MOCVD and ferromagnetic resonance of epitaxial Lu3Fe5O12 films for high-frequency applications
DOI:
https://doi.org/10.17308/kcmf.2026.28/13564Keywords:
Thin films, Iron garnet, MOCVD, Structure, Ferrimagnetic resonanceAbstract
Objectives: The production of thin films of rare earth iron garnets with a narrower ferrimagnetic resonance (FMR) linewidth is extremely important in the development of spintronic materials. Among rare earth iron garnets, the compound Lu3Fe5O12, which has the highest saturation magnetization, is promising. The aim of this work is to study the dependence of the FMR linewidth of Lu3Fe5O12 iron garnet films on the lattice mismatch between the film and the substrate, as well as on the film thickness during their production by metalorganic chemical vapor deposition (MOCVD).
Experimental: Thin films of Lu3Fe5O12 garnet were obtained by MOCVD technique on isostructural single-crystal substrates of Nd3Ga5O12(111), Gd3Ga5O12(111), Gd3Ga5O12(210), Gd3(AlGa4)O12(111) and Y3Al5O12(111). The films were studied by XRD, EDX, and FMR methods. The dependences of the FMR linewidth on the mismatch of the unit cell (UC) parameters of the garnet at the film–substrate interface, substrate orientation, and film thickness were studied.
Conclusions: It has been established that the minimum FMR linewidth (ΔН) of Lu3Fe5O12 films is achieved on substrates with minimal mismatch at the interface. The dependence of ΔН on film thickness is shown to be extreme, with the minimum corresponding to a film thickness at which significant relaxation of epitaxial stresses has occurred, but the concentration of defects characteristic of the polycrystalline state is still low. Taking these factors into account will make it possible to obtain iron garnet films with a narrower ferromagnetic resonance linewidth, which can subsequently be used in various areas of spintronics as sensitive elements in microwave detectors
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1. Yang Y., Liu T., Bi L., Deng L. Recent advances in development of magnetic garnet thin films for applications in spintronics and photonics. Journal of Alloys and Compounds. 2021;860: 158235. https://doi.org/10.1016/j.jallcom.2020.158235
2. Borisenko V. E., Danilyuk A. L., Migas D. B. Spintronics*. Laboratoriya znaniy Publ.; 2017. 229 p. (in Russ.)
3. Nikitov S. A., Kalyabin D. V., Lisenkov I. V… Pavlov E. S. Magnonics: a new research area in spintronics and spin wave electronics. Physics-Uspekhi. 2015;58: 1002–1028. https://doi.org/10.3367/UFNr.0185.201510m.1099
4. Žutić I., Fabian J., Das Sarma S. Spintronics: fundamentals and applications. Reviews of Modern Physics. 2004; 76(2): 323–410. https://doi.org/10.1103/RevModPhys.76.323
5. Fert A. Nobel lecture: origin, development, and future of spintronics*. Reviews of Modern Physics. 2008;80(4): 1517–1530. https://doi.org/10.1103/RevModPhys.80.1517
6. Hirohata A., Yamada K., Nakatani Y., … Hillebrands B. Review on spintronics: principles and device applications. Journal of Magnetism and Magnetic Materials. 2020;509: 166711. https://doi.org/10.1016/j.jmmm.2020.166711
7. Chechenin N. G., Dzhun I. O., Babaytsev G. V., Kozin M. G., Makunin A. V., Romashkina I.L. FMR damping in thin films with exchange bias. Magnetochemistry. 2021; 7(5): 70. https://doi.org/10.3390/magnetochemistry7050070
8. Geller S. Crystal chemistry of the garnets. Zeitschrift für Kristallographie; 1967;125: 1-47. https://doi.org/10.1524/zkri.1967.125.16.1
9. Liu C., Chen J., Liu T., … Wu M. Long-distance propagation of short-wavelength spin waves. Nature Communications. 2018;9(1): 738. https://doi.org/10.1038/s41467-018-03199-8
10. Zhu D., Zhao W. Threshold current density for perpendicular magnetization switching through spin-orbit torque. Physical Review Applied. 2020;13(4): 044078. https://doi.org/10.1103/PhysRevApplied.13.044078
11. Hahn C., de Loubens G., Klein O., Viret M., Naletov V. V., Ben Youssef J. Comparative measurements of inverse spin Hall effects and magnetoresistance in YIG/Pt and YIG/Ta. Physical Review B. 2013;87(17): 174417. https://doi.org/10.1103/PhysRevB.87.174417
12. Knauer S., Davídková K., Schmoll D., … Chumak A. V. Propagating spin-wave spectroscopy in a liquid-phase epitaxial nanometer-thick YIG film at millikelvin temperatures. Journal of Applied Physics. 2023;133(14): 143905. https://doi.org/10.1063/5.0137437
13. Jermain C. L., Paik H., Aradhya S. V., Buhrman R. A., Schlom D. G., Ralph D. C. Low-damping sub-10-nm thin films of lutetium iron garnet grown by molecular-beam epitaxy. Applied Physics Letters. 2016;109(19): 192408. https://doi.org/10.1063/1.4967695
14. Wu X., Wang X., Liu Y., … Zhu J. Study on dielectric and magnetodielectric properties of Lu3Fe5O12 ceramics. Applied Physics Letters. 2009;95: 182903. https://doi.org/10.1063/1.3259651
15. Hou Y. Epitaxial growth and observation of the magnetodielectric effect in ferrimagnetic Lu3Fe5O12 films. Journal of Physics D: Applied Physics. 2018;51(27): 275001. https://doi.org/10.1088/1361-6463/aac8d1
16. Hioki T., Hashimoto Y., Saitoh E. Bi-reflection of spin waves. Communications Physics. 2020;3: 188. https://doi.org/10.1038/s42005-020-00455-6
17. Volkov D. A., Gabrielyan D. A., Matveev A. A., … Nikitov S. A. Spin pumping from Lu3Fe5O12. JETP Letters. 2024; 119(5): 357–362. https://doi.org/10.1134/S0021364024600150
18. Dubs C., Surzhenko O. Magnetically compensated nanometer-thin Ga-substituted yttrium iron garnet (Ga:YIG) films with robust perpendicular magnetic anisotropy. Advanced Electronic Materials. 2025;11(15): e00232. https://doi.org/10.1002/aelm.202500232
19. Arsad A. Z., Zuhdi A. W. M., Ibrahim N. B., Hannan M. A. Recent advances in yttrium iron garnet films: methodologies, characterization, properties, applications, and bibliometric analysis for future research directions. Applied Sciences. 2023;13(2): 1218. https://doi.org/10.3390/app13021218
20. Yakovlev Yu. M., Gendelev S. Sh. Iron ferrites monocrystals in radioelectonics*. “Sovetskoye Radio” Publ.; 1975. 360 p. (in Russ.)
21. Yushchuk S. I. Layered structure of epitaxial yttrium iron garnet films. Technical Physics. 1999;44: 1454–1456. https://doi.org/10.1134/1.1259547
22. Prokopov A. R., Vetoshko P. M., Shumilov A. G., … Belotelov V. I. Epitaxial Bi–Gd–Sc iron-garnet films for magnetophotonic applications. Journal of Alloys and Compounds. 2016;671: 403–407. https://doi.org/10.1016/j.jallcom.2016.02.036
23. Soumah L., Beaulieu N., Qassym L., … Anane A. Ultra-low damping insulating magnetic thin films get perpendicular. Nature Communications. 2018;9(1): 3355. https://doi.org/10.1038/s41467-018-05732-1
24. Yamahara H., Feng B., Seki M., … Tabata H. Flexoelectric nanodomains in rare-earth iron garnet thin films under strain gradient. Communications Materials. 2021;2: 95. https://doi.org/10.1038/s43246-021-00199-y
25. Khurana B., Kaczmarek A. C., Chou C.-T., … Ross C. A. Rare earth iron garnet superlattices with sub-unit-cell composition modulation. ACS Nano. 2024;18(52): 35269–35275. https://doi.org/10.1021/acsnano.4c11117
26. Ahamed E. I., Sarker M. S., Yamahara H., … Tabata H. Spin wave perturbation in rare-earth iron garnet thin films with epitaxial strain relaxation. APL Materials. 2025;13: 041114. https://doi.org/10.1063/5.0257413
27. Krichevtsov B. B., Gastev S. V., Suturin S. M., … Sokolov N. S. Magnetization reversal in YIG/GGG(111) nanoheterostructures grown by laser molecular beam epitaxy. Science and Technology of Advanced Materials. 2017;18(1): 351–363. https://doi.org/10.1080/14686996.2017.1316422
28. Samoilenko K. D., Volkov D. A., Gabrielyan D. A., … Nikitov S. A. Spintronic detector of linearly polarized microwave radiation based on a ferromagnet/normal metal heterostructure. JETP Letters, 2025;121(7): 554–561. https://doi.org/10.1134/S002136402460530X
29. Markelova M. N., Hafizov A. A., Shi X., … Kaul A. R. Chemical vapor deposition of Tm3Fe5O12 epitaxial films, investigation of their structure and properties in the terahertz range. Condensed Matter and Interphases. 2025;27(1): 104–114. https://doi.org/10.17308/kcmf.2025.27/12488
30. Popova E., Keller N., Jomard F., … Tessier M. Exchange coupling in ultrathin epitaxial yttrium iron garnet films. The European Physical Journal B - Condensed Matter. 2003;31: 69–74. https://doi.org/10.1140/epjb/e2003-00010-2
31. Bossak A., Graboy I., Gorbenko O., … Zandbergen H. W. XRD and HREM studies of epitaxially stabilized hexagonal orthoferrites RFeO3 (R = Eu–Lu). Chemistry of Materials. 2004;16(9): 1751–1755. https://doi.org/10.1021/cm0353660
32. Kaul A. R., Nygaard R. R., Ratovskiy V. Yu., Vasiliev A. L. TSF-MOCVD – a novel technique for chemical vapour deposition on oxide thin films and layered heterostructures. Condensed Matter and Interphases. 2021;23(3): 396–405. https://doi.org/10.17308/kcmf.2021.23/3531
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