The study of sorption of palmitic acid polymers based on imidizated polyamide acid
Keywords:
polyamide acid, molecularly imprinted polymers (MIPs), palmitic acids, sorption.
Abstract
Currently, molecularly imprinted polymers (MIPs) may are used for problem solving the selective
sorption separation of organic substances. Therefore, the aim is to study the adsorption of palmitic acid by
molecularly imprinted polymers and comparison polymer. In the work were synthesized comparison
polymers and polymers with molecular imprints of palmitic acid. In the synthesis of MIPs had used
polyamide acid as a precursor. Study of adsorption of palmitic acid polymers based on polyamide acid
conducted at the facility with a conductometric detector in the on-line mode. From the obtained data were
built sorption isotherms, calculated distribution coefficient, the degree of extraction and imprinting factor
(IF=12,7). During the work it was found that the polymer with molecular imprints best absorbs palmitic acid,
which is caused by the presence in MIP centers complementary in shape and size of the template molecules.
Downloads
Download data is not yet available.
References
1. Gendrikson O.D., Zherdev A.V., Dzantiev
B.B. Molekulyarno-imprintirovannye polimery
i ikh primenenie v biologicheskom analize
(Molecularly imprinted polymers and their use
in biological analysis), Uspekhi biologicheskoi
khimii, 2006, V. 46, pp. 149-192.
2. Lisichkin G.V., Krutyakov Yu.A.
Materialy s molekulyarnymi otpechatkami:
sintez, svoistva, primenenie (Materials with
molecular imprints: synthesis, properties,
application), Uspekhi khimii, 2006, V. 75, No.
10, pp. 998-1016.
3. Zhibrova Yu.A., Zyablov A.N., Selemenev
V.F., D'yakonova O.V., Sokolova S.A.
Polimery s molekulyarnymi otpechatkami dlya
p'ezokvartsevykh sensorov [Polymers with
molecular imprints for piezoquartz sensors],
Sorbtsionnye i khromatograficheskie protsessy,
2008, Vol. 8, No. 5, pp. 853-854.
4. Dmitrienko S.G., Irkha V.V., Kuznetsova
L.Yu., Zolotov Yu.A. Ispol'zovanie polimerov s
molekulyarnymi otpechatkami v protsessakh
razdeleniya i kontsentrirovaniya organicheskikh
soedinenii [The use of polymers with molecular
imprints in the processes of separation and
concentration of organic compounds], Zhurnal
analiticheskoi khimii, 2004, V. 59, No. 9, pp.
902-913.
5. Kotov V.V., D'yakonova O.V., Sokolova
S. A., Volkov V.I. Struktura i
elektrokhimicheskie svoistva
kationoobmennykh membran na osnove
chastichno imidizirovannoi poliamidokisloty
[Structure and electrochemical properties of cation exchange membranes based on partially
imidizated polyamide acid], Elektrokhimiya,
2002, V. 38, No. 8, pp. 994-997.
6. Kotov V.V., Sokolova S.A., Netesova
G.A., Karpov S.I., Kuznetsova I.V. Sostoyanie
vody v membranakh na osnove
aromaticheskikh poliamidov [The state of water
in the membranes based on aromatic
polyamides], Zhurnal fizicheskoi khimii, 2005,
V. 79, No. 10, pp. 1896.
7. D'yakonova O.V., Zyablov A.N., Kotov
V.V., Eliseeva T.V., Selemenev V.F., Frolova
V.V. Issledovanie sostoyaniya poverkhnosti
membran na osnove poliamidokisloty [The
study of the surface membranes based on
polyamide acid], Sorbtsionnye i
khromatograficheskie protsessy, 2005, V. 5,
No. 4, pp. 501-506.
8. D'yakonova O.V., Sokolova S.A, Zyablov
A.N., Zhibrova Yu.A. Osobennosti
formirovaniya struktury poliamidokislotnykh
membran v zavisimosti ot temperatury sinteza
[Features of formation of structure
polyamidation membranes depending on the
synthesis temperature], Sorbtsionnye i
khromatograficheskie protsessy, 2007, V. 7,
No. 5, pp. 873-877.
9. Zyablov A.N., Duvanova O.V., Volodina
L.V., Selemenev V.F., D'yakonova O.V.
P'ezoelektricheskii sensor na osnove
molekulyarno-imprintirovannogo polimera dlya
opredeleniya pal'mitinovoi kisloty
[Piezoelectric sensor based on molecularly
imprinted polymers for the determination of
palmitic acid], Patent RF, No. 2013144501/28,
2014.
10. Duvanova O.V., Volodina L.V., Zyablov
A.N., Grechkina M.V., Semiletova E.S. et al.
Analiz morfologii poverkhnosti polimerov s
molekulyarnymi otpechatkami oleinovoi i
pal'mitinovoi kislot [Analysis of the surface
morphology of polymers with molecular
imprints oleic and palmitic acids], Sorbtsionnye
i khromatograficheskie protsessy, 2013, V. 13,
No. 5, pp. 884-890.
11. Volodina L.V., Duvanova O.V., Zyablov
A.N., Selemenev V.F., D'yakonova O.V. et al.
Analiz struktury i sostava polimerov s
molekulyarnymi otpechatkami oleinovoi i
pal'mitinovoi kislot [Analysis of the structure
and composition of polymers with molecular
imprints oleic and palmitic acids], Sorbtsionnye
i khromatograficheskie protsessy, 2014, V. 14,
No. 1, pp. 111-120.
12. Kudrinskaya V.A., Dmitrienko S.G.
Vliyanie rastvoritelya na sorbtsionnye svoistva
polimerov s molekulyarnymi otpechatkami
kvertsetina [Solvent effect on the sorption
properties of polymers with molecular imprints
quercetin], Sorbtsionnye i
khromatograficheskie protsessy, 2009, V. 9,
No. 6, pp. 824-829.
13. Karnaukhov A.P. Adsorbtsiya. Tekstura
dispersnykh i poristykh. Novosibirsk: Nauka.
Sib. predpriyatie RAN, 1999, 470 p.
14. Sokolova S.A., D'yakonova O.V.,
Zyablov A.N. Osobennosti struktury
ionoobmennykh poliamidokislotnykh membran,
sintezirovannykh pri razlichnykh temperaturakh
[Features of the structure of ion-exchange
polyamidation membranes synthesized at
different temperatures], Sorbtsionnye i
khromatograficheskie protsessy, 2009, V. 9,
No. 6, pp. 1002-1007.
B.B. Molekulyarno-imprintirovannye polimery
i ikh primenenie v biologicheskom analize
(Molecularly imprinted polymers and their use
in biological analysis), Uspekhi biologicheskoi
khimii, 2006, V. 46, pp. 149-192.
2. Lisichkin G.V., Krutyakov Yu.A.
Materialy s molekulyarnymi otpechatkami:
sintez, svoistva, primenenie (Materials with
molecular imprints: synthesis, properties,
application), Uspekhi khimii, 2006, V. 75, No.
10, pp. 998-1016.
3. Zhibrova Yu.A., Zyablov A.N., Selemenev
V.F., D'yakonova O.V., Sokolova S.A.
Polimery s molekulyarnymi otpechatkami dlya
p'ezokvartsevykh sensorov [Polymers with
molecular imprints for piezoquartz sensors],
Sorbtsionnye i khromatograficheskie protsessy,
2008, Vol. 8, No. 5, pp. 853-854.
4. Dmitrienko S.G., Irkha V.V., Kuznetsova
L.Yu., Zolotov Yu.A. Ispol'zovanie polimerov s
molekulyarnymi otpechatkami v protsessakh
razdeleniya i kontsentrirovaniya organicheskikh
soedinenii [The use of polymers with molecular
imprints in the processes of separation and
concentration of organic compounds], Zhurnal
analiticheskoi khimii, 2004, V. 59, No. 9, pp.
902-913.
5. Kotov V.V., D'yakonova O.V., Sokolova
S. A., Volkov V.I. Struktura i
elektrokhimicheskie svoistva
kationoobmennykh membran na osnove
chastichno imidizirovannoi poliamidokisloty
[Structure and electrochemical properties of cation exchange membranes based on partially
imidizated polyamide acid], Elektrokhimiya,
2002, V. 38, No. 8, pp. 994-997.
6. Kotov V.V., Sokolova S.A., Netesova
G.A., Karpov S.I., Kuznetsova I.V. Sostoyanie
vody v membranakh na osnove
aromaticheskikh poliamidov [The state of water
in the membranes based on aromatic
polyamides], Zhurnal fizicheskoi khimii, 2005,
V. 79, No. 10, pp. 1896.
7. D'yakonova O.V., Zyablov A.N., Kotov
V.V., Eliseeva T.V., Selemenev V.F., Frolova
V.V. Issledovanie sostoyaniya poverkhnosti
membran na osnove poliamidokisloty [The
study of the surface membranes based on
polyamide acid], Sorbtsionnye i
khromatograficheskie protsessy, 2005, V. 5,
No. 4, pp. 501-506.
8. D'yakonova O.V., Sokolova S.A, Zyablov
A.N., Zhibrova Yu.A. Osobennosti
formirovaniya struktury poliamidokislotnykh
membran v zavisimosti ot temperatury sinteza
[Features of formation of structure
polyamidation membranes depending on the
synthesis temperature], Sorbtsionnye i
khromatograficheskie protsessy, 2007, V. 7,
No. 5, pp. 873-877.
9. Zyablov A.N., Duvanova O.V., Volodina
L.V., Selemenev V.F., D'yakonova O.V.
P'ezoelektricheskii sensor na osnove
molekulyarno-imprintirovannogo polimera dlya
opredeleniya pal'mitinovoi kisloty
[Piezoelectric sensor based on molecularly
imprinted polymers for the determination of
palmitic acid], Patent RF, No. 2013144501/28,
2014.
10. Duvanova O.V., Volodina L.V., Zyablov
A.N., Grechkina M.V., Semiletova E.S. et al.
Analiz morfologii poverkhnosti polimerov s
molekulyarnymi otpechatkami oleinovoi i
pal'mitinovoi kislot [Analysis of the surface
morphology of polymers with molecular
imprints oleic and palmitic acids], Sorbtsionnye
i khromatograficheskie protsessy, 2013, V. 13,
No. 5, pp. 884-890.
11. Volodina L.V., Duvanova O.V., Zyablov
A.N., Selemenev V.F., D'yakonova O.V. et al.
Analiz struktury i sostava polimerov s
molekulyarnymi otpechatkami oleinovoi i
pal'mitinovoi kislot [Analysis of the structure
and composition of polymers with molecular
imprints oleic and palmitic acids], Sorbtsionnye
i khromatograficheskie protsessy, 2014, V. 14,
No. 1, pp. 111-120.
12. Kudrinskaya V.A., Dmitrienko S.G.
Vliyanie rastvoritelya na sorbtsionnye svoistva
polimerov s molekulyarnymi otpechatkami
kvertsetina [Solvent effect on the sorption
properties of polymers with molecular imprints
quercetin], Sorbtsionnye i
khromatograficheskie protsessy, 2009, V. 9,
No. 6, pp. 824-829.
13. Karnaukhov A.P. Adsorbtsiya. Tekstura
dispersnykh i poristykh. Novosibirsk: Nauka.
Sib. predpriyatie RAN, 1999, 470 p.
14. Sokolova S.A., D'yakonova O.V.,
Zyablov A.N. Osobennosti struktury
ionoobmennykh poliamidokislotnykh membran,
sintezirovannykh pri razlichnykh temperaturakh
[Features of the structure of ion-exchange
polyamidation membranes synthesized at
different temperatures], Sorbtsionnye i
khromatograficheskie protsessy, 2009, V. 9,
No. 6, pp. 1002-1007.
Published
2019-11-20
How to Cite
KrivonosovаI. A., Duvanova, O. V., Zyablov, A. N., & Falaleev, A. V. (2019). The study of sorption of palmitic acid polymers based on imidizated polyamide acid. Sorbtsionnye I Khromatograficheskie Protsessy, 14(6). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1576
Section
Статьи
