Basic regularities of electrolyte separation in the method of Acid Retardation. II. Influence of acid and salt concentration on their sorption from individual solutions
Keywords:
electrolytes, sorption.
Abstract
Study of regularities and development of the Acid and Ion Retardation processes determine the
subject and purpose of the work.
The retardation and non-exchange sorption of the components of individual electrolyte solution was
studied in the systems: nitric, hydrochloric, sulfuric or phosphoric acid – anionic resin AB-17 in the same
ionic form, as well as ammonium or magnesium nitrate - AB-17 in the nitrate form.
The dependencies of sorption capacities on the concentration of electrolytesin solutions are exposed.
It is shown that these relationships are almost identical for both acids for the sorption on suitable anionic
forms of the anion exchanger, but differ significantly for different nitrate salts.
The regularities found can be applied for choosing the conditions for the separation of electrolytes
from their mixed concentrated solutions.
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References
1. Evtushenko A.V., Pavlukhina L.D.,
Yakusheva A.M. Vliyanie kontsentratsii kisloty
i ee soli na protsessy sorbtsii-desorbtsii kislot i
ikh solei v rastvorakh v metode «uderzhivaniya
kisloty» [Influence of acid and it’s salt
concentrations on the process
sorptiondesorption of acids and their salts in
solutions in the Acid Retardation method],
Sorbtsionnye i khromatograficheskie protsessy,
2013, V. 13, No 3, pp. 313-321.
2. Khamizov R.Kh., Krachak A.N., Gruzdeva
A.N. et al. Sorbtsionnoe kontsentrirovanie i
vydelenie RZE iz ekstraktsionnoi fosfornoi
kisloty [Concentration and insulation of REE
from industrial extractive phosphorous acid by
sorption method], Sorbtsionnye i
khromatograficheskie protsessy, 2012, V. 12.
No 1, pp. 29-39.
3. Khokhlova O.N. Bezreagentnoe razdelenie
tirozina i fenilalanina na anionite an-221 v
usloviyakh neobmennogo pogloshcheniya
[Reagentless separation of thyrosinum and
phenylalanine on the anionite AN- 221 in the
conditions of nonexchange absorption],
Sorbtsionnye i khromatograficheskie protsessy,
2005, V. 5, No 3, pp. 340-346.
4. Krachak A.N., Khamizov R.Kh.,
Poznukhova V.A. et al. Osnovnye
zakonomernosti razdeleniya elektrolitov v
metode «Uderzhivaniya kisloty» (Acid
retardation). I. Vliyanie prirody kationa na
sorbtsiyu kislot i ikh solei iz binarnykh
rastvorov [Basic regularities of electrolyte
separation in the method of Acid Retardation. I.
Influence of cation type on the sorption of acids
and their salts from binary solutions],
Sorbtsionnye i khromatograficheskie protsessy,
2011, V.11, No 1, pp. 77-88
5. Glotova E. A., Tikhonov N.A, Khamizov
R. Kh. et al. Matematicheskoe modelirovanie
sorbtsionnogo protsessa "uderzhivaniya kisloty"
iz rastvora [Mathematical modeling of sorption
process «Acid Retardation» from solution],
Vestnik Moskovskogo Universiteta, Seriya 3,
Fizika. Astronomiya, 2013, No 1, pp.64-68.
6. Sidel'nikov G.B., Tikhonov N.A.,
Khamizov R.Kh. et al. Modelirovanie i
issledovanie sorbtsionnogo protsessa
razdeleniya kislot i solei v rastvore [Modeling
and research of acids and salts sorption
separation process in the solution],
Matematicheskoe modelirovanie, 2013, V. 25,
No 4, pp. 3-16
7. Dolgonosov A.M. Mekhanizm razdeleniya
sil'nykh elektrolitov ionitami, baziruyushchiisya
na elektrokineticheskoi eksklyuzii koionov
[Mechanism of separation of strong electrolytes
by ion-exchangers, based on electrokinetic
exclusion of co-ions], Sorbtsionnye i
khromatograficheskie protsessy, 2013, V. 13,
No 5, pp. 568-577.
8. Senyavin M.M., Rubinshtein R.N.,
Komarova I.V. et al. Teoreticheskie osnovy
demineralizatsii presnykh vod [Theoretical
bases of demineralization of fresh waters],
«Nauka», 1975, 326 p.
9. Ferapontov N.B., Gorshkov V.I., Trobov
Kh.T. et al. Bezreagentnoe razdelenie
elektrolitov na ionitakh [Reagentless separation
of electrolytes on ion-exchangers], Zhurnal
fizicheskoi khimii, 1996, V.70, No 5. pp. 904-907.
10. Tsyurupa M.P., Blinnikova Z.K.,
Davankov V.A. Eksklyuzionnaya
khromatografiya mineral'nykh elektrolitov na
neitral'nom nanoporistom sverkhsshitom
polistirole: mekhanizm «zaderzhivaniya» kislot,
solei i osnovanii [Size exclusion
chromatography of mineral electrolytes on
neutral nanoporous hypercrosslinked
polystyrene: mechanism of acid retardation, salt
retardation, base retardation], Sorbtsionnye i
khromatograficheskie protsessy, 2013, V. 13,
No 5, pp. 541-552
11. Ferapontov N.B., Gorshkov V.I.,
Parbuzina L.R.et al. Heterophase model of
swollen cross-linked polyelectrolyte. // React.
Funct. Polymers, 1999, V. 41, No 1-3, pp. 213-225.
Yakusheva A.M. Vliyanie kontsentratsii kisloty
i ee soli na protsessy sorbtsii-desorbtsii kislot i
ikh solei v rastvorakh v metode «uderzhivaniya
kisloty» [Influence of acid and it’s salt
concentrations on the process
sorptiondesorption of acids and their salts in
solutions in the Acid Retardation method],
Sorbtsionnye i khromatograficheskie protsessy,
2013, V. 13, No 3, pp. 313-321.
2. Khamizov R.Kh., Krachak A.N., Gruzdeva
A.N. et al. Sorbtsionnoe kontsentrirovanie i
vydelenie RZE iz ekstraktsionnoi fosfornoi
kisloty [Concentration and insulation of REE
from industrial extractive phosphorous acid by
sorption method], Sorbtsionnye i
khromatograficheskie protsessy, 2012, V. 12.
No 1, pp. 29-39.
3. Khokhlova O.N. Bezreagentnoe razdelenie
tirozina i fenilalanina na anionite an-221 v
usloviyakh neobmennogo pogloshcheniya
[Reagentless separation of thyrosinum and
phenylalanine on the anionite AN- 221 in the
conditions of nonexchange absorption],
Sorbtsionnye i khromatograficheskie protsessy,
2005, V. 5, No 3, pp. 340-346.
4. Krachak A.N., Khamizov R.Kh.,
Poznukhova V.A. et al. Osnovnye
zakonomernosti razdeleniya elektrolitov v
metode «Uderzhivaniya kisloty» (Acid
retardation). I. Vliyanie prirody kationa na
sorbtsiyu kislot i ikh solei iz binarnykh
rastvorov [Basic regularities of electrolyte
separation in the method of Acid Retardation. I.
Influence of cation type on the sorption of acids
and their salts from binary solutions],
Sorbtsionnye i khromatograficheskie protsessy,
2011, V.11, No 1, pp. 77-88
5. Glotova E. A., Tikhonov N.A, Khamizov
R. Kh. et al. Matematicheskoe modelirovanie
sorbtsionnogo protsessa "uderzhivaniya kisloty"
iz rastvora [Mathematical modeling of sorption
process «Acid Retardation» from solution],
Vestnik Moskovskogo Universiteta, Seriya 3,
Fizika. Astronomiya, 2013, No 1, pp.64-68.
6. Sidel'nikov G.B., Tikhonov N.A.,
Khamizov R.Kh. et al. Modelirovanie i
issledovanie sorbtsionnogo protsessa
razdeleniya kislot i solei v rastvore [Modeling
and research of acids and salts sorption
separation process in the solution],
Matematicheskoe modelirovanie, 2013, V. 25,
No 4, pp. 3-16
7. Dolgonosov A.M. Mekhanizm razdeleniya
sil'nykh elektrolitov ionitami, baziruyushchiisya
na elektrokineticheskoi eksklyuzii koionov
[Mechanism of separation of strong electrolytes
by ion-exchangers, based on electrokinetic
exclusion of co-ions], Sorbtsionnye i
khromatograficheskie protsessy, 2013, V. 13,
No 5, pp. 568-577.
8. Senyavin M.M., Rubinshtein R.N.,
Komarova I.V. et al. Teoreticheskie osnovy
demineralizatsii presnykh vod [Theoretical
bases of demineralization of fresh waters],
«Nauka», 1975, 326 p.
9. Ferapontov N.B., Gorshkov V.I., Trobov
Kh.T. et al. Bezreagentnoe razdelenie
elektrolitov na ionitakh [Reagentless separation
of electrolytes on ion-exchangers], Zhurnal
fizicheskoi khimii, 1996, V.70, No 5. pp. 904-907.
10. Tsyurupa M.P., Blinnikova Z.K.,
Davankov V.A. Eksklyuzionnaya
khromatografiya mineral'nykh elektrolitov na
neitral'nom nanoporistom sverkhsshitom
polistirole: mekhanizm «zaderzhivaniya» kislot,
solei i osnovanii [Size exclusion
chromatography of mineral electrolytes on
neutral nanoporous hypercrosslinked
polystyrene: mechanism of acid retardation, salt
retardation, base retardation], Sorbtsionnye i
khromatograficheskie protsessy, 2013, V. 13,
No 5, pp. 541-552
11. Ferapontov N.B., Gorshkov V.I.,
Parbuzina L.R.et al. Heterophase model of
swollen cross-linked polyelectrolyte. // React.
Funct. Polymers, 1999, V. 41, No 1-3, pp. 213-225.
Published
2019-11-20
How to Cite
Krachak, A. N., Khamizov, R. K., Dolgonosov, A. M., & Malkova, L. M. (2019). Basic regularities of electrolyte separation in the method of Acid Retardation. II. Influence of acid and salt concentration on their sorption from individual solutions. Sorbtsionnye I Khromatograficheskie Protsessy, 14(6). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1575
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