ТРОЙНЫЕ СИСТЕМЫ AV–BVI–I: КРАТКИЙ ОБЗОР ФАЗОВЫХ РАВНОВЕСИЙ ОБЗОР

Аннотация

В работе представлен краткий обзор по фазовым равновесиям в тройных системах AV–BVI–I (AV = Sb, Bi; BVI = S, Se, Te). Эти системы характеризуются образованием ряда тройных соединений, являющихся перспективными базовыми материалами для фото-, термо- и ферроэлектрических преобразователей энергии. Некоторые из них демонстрируют гигантское спиновое расщепление Рашба, в результате чего на поверхности кристалла возникает уникальная тороидальная 3Д поверхность Ферми, которая приводит к необычным свойствам, открывающим возможность реализации на основе этих соединений уникальных электронных устройств. Разработка методов направленного синтеза указанных соединений и мультифункциональных материалов на их основе базируется на данных по фазовым равновесиям в соответствующих системах.

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