Thermodynamic study of manganese tellurides by the electromotive force method

Elnur N. Orujlu; Ziya S. Aliev; Yasin I. Jafarov; Eldar I. Ahmadov; Mahammad B. Babanly

doi:10.17308/kcmf.2021.23/3438

Elnur N. Orujlu Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan https://orcid.org/0000-0001-8955-7910
Ziya S. Aliev Azerbaijan State Oil and Industry University, 6/21 Azadlэq ave., Baku AZ-1010, Azerbaijan https://orcid.org/0000-0001-5724-4637
Yasin I. Jafarov Baku State University, 23 Z. Khalilov Street, Baku Az-1148 Azerbaijan https://orcid.org/0000-0002-6597-2252
Eldar I. Ahmadov Baku State University, 23 Z. Khalilov Street, Baku Az-1148 Azerbaijan
Mahammad B. Babanly Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan; Baku State University, 23 Z. Khalilov Street, Baku Az-1148 Azerbaijan https://orcid.org/0000-0001-5962-3710

DOI: https://doi.org/10.17308/kcmf.2021.23/3438

Keywords: Electromotive force method, Thermodynamic properties, Manganese tellurides, MnTe, MnTe2, Partial molar functions

Abstract

The thermodynamic properties of manganese tellurides were determined using an electromotive force (EMF) method with a liquid electrolyte in a temperature range from 300 to 450 K. EMF measurements were performed using equilibrium samples taken from the two-phase regions, namely MnTe₂ + Te and MnTe + MnTe₂, of the Mn–Te system. The phase compositions of all samples were controlled with the X-ray diffraction (XRD) method. The partial molar functions of manganese in alloys, as well as the standard thermodynamic functions of the formation and standard entropies of MnTe and MnTe₂, were calculated. A comparative analysis of obtained results with literature data is performed

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Author Biographies

Elnur N. Orujlu, Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan

PhD student, Junior Researcher at
the Institute of Catalysis and Inorganic Chemistry,
Azerbaijan National Academy of Sciences, Baku,
Azerbaijan; e-mail: elnur.oruclu@yahoo.com

Ziya S. Aliev, Azerbaijan State Oil and Industry University, 6/21 Azadlэq ave., Baku AZ-1010, Azerbaijan

PhD in Chemistry, Assistance
Professor, Azerbaijan State Oil and Industry University,
Baku, Azerbaijan; e-mail: ziyasaliev@gmail.com

Yasin I. Jafarov, Baku State University, 23 Z. Khalilov Street, Baku Az-1148 Azerbaijan

DSc in Chemistry, Associate
Professor, Baku State University, Baku, Azerbaijan;
e-mail: yasin.cafarov@hotmail.com

Eldar I. Ahmadov, Baku State University, 23 Z. Khalilov Street, Baku Az-1148 Azerbaijan

DSc in Chemistry, Professor,
Baku State University, Baku, Azerbaijan; e-mail:
eldar_akhmedov@mail.ru

Mahammad B. Babanly, Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan; Baku State University, 23 Z. Khalilov Street, Baku Az-1148 Azerbaijan

Corresponding Member of
the Azerbaijan National Academy of Sciences, Deputydirector
of the Institute of Catalysis and Inorganic
Chemistry, Azerbaijan National Academy of Sciences,
Baku State University, Baku, Azerbaijan; e-mail:
babanlymb@gmail.com

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