Hydration of heterogeneous cation-exchange membranes in hydrogen and amino acids forms. I. Study by IR-spectroscopy
Keywords:
arginine, histidine, cation-exchange membrane, hydration, IR-spectrum.
Abstract
Hydration characteristics of heterogeneous sulfocation-exchange membranes MK-40 and
FTCM-E in hydrogen and amino acid’s forms are studied by IR-spectroscopy. Energy of hydrogen bonds
in ion-exchange membrane is calculated on the basis of absorption strips displacement in the IRspectrum.
Basic amino acids sorption by the membrane leads to a decrease of total water content in the
membrane phase and to an increase of water molecules fraction having high values of hydrogen bonds
energy.
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References
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with simultaneous concentration by electrodialysis // Sorbtsion. Khromatogr. Protsessy.
2008. Vol. 8. Iss.6. P. 1013-1017. [in Russian].
2.Selemenev V.F., Khokhlov V.Yu., Bobreshova O.V. et al. Physicochemical Bases of
Sorbtion and Membrane Methods of Extraction and Separation of Amino Acids. Moscow:
Stelait. 2002. 298 p. [in Russian].
3.Krisilova E.V., Eliseeva T.V., Selemenev V.F. The hydration of cation-exchange
membranes after sorption of basic amino acids // Zh. Fiz. Khim. 2009. Vol. 83. № 11. Р.
2145-2151.
4.Berezina N.P., Kononenko N.A., Dvorkina G.A. et al. Fizikokhimicheskie svoistva
ionoobmennykh materialov:praktikum (The Physicochemical Properties of Ion- Exchange
Materials: Practical Course), Krasnodar: Kuban. Gos. Univ. 1999. 82 p.[in Russian].
5.Roshal E.R., Demina N.G., Sholin A.F. Analysis of amino acids in the form of copper
complexes // Russian Chem.-Pharm. J. 1988. № 6. Р. 30. [in Russian].
6.Rowland S.P., Ed. Water in Polymers. ACS Symposium Series 127: Washington. 1980.
532 p.
7.Eliseeva T.V., Shaposhnik V.A., Krisilova E.V., Bukhovets A.E. Transport of basic
amino acids through the ion-exchange membranes and their recovery by electrodialysis //
Desalination. 2009. V. 241. P. 86-90.
8.Krisilova E.V., Eliseeva T.V., Selemenev V.F. Sorption of arginine and lysine by
homogeneous cation-exchange membrane MF-4SK // Sorbtsion. Khromatogr. Protsessy.
2009. Vol. 9. № 5. Р. 671-676. [in Russian].
9.Bellamy L.J. Infrared Spectra of Complex Molecules. John Wiley & Sons, Inc.: N.Y.
1958. 280 p.
10. Zundel G. Hydrate structures, intermolecular interactions and proton conducting
mechanism in polyelectrolyte membranes — infrared results // J. Membr. Sci. 1982. V. 11.
Iss. 3. P. 249-274.
11. Zundel G. Hydration Structure and Intermolecular Interaction in Polyelectrolytes //
Angewandte Chemie. Int. Edition in English. 1969. V. 8. Iss.7. P. 499-509.
12. Johansen A.V. Infrared Spectroscopy and Spectral Determination of Hydrogen
Bond Energy. In: Hydrogen Bond [Russian translation]. Moscow. 1981. P. 112-155.
Published
2019-11-18
How to Cite
Lantsuzskaya, E. V., Eliseeva, T. V., Oros, G. Y., Chernikov, M. A., Selemenev, V. F., & Sholokhova, A. Y. (2019). Hydration of heterogeneous cation-exchange membranes in hydrogen and amino acids forms. I. Study by IR-spectroscopy. Sorbtsionnye I Khromatograficheskie Protsessy, 14(1). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1440
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