Influence of eluent composition on retention by hypercrosslinked polystyrene in RP HPLC
Keywords:
reversed-phase high performance liquid chromatography, hypercrosslinked polystyrene, octadecylsilicagel, mobile phase composition.
Abstract
Chromatographic retention of some organic compounds was investigated under different eluent
composition within the limits of Snyder, Snyder – Sochevinsky and Scott – Cućera models on the
octadecylsilicagel and hypercrosslinked polystyrene. Application limites of such models were estimated,
retention mechanism of investigated substances on both sorbents were compared.
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References
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2.Snyder L.R., Dolan J.W., Gant J.R. Gradient elution in high-performance liquid
chromatography. I. Theoretical basis for reversed-phase systems // J. Chromatogr. 1979.
V. 165 P 3.
3.Soczewinski E. Solvent composition effects in TLC systems of the type silica gelelectron
donor solvuit. // Anal. Chem. 1969. V. 41. P. 179.
4.Scott R.P.W., Kucera P. Examination of five commercially available liquid
chromatographic reversed phases (including the nature of the solute-solvent-stationary
phase interactions associated with them) // J. Chromatogr. 1977. V. 142. P. 213.
5.Ланин С.Н., Ланина Н.А., Никитин Ю.С. Влияние ассоциации молекул сорбата и
модификатор в подвижной фазе на удерживание в высокоэффективной жидкостной
хроматографии // Журн. физ. химии. 1995. Т. 69. № 11. С. 2045.
6.Davankov V., Tsyurupa M., Ilyin M., Pavlova L. Hypercross-linked polystyrene and its
potentials for liquid chromatography: a mini-review // J. Chromatogr. A. 2002. V. 965.
P. 65.
7.Davankov V.A., Sychov C.S., Ilyin M.M., Sochilina K.O. Hypercrosslinked
polystyrene as a novel type of high-performanceliquid chromatography column packing
material. Mechanisms of retention // J. Chromatogr. A. 2003. V. 987. P. 67.
8.Tate P.A., Dorsey J.G. Column selection for liquid chromatographic estimation of the
k’w hydrophobicity parameter. // J. Chromatogr. A. 2004. V. 1024. P. 37.
9.Ланин С.Н. Адсорбционные модели удерживания в жидкостной хроматографии /
100 лет хроматографии. М.: Наука, 2003. С. 407.
10. Penner N.A., Nesterenko R.N., Ilyin M.M., Tsyurupa M.P., Davankov V.A.
Investigation of the Properties of Hypercrosslinked Polystyrene as a Stationary Phase for
High-Performance Liquid Chromatography // Chromatographia 1999. Vol. 50. № 9/10. P.611.
11. Sychov C.S., Ilyin M.M., Davankov V.A., Sochilina K.O. Elucidation of retention
mechanisms on hypercrosslinked polystyrene used as column packing material for highperformance
liquid chromatography // J. Chromatogr. A. 2004. V. 1030. P. 17.
Published
2019-11-22
How to Cite
Prokopov, S. V., Frolova, I. V., & Kurbatova, S. V. (2019). Influence of eluent composition on retention by hypercrosslinked polystyrene in RP HPLC. Sorbtsionnye I Khromatograficheskie Protsessy, 12(3). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1791
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