Термодинамическое исследование теллуридов марганца методом электродвижущих сил
Аннотация
Термодинамические свойства теллуридов марганца изучены методом электродвижущих сил (ЭДС) с жидким электролитом в интервале температур от 300–450 К. Измерения ЭДС проводились на равновесных образцах из двухфазных областей – MnTe2+Te и MnTe+MnTe2 системы Mn–Te. Фазовые составы всех образцов контролировали методом рентгенофазового анализа (РФА). Из данных измерений ЭДС рассчитаны парциальные молярные функции марганца в сплавах, а также стандартные термодинамические функции образования и стандартные энтропии соединений MnTe и MnTe2. Проведен сравнительный анализ полученных результатов с литературными данными
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