Synthesis and study of graphene oxide obtained from waste transparent polythene bags using Modified Hummers method
Abstract
Purpose: Plastic industry has seen explosive growth in previous decades over the world. Every sphere of day to day life revolves around plastic products. The used plastic gets accumulated on the Earth s surface and serves as a contaminant causing soil, land and water pollution. Waste plastic needs proper management and elimination from the biotic layer of the ecosystem. Most potent solution is conversion of plastic waste into a functional carbon material. Present workconcentrates on upcycling of waste plastic into economically crucial material that is graphene oxide. The waste polythene bags were successfully converted to graphitic carbon which in turn serves as the base for the synthesis of graphene oxide using modified Hummers method.
Experimental: The analysis was made by studying the FTIR spectra, SEM images and XRD graphs. The FTIR confirms the presence of hydroxyl and carbonyl groups along with carbon carbon interaction. Surface orphology shows the porous and layered structure with an average particle size of 2.74 μm. X ray iffractogram illustrates the crystal structure of the graphene oxide and interlayer spacing.
Conclusions: With the characterisation results, the synthesis of graphene oxide from plastic waste was erified
Downloads
References
Bhattacharya R. R., Chandrasekhar K., Roy P., Khan A. Challenges and opportunities: plastic waste management in India. Available at: http://hdl.handle.net/2451/42242
Sandipan D. S. The concept of control and manage plastic pollution of India/world. The International Journal of Engineering and Science. 2016;5(6): 1–7. Available at: https://theijes.com/papers/v5-i6/version-2/A0506020107.pdf
Sruthy S., Ramasamy E. V. Microplastic pollution in Vembanad Lake, Kerala, India: the first report of microplastics in lake and estuarine sediments in India. Environmental pollution. 2017;222: 315–322. https://doi.org/10.1016/j.envpol.2016.12.038
Sunitha T. G., Monisha V., Sivanesan S., … Darchen A. Micro-plastic pollution along the Bay of Bengal coastal stretch of Tamil Nadu, South India. Science of the Total Environment. 2021;756: 144073. https://doi.org/10.1016/j.scitotenv.2020.144073
Verma R., Vinoda K. S., Papireddy M., Gowda A. N. Toxic pollutants from plastic waste-a review. Procedia Environmental Sciences. 2016;35: 701–708. https://doi.org/10.1016/j.proenv.2016.07.069
Schmaltz E., Melvin E. C., Diana Z., … Dunphy-Daly M. M. Plastic pollution solutions: emerging technologies to prevent and collect marine plastic pollution. Environment International. 20201;144: 106067. https://doi.org/10.1016/j.envint.2020.106067
Syamsiro M., Saptoadi H., Norsujianto T., … Yoshikawa K. Fuel oil production from municipal plastic wastes in sequential pyrolysis and catalytic reforming reactors. Energy Procedia. 2014;47: 180–188. https://doi.org/10.1016/j.egypro.2014.01.212
Faussone G. C. Transportation fuel from plastic: Two cases of study. Waste Management. 2018;73: 416–423. https://doi.org/10.1016/j.wasman.2017.11.027
Kumari M., Chaudhary G. R., Chaudhary S., Umar A. Transformation of solid plastic waste to activated carbon fibres for wastewater treatment. Chemosphere. 2022;294: 133692. https://doi.org/10.1016/j.chemosphere.2022.133692
da Silva E. P., Fragal V. H., Fragal E. H., … Muniz E. C. Sustainable energy and waste management: how to transform plastic waste into carbon nanostructures for electrochemical supercapacitors. Waste Management. 2023; 171: 71–85. https://doi.org/10.1016/j.wasman.2023.08.028
Shukla S., Kamal M. Plastic waste to functional carbon nanomaterials/graphene: a review. Essential Chem. 2024; 1(1): 1–2. https://doi.org/10.1080/28378083.2024.2407322
Berktas I., Hezarkhani M., Haghighi Poudeh L., Saner Okan B. Recent developments in the synthesis of raphene and graphene-like structures from waste sources by recycling and upcycling technologies: a review. Graphene Technology. 2020;5: 59–73. https://doi.org/10.1007/s41127-020-00033-1
Cooper D. R., D’Anjou B., Ghattamaneni N., … Yu V. Experimental review of graphene. ISRN Condensed Matter Physics. 2012: 1–56. https://doi.org/10.5402/2012/501686
Pei S., Cheng H. M. The reduction of graphene oxide. Carbon. 2012;50(9): 3210–3228. ttps://doi.org/10.1016/j.carbon.2011.11.010
Tiwari S. K., Mishra R. K., Ha S. K., Huczko A. Evolution of graphene oxide and graphene: from imagination to industrialization. ChemNanoMat. 2018;4(7): 598–620. https://doi.org/10.1002/cnma.201800089
Jiříčková A., Jankovský O., Sofer Z., Sedmidubský D. Synthesis and applications of graphene oxide. Materials. 2022;15(3): 920. https://doi.org/10.3390/ma15030920
Shahriary L., Athawale A. A. Graphene oxide synthesized by using modified hummers approach. International Journal of Renewable Energy and Environmental Engineering. 2014;2(01): 58-63.
Alam S. N., Sharma N., Kumar L. Synthesis of graphene oxide (GO) by modified hummers method and its thermal reduction to obtain reduced graphene oxide (rGO). Graphene. 2017;6(01): 1–18. https://doi.org/10.4236/graphene.2017.61001
Santamaría-Juárez G., Gómez-Barojas E., Quiroga-González E., Sánchez-Mora E., Quintana-Ruiz M., Santamaría-Juárez J. D. Safer modified Hummers’ method for the synthesis of graphene oxide with high quality and high yield. Materials Research Express. 2020;6(12): 125631. https://doi.org/10.1088/2053-1591/ab4cbf
Yoo M. J., Park H. B. Effect of hydrogen peroxide on properties of graphene oxide in Hummers method. arbon. 2019; 141: 515–22. https://doi.org/10.1016/j.carbon.2018.10.009
Sujiono E. H., Zabrian D., Dahlan M. Y., Amin B. D., Agus J. Graphene oxide based coconut shell waste: synthesis by modified Hummers method and characterization. Heliyon. 2020;6(8): e04568. https://doi.org/10.1016/j.heliyon.2020.e04568
Méndez-Lozano N., Pérez-Reynoso F., González-Gutiérrez C. Eco-friendly approach for graphene oxide synthesis by Modified Hummers method. Materials. 2022;15(20): 7228. https://doi.org/10.3390/ma15207228
Cao N., Zhang Y. Study of reduced graphene oxide preparation by Hummers’ method and related characterization. Journal of Nanomaterials. 2015;2015(1): 168125. https://doi.org/10.1155/2015/168125
Guerrero-Contreras J., Caballero-Briones F. Graphene oxide powders with different oxidation degree, prepared by synthesis variations of the Hummers method. Materials Chemistry and Physics. 2015;153: 209–220. https://doi.org/10.1016/j.matchemphys.2015.01.005
Alkhouzaam A., Qiblawey H., Khraisheh M., Atieh M., Al-Ghouti M. Synthesis of graphene oxides particle of igh oxidation degree using a modified Hummers method. Ceramics International. 2020;46(15): 23997–4007. https://doi.org/10.1016/j.ceramint.2020.06.177
Gul W., Akbar Shah R. S., Khan A., …Khan R. Synthesis of graphene oxide (GO) and reduced graphene oxide (rGO) and their application as nano-fillers to improve the physical and mechanical properties of medium density fibreboard. Frontiers in Materials. 2023;10. https://doi.org/10.3389/fmats.2023.1206918
Chen X., Qu Z., Liu Z., Ren G. Mechanism of oxidization of graphite to graphene oxide by the Hummers Method. ACS Omega. 2022;7(27): 23503–23510. https://doi.org/10.1021/acsomega.2c01963
Shamaila S., SajjadA. K. L., Iqbal A. Modifications in development of graphene oxide synthetic routes. Chemical Engineering Journal. 2016; 294: 458–477. https://doi.org/10.1016/j.cej.2016.02.109
Szabo T., Maroni P., Szilagyi I. Size-dependent aggregation of graphene oxide. Carbon. 2020;160: 145–55. https://doi.org/10.1016/j.carbon.2020.01.022
Hou Y., Lv S., Liu L., Liu X. High-quality preparation of graphene oxide via the Hummers' method: inderstanding the roles of the intercalator, oxidant, and graphite particle size. Ceramics International. 2020;46(2): 2392–2402. https://doi.org/10.1016/j.ceramint.2019.09.231
Marcano D. C., Kosynkin D. V., Berlin J. M., … Tour J. M. Improved synthesis of graphene oxide. ACS nano. 2010;4(8): 4806–4814. https://doi.org/10.1021/nn1006368
Surekha G., Krishnaiah K. V., Ravi N., Suvarna R. P. FTIR, Raman and XRD analysis of graphene oxide films prepared by modified Hummers method. Journal of Physics: Conference Series. 2020;1495(1): 012012). https://doi.org/10.1088/1742-6596/1495/1/012012
Zaaba N. I., Foo K. L., Hashim U., Tan S. J., Liu W. W., Voon C. H. Synthesis of graphene oxide using modified hummers method: solvent influence. Procedia Engineering. 2017; 184: 469–477. https://doi.org/10.1016/j.proeng.2017.04.118
Copyright (c) 2025 Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases

This work is licensed under a Creative Commons Attribution 4.0 International License.








