INTERFACIAL REACTION OF CeO2 FILMS WITH TEXTURED Ni-ALLOY SUBSTRATES

  • Georgy A. Dosovitskiy Ph.D., Researcher at Neo- Chem JSC, Moscow, Russian Federation
  • Vadim A. Amelichev Ph.D., Researcher at SuperOx Company, Moscow, Russian Federation
  • Sergey V. Samoilenkov Ph.D., Chief Technology Officer at SuperOx Company, Moscow, Russian Federation
  • Dominique Eyidi Ph.D., Researcher at Pole Polytechnique de Recherche en Ingeniérie, Matériaux et Energétique, Chasseneuil CEDEX, France
  • Bertrand Lacroix Ph.D., Pole Polytechnique de Recherche en Ingeniérie, Matériaux et Energétique, Chasseneuil CEDEX, France
  • Fabien Paumier Ph.D., Researcher at Pole Polytechnique de Recherche en Ingeniérie, Matériaux et Energétique, Chasseneuil CEDEX, France
  • Dmitry P. Rodionov Dr.Sci., Leading Researcher at Institute of Metals Physics, Ural dpt. of RAS, Ekaterinburg, Russian Federation
  • Rolly J. Gaboriaud Professor, Head of laborattory at Pole Polytechnique de Recherche en Ingeniérie, Matériaux et Energétique, Chasseneuil CEDEX, France
  • Andrey R. Kaul Dr. Sci. (Chem.), Professor, Head of laborattory at Chemistry Department, Moscow State University, Moscow, Russian Federation, Chief Scientist at SuperOx Company, Moscow, Russian Federation
Keywords: alloys, oxides, thin films, interfaces, chemical vapor deposition (CVD), epitaxial growth, annealing, electron microscopy, recrystallization, phase equilibria.

Abstract

CeO2 films were deposited on biaxially textured tapes of Ni-W and Ni-Cr-W alloys using MOCVD at 550 °C and subsequently treated in post-deposition annealing at 1000 °C and reducing atmosphere. Upon annealing of the films on the Ni-W alloy substrate, cube texture in the CeO2 films
was formed, and the oxide had an epitaxial interface with the Ni-W alloy substrate as shown by high resolution transmission electron microscopy. Similar annealing of the CeO2 films on the Ni-Cr-W alloy substrate resulted in interaction of the oxide layer with the metal substrate leading to the formation of epitaxial NiO interlayer at the CeO2/Ni-Cr-W interface.

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Published
2013-09-27
How to Cite
Dosovitskiy, G. A., Amelichev, V. A., Samoilenkov, S. V., Eyidi, D., Lacroix, B., Paumier, F., Rodionov, D. P., Gaboriaud, R. J., & Kaul, A. R. (2013). INTERFACIAL REACTION OF CeO2 FILMS WITH TEXTURED Ni-ALLOY SUBSTRATES. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 15(3), 217-223. Retrieved from https://journals.vsu.ru/kcmf/article/view/900
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