Сoncentration waves behaviour and the chromatographic displacement development in the sorbentsnanocomposites during the multicomponent mass transfer and visualisation of the sorption kinetics process
Abstract
There is considered the Multi-(6th)-component Mass Transfer (MMT) inside the planar matrices of
the sorbent-NanoComposite (NC) by the computerized modelling. During the MMT kinetics in the NC planar-
membrane the chromatographic Displacement Development (DD) for the propagating modes of the two
concentration Xm(1,2)(L,T)-principal waves is modeled for the two principal m1,2-sorbate components (m=1,2)
of the Multi(6)-components NC MMT combined “Diffusion, and sorption” system.
The computerized modelling mentioned here is based on the mathematical solution of the MMT
multi 6-components Eqns. partial differential including as the basis the author’s bi-functional NC MMT
Models. The main advantage of the NC Models considered concludes in the introduction of the two sorbate
diffusing principal Pi(3.4)-components into the consideration. The similarity and the differences between the
multicomponent Xn(L,T)-concentration waves propagation for the MMT processes in the modern NC matrix
and in the chromatographic column are discussed.
The visualization of the kinetics of the MMT процесс is realized by the creation of the Sci. computerized
Animations: “SCA.avi” video-files which demonstrate visually (after the program start) the propagation
of the multi(n)-component Xn(1-6)(L,T)-concentration waves through the NC matrixe. Here the “SCA.avi
animations display the DD chromatographic effect during oral presentation with the mentioned DDdisplacement
of the X2-concentration waves by the X1-waves of the 1-component (displacer).
Downloads
References
2..Kalinitchev A., Journal for Phys. Chem.(Rus.), 2019, No 9, pp.369-377. doi:10.1134/S0044453719090073.
3. Kalinitchev A., Sorbtsionnye i khromatograficheskie protsessy, 2018, Vol. 18, No 5, pp.916-930.(Rus).
4.Kalinitchev A., Material Sci & Eng.J MS&EIJ (USE, Med Crave Ed.), 2018, No 2(4), pp. 128-132. (CrossRef; doi: 10.15406/mseij.2018.02.00045).
5. Kalinitchev A., NanoTechnol Rev.(NTREV). Special issue (N5) “NanoTechnology: from Convergence to Divergence”,
DeGruyter Ed.3(5), 2014, pp. 467-498 (.http://degruyter.com/new/ ntrev2014.3 issuefiles. doi:10.1515/ntrev-2014-0007. Publ. on
line 8.10, and Printed 14.10. 2014(Ed. Ja S.Lee).
6. Kalinitchev A., Prot. Met.&Phys. Chem. Surf. (Springer Ed.), 2013, Vol. 49(6), pp.627-638. doi:10.1134/S2070205113060051.http:
//www. springerlink. com/ openurl. asp?genre=article& ID.
7. Kalinitchev A., Advances in Nanoparticles, AnP. 2013, No 2(2), pp. 1-13. Sci.Res.Publ.:SCIRP. E-Journ. doi:10.4236/anp.2013.22028 (Site AnP:http:// www.scirp.org/ journal/anp/).ID: 31894..
8. Kalinitchev A., Sorbtsionnye i khromatograficheskie protsessy, 2016, Vol. 16, No 6, pp.748-768 (Eng).
9. Kravchenko T.A., Polyanskiy L.N., KalinichevA. I., Konev D.V., Nano Kompozity Metall–IonoObmennik. M., “Nauka”, 2009, 390 p.
(Monografiya) (Rus.).
10.. Kalinitchev A. Laboratory and production (Rus), 2019, No 2(6), pp.162-167 DOI: 10.32757/2619-0923.2019.2.6.162.167.
http://labpro-media.ru/wpcontent/uploads/2019/05/Kalinichev.pdf.
11. Haaze R., Termodinamiсs of Irreversible Processes, (Rus.) Ch.2;4, M., Mir, 1967, 544 p.
12. Helfferich F., Klein G., Multicomponent Chromatography. Theory of Interference, New York, M. Dekker Inc., 1970, 360 p.
13 Kalinitchev A., J. Rus. Chem. Reviews, 1996, Vol. 65, pp. 95-115. (English) doi:10.1070/RC 1996v065n02A BEH000201.
14. Whitham G., Linear and Nonlinear waves, Wiley. NY, 1974, 636 p.
15. Kalinitchev A.I., Hoell W.H., Ion Exchange Technology for Today and Tomorrow, Cox M., Ed.,Soc.Chem.Ind.(SCI)Lond., 2004,
pp.53-58 (Extend.Thes., pp.349-356).www. soci.org.
16. Kalinitchev A.I., Hoell W.H., Recent Advancesin IEx Theory&Practice, Cox M., Ed.Soc.Chem.Ind. (SCI), Lond., 2008, pp. 85-93, (www.soci.org.).
17.Kalinitchev A.I., In “IEX2012” Cox M.,Ed.,Soc. of Chem. Ind., Lond., S. Fundam.(El. Book). 2012. pp. 1-18.