State University, Voronezh

Keywords:

potentiometric titration, citrates, copper-selective electrode, numerical experiment.

Abstract

A mathematical model of the potentiometric titration of citrate solutions with copper (II) salt that
adequately reflects the influence of ionic strength on the accuracy of determining the equivalence point
built. The way of correction of the analysis results was proposed. The measures to optimize the technique
of titration that reduce systematic error were determined.

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Published

2019-11-28

How to Cite

Optimization of conditions for potentiometric determination of citrate ions. (2019). Sorbtsionnye I Khromatograficheskie Protsessy, 10(6). https://journals.vsu.ru/sorpchrom/article/view/2126

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