Sorption of synthetic dyes polymers with molecular imprints

  • А. Н. Зяблов Zyablov Alexander N. – Dr. Sci.(Chemistry), associate professor оf Chair of Analytical Chemistry Voronezh State University; Voronezh
  • С. А. Хальзова Khalzova S.A. - postgraduate student department of analytical chemistry, Voronezh State University; Voronezh, e-mail: ahalzov@mail.ru
  • О. В. Дуванова Duvanova Olga V. - PhD in Chemistry, lead engineer, department of analytical chemistry, Voronezh State University; Voronezh
  • В. Ф. Селеменев Selemenev Vladimir F. – Dr. Sci.(Chemistry), professor, head of Department of Analytical Chemistry, Voronezh State University, Voronezh
  • А. Т. Козлов Kozlov Alexander T. - Ph. D., prof., Head. Department of Ecology, Voronezh Military Aviation Engineering Institute, Voronezh
Keywords: synthetic dyes, sorption, polymers with molecular imprints, imprinting factor.

Abstract

The method of non-covalent imprinting the resulting polymers with molecular imprints of synthetic
dyes on the basis of polyimides (the original monomers - 1,2,4,5-sensortechnology acid and 4,4’-
diaminodiphenyloxide), and the resulting polymers without addition of molecules of the template. Comparative
evaluation of the sorption capacity of PC and MIP synthetic dyes. The work established that the polymer
with molecular imprints can best absorb synthetic dyes. On the isotherms of sorption were calculated the distribution
coefficient, degree of extraction and imprinting factor. From the comparison of the obtained experimental
data show that high values of imprinting factor characteristic of the dye E110. We offer polymers
with molecular prints can be used as sorbents in the processes of separation and concentration, as a modifier
of piezoelectric sensors for selective determination of substances in liquid media.

Downloads

Download data is not yet available.

References

1. Kalach A.V., Zyablov A.N., Selemenev V.F., Sensory v analize gazov i zhidkostei, Voronezh, LIO, 2011, 240 p.
2. Ermolaeva T.N., Chernyshov V.N., Bessonov O.I., Sorbtsionnye i khromatograficheskie protsessy, 2015, Vol. 15, No 3, pp. 345-365.
3. Bessonov M.I. Polyimides – a new class of heat-resistant polymers. L., Nauka Publ., 1983, 328 p.
4. Buller K.W. Heat - resistant polymers. M., Chemistry Publ., 1984, 1056 p. 5. Zyablov A.N et al.. Patent RF, no 138636, 2014.
6. Duvanova O.V., Dashina A.I., Zyablov A.N. et al., Vestnik Voronezhskogo gosudarstvennogo agrarnogo universiteta, 2014, Vol. 3 (42), pp. 147-157.
7. Selemenev V.F., Slavinskaya G.V., Khokhlov V.Yu, et al. Praktikum po ionnomu obmenu. Voronezh, Izd-vo Voronezh. gos. u-ta, 2004, 160 p.
8. Kudrinskaya, V.A., Dmitrienko, S.G., Sorbtsionnye i khromatograficheskie protsessy, 2009, Vol. 9, No 6, pp. 824-829.
9. D'yakonova O. V. Diss. cand. сhem. nauk. Voronezh, 1999, 158 p.
Published
2018-02-21
How to Cite
Зяблов, А. Н., Хальзова, С. А., Дуванова, О. В., Селеменев, В. Ф., & Козлов, А. Т. (2018). Sorption of synthetic dyes polymers with molecular imprints. Sorbtsionnye I Khromatograficheskie Protsessy, 17(1), 156-160. https://doi.org/10.17308/sorpchrom.2017.17/365