Elektric-selectivity factor in exchange of multicharged ions
Keywords:
phenomenology, ion-echange adsorption, equilibrium, strong dissociating ionits, different electrical ion-charges, isotherm of sorption.
Abstract
The interrelation between ratio of division and equilibrium chemical composition of ionit’s phase
was derived in binary ion-echange sistems with strong dissociating ionits for case of different electrical ioncharges.
Established interrelation allows to receive a quantitative estimate of influence of electric-selectivity
phenomen, as factor of division - for any ion-charges and concentrations
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References
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tehnologii [Ion exchangers in chemical
technology]. L., Himiya, 1982, 416 p.
2. Mariinskiy Ya.M. Ionnyj obmen [Ion
exchange],Mir, 1968, 565 p.
3. Soldatov V.S. Prostye ionoobmennye
ravnovesija [Simple ion exchange equilibrium],
Minsk: Nauka i tehnika, 1972, 218 p.
4. Kokotov Ju.A., Pasechnik V.A.
Ravnovesie i kinetika ionnogo obmena
[Equilibrium and kinetics of ion exchange], L.,
Himija, 1970, 336 p.
5. Kokotov Ju.A., Zolotarev P.P., El'kin G.Je.
Teoreticheskie osnovy ionnogo obmena:
Slozhnye sistemy [Theoretical Foundations of
ion exchange: Complex Systems], L., Himiya,
1986, 280 p.
6. Kuz'minyh V.A., Selemenev V.F.
Fenomenologija selektivnoj ionoobmennoj
sorbcii [Phenomenology of selective ionexchange
sorption], Materialy V Vserossijskoj
konferencii «Fiziko-himicheskie processy v
kondensirovannyh sredah i na mezhfaznyh
granicah (FAGRAN-2010)», 3-8okt. 2010 g..
Voronezh: IPC «Nauchnaja kniga», 2010, pp.
746-749.
7. Kuz'minyh V.A., Selemenev V.F.
Vzaimosvjaz' kojefficienta razdelenija
mnogozarjadnyh ionov s faktorami vlijanija
[Relationship partition coefficient of multiply
charged ions with the factors of influence],
Materialy V Vserossijskoj konferencii «Fizikohimicheskie
processy v kondensirovannyh
sredah i na mezhfaznyh granicah (FAGRAN-
2010)», 3-8okt. 2010 g.. Voronezh: IPC
«Nauchnaja kniga», 2010, pp. 749-752.
8. Kuz'minyh V.A., Selemenev V.F.
Izmenenie i obrashhenie selektivnosti
nepolnost'ju dissociirujushhego ionita pri
ionnom obmene [Change and handling selective
partial dissociation of the ion exchanger in ionexchange],
Teorija i praktika sorbcionnyh
processov. Voronezh: Izd-vo VGU, 2000, No.
26, pp. 195-212.
9. Kuz'minyh V.A., Selemenev V.F.
Razdelenie ionov pri nepolnoj dissociacii
vzaimodejstvujushhih faz v ionoobmennoj
sisteme [Separation of ions with incomplete
dissociation of the interacting phases in the ion
exchange system], Sorbcionnnye i
khromatograficheskie processy, 2007, No. 5,
pp. 764-773.
10. Korotkih O.I., Khohlova O.N., Khohlov
V.Ju., Selemenev V.F. Prognozirovanie vida
vyhodnyh krivyh sorbcii aminokislot
nizkoosnovnym anionoobmennikom AN-251, Sorbcionnnye i khromatograficheskie processy,
2009, No. 5, pp. 603-609.
11. Gel'man V.Ja. Reshenie matematicheskih
zadach sredstvami Excel: Praktikum, SPb.:
Piter, 2003. 240 p.
Published
2019-11-20
How to Cite
Kuzminykh, V. A., Selemenev, V. F., & Kozlov, A. T. (2019). Elektric-selectivity factor in exchange of multicharged ions. Sorbtsionnye I Khromatograficheskie Protsessy, 14(6). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1577
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Статьи