Planetary centrifuge as a chromatographic device
Keywords:
countercurrent chromatography, planetary centrifuge, rotating coiled columns.
Abstract
Basic factors that determine the effect of planetary centrifuges used in countercurrent
chromatography are considered. An expression for the tangential projection of the centrifugal inertial force is
obtained for rotating coiled column motion which is a sum of two rotations in the same direction around two
parallel axes at different angular velocities. It is shown that the proposed physical model can describe both
the chromatographic separation of components and existence of stationary phase retention due to the force
field in rotating coiled columns.
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References
1.Ito Y., Weinstein M., Aoki I., Harada R. et
al. The Coil Planet Centrifuge // Nature, 1966,
V. 212, pp. 985-987.
2.Ito Y., Bowman R.L. Countercurrent
Chromatography: Liquid-Liquid Partition
Chromatography without Solid Support, Science,
1970, V. 167, No. 3916, pp. 281-283.
3.Ito Y., Bowman R.L. Countercurrent
Chromatography with Flow-Through Coil Planet
Centrifuge, Science, 1971, V. 173, No. 3995, pp.
420-422.
4.Berthod A., Maryutina T., Spivakov B. et al.
Countercurrent Chromatography in Analytical
Chemistry (IUPAC Technical Report), Pure and
Appl. Chem. 2009, V. 81, No. 2, pp. 355-387.
5.Countercurrent Chromatography: The
Support-Free Liquid Stationary Phase, Ed.
Berthod A. Comprehensive Analytical
Chemistry, 2002, V. 38, pp. 1-397.
6.Conway W.D. Countercurrent
Chromatography: Apparatus, Theory and
Applications. New York: VCH Publishers, 1990,
475 p.
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T.A. et al. Partition countercurrent
chromatography in inorganic analysis, Fresenius
Z. Anal. Chem, 1989, V. 335, No. 8, P. 938-944.
8.Maryutina T.A., Spivakov B.Ya., Tschopel
P. Application of countercurrent
chromatography to purification of chemical
reagents, Fresenius J. Anal. Chem, 1996, V. 356,
No. 7, pp. 430-434.
9.Ignatova S.N., Maryutina T.A., Spivakov
B.Ya. et al. Group separation of trace rare
earth elements by countercurrent chromatography
for their determination in high-purity
calcium chloride, Fresenius J. Anal. Chem.,
2001, V. 370, No. 8, P. 1109-1113.
10. Maryutina T.A., Fedotov P.S., Spivakov
B.Ya. Application of Countercurrent
Chromatography in Inorganic Analysis,
Countercurrent Chromatography. Eds. Menet J.-
M., Thiébaut D. Chromatographic Science
Series, 1999, V. 82, pp. 171-221.
11. Fedotov P.S. Untraditional Applications
of Countercurrent Chromatography, J. Liq.
Chrom. & Rel. Tech., 2002. V. 25, No. 13-15,
pp. 2065-2078.
12. Fedotov P.S., Spivakov B.Ya., Shkinev
V.M. Possibility of field-flow fractionation
of macromolecules and particles in a rotating
coiled tube, Anal. Sci., 2000, V. 16, No. 4,
pp. 535-536.
13. Katasonova O.N., Fedotov P.S.,
Spivakov B.Ya. et al. Behavior of Solid
Microparticles in Their Fractionation on a
Rotating Coiled Column, J. Anal. Chem., 2003,
V. 58, No. 5, pp. 473-477.
14. Katasonova O.N., Fedotov P.S.,
Karandashev V.K. et al. Application of rotating
coiled columns to the fractionation of soil
particles and to the sequential extraction of
heavy-metal species from silty, dusty, and sandy
fractions, J. Anal. Chem., 2005, V. 60, No. 7,
pp. 684-690.
15. Fedotov P.S., Ermolin M.S., Savonina
E.Yu. et al. Fractionation of nano- and
microparticles in a rotating conoidal coiled
column, J. Anal. Chem., 2010, V. 65, No. 12,
pp. 1209-1214.
16. Fedotov P.S. Rotating coiled columns in
the speciation analysis of natural samples:
Dynamic fractionation of element forms in soils,
sludges, and bottom sediments, J. Anal. Chem.,
2012, V. 67, No. 5, pp. 399-413.
17. Fedotov P.S., Savonina E.Yu., Spivakov
B.Ya. et al. Possibilities for the harmonization
of methods of the dynamic fractionation
of elements in soils and bottom sediments, J.
Anal. Chem., 2012, V. 67, No. 10, pp. 851-861.
18. Ito Y. Development of high-speed
countercurrent chromatography, Advances in
Chromatogr., 1984, V. 24, pp. 181-226.
19. Ito Y. Cross-Axis Synchronous FlowThrough
Coil Planet Centrifuge Free of Rotary
Грибов и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
18
Seals for Preparative Countercurrent Chromatography.
Part I. Apparatus and Analysis of
Acceleration, Separation Science and Technology,
1987, V. 22, No. 8-10, pp. 1971-1987.
20. Mandava N.B., Ito Y. Principles and
instrumentation of countercurrent chromatography,
Countercurrent Chromatography. Theory
and Practice. Eds. Mandava N.B., Ito Y. Chromatographic
Science Series., 1988, V. 44,
pp. 79-442.
21. Ito Y. Speculation on the Mechanism of
Unilateral Hydrodynamic Distribution of Two
Immiscible Solvent Phases in the Rotating Coil,
J. Liq. Chromatogr., 1992, V. 15, No. 15-16,
pp. 2639-2675.
22. Ito Y. High-Speed Countercurrent Chromatography.
New York: Wiley, 1996, 477 p.
23. Wood P.L., Hawes D., Janaway L. et al.
Stationary Phase Retention in CCC: Modelling
the J-Type Centrifuge as a Constant Pressure
Drop Pump, J. Liq. Chrom. & Rel. Tech., 2003,
V. 26, No.9-10, pp. 1373-1396.
24. Fedotov P.S., Kronrod V.A., Maryutina
T.A. et al. Simulation of the Mechanism of
Liquid Stationary Phase Retention in a Rotating
Coil Column: Hydrophobic Liquid Systems, J.
Anal. Chem., 2002, V. 57, No. 1, pp. 24-30.
25. Fedotov P.S., Kronrod V.A., Kasatonova
O.N. Simulation of the motion of solid
particles in the carrier liquid flow in a rotating
coiled column, J. Anal. Chem., 2005, V. 60,
No. 4, pp. 310-316.
26. Zhukovsky N.E. Teoreticheskaya
mehanika [Theoretical Mechanics]. M.-L.:
GITTL, 1952, 107 p.
al. The Coil Planet Centrifuge // Nature, 1966,
V. 212, pp. 985-987.
2.Ito Y., Bowman R.L. Countercurrent
Chromatography: Liquid-Liquid Partition
Chromatography without Solid Support, Science,
1970, V. 167, No. 3916, pp. 281-283.
3.Ito Y., Bowman R.L. Countercurrent
Chromatography with Flow-Through Coil Planet
Centrifuge, Science, 1971, V. 173, No. 3995, pp.
420-422.
4.Berthod A., Maryutina T., Spivakov B. et al.
Countercurrent Chromatography in Analytical
Chemistry (IUPAC Technical Report), Pure and
Appl. Chem. 2009, V. 81, No. 2, pp. 355-387.
5.Countercurrent Chromatography: The
Support-Free Liquid Stationary Phase, Ed.
Berthod A. Comprehensive Analytical
Chemistry, 2002, V. 38, pp. 1-397.
6.Conway W.D. Countercurrent
Chromatography: Apparatus, Theory and
Applications. New York: VCH Publishers, 1990,
475 p.
7.Zolotov Yu.A., Spivakov B.Ya., Maryutina
T.A. et al. Partition countercurrent
chromatography in inorganic analysis, Fresenius
Z. Anal. Chem, 1989, V. 335, No. 8, P. 938-944.
8.Maryutina T.A., Spivakov B.Ya., Tschopel
P. Application of countercurrent
chromatography to purification of chemical
reagents, Fresenius J. Anal. Chem, 1996, V. 356,
No. 7, pp. 430-434.
9.Ignatova S.N., Maryutina T.A., Spivakov
B.Ya. et al. Group separation of trace rare
earth elements by countercurrent chromatography
for their determination in high-purity
calcium chloride, Fresenius J. Anal. Chem.,
2001, V. 370, No. 8, P. 1109-1113.
10. Maryutina T.A., Fedotov P.S., Spivakov
B.Ya. Application of Countercurrent
Chromatography in Inorganic Analysis,
Countercurrent Chromatography. Eds. Menet J.-
M., Thiébaut D. Chromatographic Science
Series, 1999, V. 82, pp. 171-221.
11. Fedotov P.S. Untraditional Applications
of Countercurrent Chromatography, J. Liq.
Chrom. & Rel. Tech., 2002. V. 25, No. 13-15,
pp. 2065-2078.
12. Fedotov P.S., Spivakov B.Ya., Shkinev
V.M. Possibility of field-flow fractionation
of macromolecules and particles in a rotating
coiled tube, Anal. Sci., 2000, V. 16, No. 4,
pp. 535-536.
13. Katasonova O.N., Fedotov P.S.,
Spivakov B.Ya. et al. Behavior of Solid
Microparticles in Their Fractionation on a
Rotating Coiled Column, J. Anal. Chem., 2003,
V. 58, No. 5, pp. 473-477.
14. Katasonova O.N., Fedotov P.S.,
Karandashev V.K. et al. Application of rotating
coiled columns to the fractionation of soil
particles and to the sequential extraction of
heavy-metal species from silty, dusty, and sandy
fractions, J. Anal. Chem., 2005, V. 60, No. 7,
pp. 684-690.
15. Fedotov P.S., Ermolin M.S., Savonina
E.Yu. et al. Fractionation of nano- and
microparticles in a rotating conoidal coiled
column, J. Anal. Chem., 2010, V. 65, No. 12,
pp. 1209-1214.
16. Fedotov P.S. Rotating coiled columns in
the speciation analysis of natural samples:
Dynamic fractionation of element forms in soils,
sludges, and bottom sediments, J. Anal. Chem.,
2012, V. 67, No. 5, pp. 399-413.
17. Fedotov P.S., Savonina E.Yu., Spivakov
B.Ya. et al. Possibilities for the harmonization
of methods of the dynamic fractionation
of elements in soils and bottom sediments, J.
Anal. Chem., 2012, V. 67, No. 10, pp. 851-861.
18. Ito Y. Development of high-speed
countercurrent chromatography, Advances in
Chromatogr., 1984, V. 24, pp. 181-226.
19. Ito Y. Cross-Axis Synchronous FlowThrough
Coil Planet Centrifuge Free of Rotary
Грибов и др. / Сорбционные и хроматографические процессы. 2015. Т. 15. Вып. 1
18
Seals for Preparative Countercurrent Chromatography.
Part I. Apparatus and Analysis of
Acceleration, Separation Science and Technology,
1987, V. 22, No. 8-10, pp. 1971-1987.
20. Mandava N.B., Ito Y. Principles and
instrumentation of countercurrent chromatography,
Countercurrent Chromatography. Theory
and Practice. Eds. Mandava N.B., Ito Y. Chromatographic
Science Series., 1988, V. 44,
pp. 79-442.
21. Ito Y. Speculation on the Mechanism of
Unilateral Hydrodynamic Distribution of Two
Immiscible Solvent Phases in the Rotating Coil,
J. Liq. Chromatogr., 1992, V. 15, No. 15-16,
pp. 2639-2675.
22. Ito Y. High-Speed Countercurrent Chromatography.
New York: Wiley, 1996, 477 p.
23. Wood P.L., Hawes D., Janaway L. et al.
Stationary Phase Retention in CCC: Modelling
the J-Type Centrifuge as a Constant Pressure
Drop Pump, J. Liq. Chrom. & Rel. Tech., 2003,
V. 26, No.9-10, pp. 1373-1396.
24. Fedotov P.S., Kronrod V.A., Maryutina
T.A. et al. Simulation of the Mechanism of
Liquid Stationary Phase Retention in a Rotating
Coil Column: Hydrophobic Liquid Systems, J.
Anal. Chem., 2002, V. 57, No. 1, pp. 24-30.
25. Fedotov P.S., Kronrod V.A., Kasatonova
O.N. Simulation of the motion of solid
particles in the carrier liquid flow in a rotating
coiled column, J. Anal. Chem., 2005, V. 60,
No. 4, pp. 310-316.
26. Zhukovsky N.E. Teoreticheskaya
mehanika [Theoretical Mechanics]. M.-L.:
GITTL, 1952, 107 p.
Published
2015-02-06
How to Cite
Михайлов, И. В., & Грибов, Л. А. (2015). Planetary centrifuge as a chromatographic device. Sorbtsionnye I Khromatograficheskie Protsessy, 15(1), 8-18. https://doi.org/10.17308/sorpchrom.2015.15/249
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