Influence thermal dehydrated polihidroxialuminium montmorillonite on adsorption of carbon thetrachloride
Keywords:
adsorption, isotherms, isosters of adsorption, heat of adsorption, montmorillonite.
Abstract
Results are analyzed of the study of the Adsorption and Differential Isosteric Heats of Adsorption of
Carbon Tetrachloride on Polyhydroxyaluminum Montmorillonite dehydrated in the interval 293-873K.
Isotherms of adsorption were measured at sorption plant with quartz spring balances similar to Mak-Ben’s,
but isosters – on volumes plant for direct measure of adsorption of isosters. Formation of chinkous
micropores upon substitution of cations of sodium on polyhydroxyaluminum leads to rapid increase of
adsorption the volume of minerals and the increase of thermostability. Dependence of heat adsorption of size
of adsorption has extreme character. Heat adsorption of CCl4 on PHAM dehydrated at 423 K was much more
than the sample dehydrated at 873 K.
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References
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Faraday Soc, 1957, V. 53, pp. 1253-1258.
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Theory of physical adsorption of Gases and
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Acad. Press, 1972, pp. 3-11.
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Adsorption of Carbon Tetrachloride on a
Microporous Clay adsorbent, Colloid Journal,
2001, V. 63, No. 6, pp.746-749.
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A.Ya. et al. Khimicheskoe modifitsirovanie
poverkhnosti adsorbentov i ego vliyanie na
adsorbtsionnye svoistva [Chemical
Modification of Adsorbents Surface and its
Influence on Adsorption Properties], Dokl. AN
SSSR, 1959, V. 124, No 3, pp. 617-622.
I.I. et al. Adsorbtsiya gazov na sloistykh
silikatakh pri vysokikh davleniyakh [Adsorption
of gases in lamellar silicates under high
pressures], Izv. Akademii nauk. Ser.khim, 2013,
No 10, pp.2102-2107.
2. Muminov S.Z., Gulyamova D.B. Teplota
adsorbtsii parov piridina na
poligidroksialyuminievom montmorillonite
[Heat Adsorption of Pyridine Vapors on
Polyhydroxyaluminum Montmorillonite],
Russian Journal of Physical Chem. A, 2000, V.
74, No 6, pp.1085-1089.
3. Muminov S.Z., Pribylov A.A., Gulyamova
D.B. et al. Equilibrium Adsorption of n-Hexane
and Carbon Tetrachloride vapors on sodium and
polyhydroxyaluminum Montmorillonites,
Colloid journal, 2009, V. 71, No 5, pp.672-677.
4. Muminov S.Z., Gulyamova D.B., Pribylov
A.A. Adsorption of Acetonitrile Vapor on
Sodium and Polyhydroxyaluminum
Montmorillonites, Colloid Journal, 2006, V. 68,
No 5, pp.584-587.
5. Muminov S.Z., Khandamov D.A.,
Rakhimova G.B. Heats of n-Hexane and n-
Heptane Vapor Adsorption Montmorillonite,
Russian Journal of Physical Chem. A, 2011, V.
85., No 1, pp.112-116.
6. Muminov S.Z., Gulyamova D.B., Aripov
E.A. Adsorbtsiya parov benzola na
termoobrabotannom montmorillonite s
poligidroksialyuminievymi kationami
[Adsorption of Benzene Vapors on Thermal
Processing Montmorillonite With
Polyhydroxyaluminum Cations], Russian Journal of Physical Chem. A, 1993, V. 67, No
12, pp.2436-2438.
7. Muminov S.Z., Gulyamova D.B. Teplota
adsorbtsii parov metilovogo spirta na
mikroporistom montmorillonite [Heat
Adsorption of Methanol Vapor on Microporous
Montmorillonite], Russian Journal of Physical
Chem. A, 1997, V. 71, No 10, pp.1834-1836.
8. Pribylov A.A., Muminov S.Z., Kalinnikova
I.I., Shchekhovtsova L.G. Adsorbtsiya dioksida
ugleroda na montmorillonitakh razlichnykh
kationo-obmennykh form, Kolloidn. Zhurn,
2010, T.72, No 3. pp. 409-411.
9. Stacey M.H. Alumina-Pillared clays and
their adsorptive properties, Catalysis today.
1988. V. 2/3. pp. 621-631.
10. Pinnavaia T.S. Intercalated clay catalysts,
Science, 1983 V. 220, No 4595, pp. 365-369.
11. Fomkin A.A., Muminov S.Z., Pulin A.L.
et al. Adsorbtsionnaya deformatsiya
mikroporistykh adsorbentov/Sovremennye
problemy teorii adsorbtsii [Modern Problems
Theory of Adsorption], M., 1995, V. 2, pp.172-
179.
12. Fomkin A.A. Adsorbtsiya v
mikroporistykh adsorbentakh/Adsorbtsiya,
adsorbenty i sorbtsionnye protsessy v
nanoporistykh materialakh [Adsorption,
Adsorbents and Sorption Processes at
Microporous Materials], M., 2011, pp. 133-161.
13. Matsumoto M., Shinoda S., Takahashi H.,
Saito Y. Adsorption properties of pillar
intercalated montmorillonite, Bull Chem.
Soc.Jpn, 1987, V. 57, No 1, pp. 1795-1801.
14. Vargaftik N.B. Spravochnik po
teplofizicheskim svoistvam gazov i zhidkostei
[Handbook for Heat Physics Properties of
Liquids and Gases], M., Nauka, 1972, 720 p.
15. Muminov S.Z. Ustanovka dlya
neposredstvennogo izmereniya izoster
adsorbtsii [Plant for Direct Measure of Isosters
Adsorption] Uzbekskii khim.zhurn, 1965, No 6,
pp. 58-62.
16. Muminov S.Z., Aripov E.A., Issledovanie
v oblasti termodinamiki i termokhimii adsorbtsii
na glinistykh mineralakh [Studies in
Thermodynamics and Thermochemistry of
Adsorption on Clay Minerals], Tashkent, Fan.
1987, 144 p.
17. De Boer J.H. The structure and properties
of porous materials, London, Butterworth, 1958,
pp. 68.
18. Muminov S.Z., Aripov E.A., Rakhimov
A.A./Adsorbtsiya i poristost'. Pod red
[Adsorption and Porosity], M., Nauka, 1976, pp.
71-72.
19. Barrer R.M., Reay J.S.S. Sorption and
intercalation by montmorillonites, Trans.
Faraday Soc, 1957, V. 53, pp. 1253-1258.
20. Dubinin M.M. Fundamentals of the
Theory of physical adsorption of Gases and
Vapours in Micropores, In Adsorption-
Desorption Phenomena, London-New York,
Acad. Press, 1972, pp. 3-11.
21. Muminov S.Z., Gulyamova D.B., Seitova
E.A. Temperature Dependence of the
Adsorption of Carbon Tetrachloride on a
Microporous Clay adsorbent, Colloid Journal,
2001, V. 63, No. 6, pp.746-749.
22. Kiselev A.V., Kovaleva N.V., Korolev
A.Ya. et al. Khimicheskoe modifitsirovanie
poverkhnosti adsorbentov i ego vliyanie na
adsorbtsionnye svoistva [Chemical
Modification of Adsorbents Surface and its
Influence on Adsorption Properties], Dokl. AN
SSSR, 1959, V. 124, No 3, pp. 617-622.
Published
2019-11-20
How to Cite
Muminov, S. Z., Kurbonov, S. D., & Ergashev, O. K. (2019). Influence thermal dehydrated polihidroxialuminium montmorillonite on adsorption of carbon thetrachloride. Sorbtsionnye I Khromatograficheskie Protsessy, 14(6). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1582
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