Transport properties of hybrid perfluorinated membranes MF-4SC volumetrically modified using halloysite nanotubes
Keywords:
perfluorinated membranes, halloysite nanotubes, volumetric modification, diffusion permeability, electric conductivity
Abstract
The transport properties of new hybrid materials for fuel cells and catalysis based on sulfacationic
membrane MF-4SC and halloysite nanotubes are studied. Physico-chemical characteristics of hybrid
membranes were calculated from the experimental data of NaCl solutions diffusion through the membrane
into the water using the Nernst-Planck approach and the least square method. To clarify the results of
calculations we can take into account both the diffusion layers. It is shown that adding halloysite nanotube
into a bulk matrix of the perfluorinated membrane markedly affects their exchange capacity as well as
structural and transport properties of modified membranes.
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2.Neburchilov V., Martin J., Wang H., Zhang J., J. Power Sources, 2007, Vol. 169, pp. 221 -238.
3.Safronova E.Yu., Stenina I.A., Yaroslavtsev A.B., J.inorganic Chemistry, 2010, Vol. 55, No 1, pp. 16-20.
4.Chircov Yu.G., Rostokin V.I., J. Electrochemestry, 2009, Vol. 45, No 2, pp.193 -202.
5.D’Epifanio A. et al., Chem. Mater., 2010, Vol. 22, pp. 813-821.
6.Pereira F. et al., Chem. Mater., 2008, Vol. 20, pp. 1710-1718.
7.Zabolotsky V.I., Nikonenko V.V. Ions transport in membranes. Moscow, Nauka Publ., 1996, 392 p.
8.Zabolotsky V.I., Nikonenko V.V., J. Membr. Sci., 1993, Vol. 79, pp. 181-198. 9.Filippov A.N., Starov V.M., Kononenko N.A., Berezina N.P., Adv. Colloid Interface Sci., 2008, Vol. 139, pp. 29-44.
10. Filippov A. et al., J. Material Sci and Chem. Engineering, 2015, No 3, pp. 58-65.
11. Berns B.A., Romanovicz V., de Camargo Forte M.M., Carpenter D.E.O.S., Int. J. Chemical, Biomolecular, Metallurgical, Materials Science and Engineering, 2013, Vol. 7, No 2, pp. 704-709.
12. Berezina N.P., Kononenko N.A., Dyomina O.A., Gnusin N.P., Adv. Colloid Interface Sci., 2008, Vol. 139, pp. 3-28.
13. Filippov A.N., Safronova EYu., Yaroslavtsev A.B., J. Membr. Sci., 2014, Vol. 471, pp. 110–117.
Published
2018-02-20
How to Cite
Афонин, Д. С., Филиппов, А. Н., Кононенко, Н. А., & Шкирская, С. А. (2018). Transport properties of hybrid perfluorinated membranes MF-4SC volumetrically modified using halloysite nanotubes. Sorbtsionnye I Khromatograficheskie Protsessy, 15(6), 867-873. https://doi.org/10.17308/sorpchrom.2015.15/342
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