Gas chromatographic study of sorption properties of mixed polymer phase containing acetylated β-cyclodextrin
Keywords:
β-cyclodextrin, gas-liquid chromatography, polydimethylsiloxane.
Abstract
In work was studied sorption of organic compounds of different classes, including some of the
optical isomers, by gas-liquid chromatography, by polymeric phase polydimethylsiloxane PMS-100 and
mixed phase "PMS-100 - heptakis(2,3,6-O-acetyl)-β-cyclodextrin». It is shown that the additive chiral
macrocyclic compound promotes strengthening of intermolecular interactions «sorbate - stationary
phase» at the expense of formation of complexes on type «guest - host» for small molecules on the size of
organic compounds, and also causes moderated enantioselective properties of the investigated sorbent.
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References
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2. Mayer S., Schmalzing D., Jung M., Schleimer M. A chiral test mixture for
permethylated β-cyclodextrin – polysiloxane gas – liquid chromatography phases: The
Schurig test mixture. // LC-GC. 1992. V.10. P.784–785.
3. Aroonsiri Shitangkoona, Jirawit Yanchindaa, Juwadee Shiowatana. Thermodynamic
study on the gas chromatographic separation of theenantiomers of aromatic alcohols using
heptakis(2,3-di-O-methyl-6-O-tret-butyldimethylsilyl)-β-cyclodextrin as a stationary
phase. // J. Chromatogr. A. 2004. V.1049. P.223–226.
4. Suhua Qi, Ping Ai, Cenyi Wang, Liming Yuan, Guangyi Zhang. The characteristics of
a mixed stationary phase containing Permethylated-b-CD and Perpentylated-b-CD in gas
chromatography. // Separation and Purification Technology. 2006. V.48. P.310–313.
5. S. Tisse, V. Peulon-Agasse, P. Cardina, J.-P. Bouillon, J.-C. Combret. Capillary gas
chromatographic properties of three new mono-esterpermethylated β-cyclodextrin
derivatives. // Anal. chim. acta. 2006. V.560. P.207–217.
6. Eisuke Takahisa, Karl-Heinz Engel. 2,3-Di-O-methoxymethyl-6-O-tertbutyldimethylsilyl-
γ-cyclodextrin: a new class of cyclodextrin derivatives for gas
chromatographic separation of enantiomers. // J. Chromatogr. A. 2005. V.1063. P.181–
192.
7. Яшин Я.И., Яшин Е.Я., Яшин А.Я. Газовая хроматография. М.: Издательство
«ТрансЛит», 2009.– 528 с.
8. Кудряшов С.Ю., Онучак Л.А., Даванков В.А. Физико-химическая интерпретация
характеристик удерживания в газовой хроматографии с идеальной сжимаемой
подвижной фазой // Журн. физ. хим. 2002. Т.76. №5. С.833–837.
9. Стид Дж.В., Этвуд Дж.Л. Супрамолекулярная химия. М.: ИКЦ "Академкнига",
2007. Т.1. 480с. Т.2. 416с.
10. Колб Б. Газовая хроматография с примерами и иллюстрациями – Самара: Изд-
во «Самарский университет», 2007. – 243 c.
Published
2019-11-22
How to Cite
Onuchak, L. A., Kuraeva, Y. G., Platonov, V. I., Chvanov, V. O., & Belousova, Z. P. (2019). Gas chromatographic study of sorption properties of mixed polymer phase containing acetylated β-cyclodextrin. Sorbtsionnye I Khromatograficheskie Protsessy, 12(3). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1788
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