ИССЛЕДОВАНИЕ МЕЖАТОМНОГО ВЗАИМОДЕЙСТВИЯ В МНОГОСЛОЙНЫХ НАНОСТРУКТУРАХ (Co45Fe45Zr10/a-Si)40 И (Co45Fe45Zr10/SiO2)32 МЕТОДАМИ ИК-СПЕКТРОСКОПИИ И МАЛОУГЛОВОЙ ДИФРАКЦИИ

Evelina P. Domashevskaya; Van Tu Chan; Alex V. Chernyshev; Anatoly N. Lukin

doi:10.17308/kcmf.2017.19/192

Evelina P. Domashevskaya Dr. Sci. (Phys.-Math.), Full Professor, Head of Solid State Physic and Nanostructures Department, Voronezh State University; ph.: +7(473) 2208363; e-mail: ftt@phys.vsu.ru
Van Tu Chan the competitor for science degree of Master Science, Solid State Physic and Nanostructures Department, Voronezh State University; ph.: +7(473) 2208363, e-mail: ftt@phys.vsu.ru
Alex V. Chernyshev postgraduate student, Solid State Physic and Nanostructures Department, Voronezh State University; ph.: +7(473) 2208363, e-mail: ftt@phys.vsu.ru
Anatoly N. Lukin Cand. Sci. (Phys.-Math.), Associated Professor, Solid State Physics and Nanostructures Department, Voronezh State University; ph.: +7(473) 2208363, e-mail: ftt@phys.vsu.ru

DOI: https://doi.org/10.17308/kcmf.2017.19/192

Keywords: IR spectroscopy, small-angle X-ray diffraction, multilayer nanostructures, metallic layers, nonmetallic interlayers

Abstract

The aim of this work is to confirm the chemical bonds between the components of multilayer nanostructure (MLNS) by IR spectroscopy, the identification of the IR spectra in the MLNS (Co₄₅Fe₄₅Zr₁₀/a-Si)₄₀ and (Co₄₅Fe₄₅Zr₁₀/SiO₂)₃₂ with the same metal layers and various interlayers- amorphous silicon or silicon dioxide and estimation of their thickness by the method of small-angle X-ray diffraction.

The presence of interatomic Co-Fe and Fe-Zr bonds in metallic granules and the bonds with oxygen of metal layers components Fe-O and Co-O and nonmetallic Si-O-Si and Si-O interlayers was confirmed by IR spectroscopy.

Small-angle x-ray diffraction produces reflections of three types (from bilayers, from metallic layers and from interlayers) only in samples with the thickest interlayers. Samples with the thinnest interlayers do not give comparable reflections from metal layers and interlayers due to their mixing with the formation of oxide and silicide phases of d-metals.

ACKNOWLEDGMENTS

The work was financially supported by the Ministry of Education and Science of Russia within the framework of the state task to universities in the field of scientific activity for 2017-2019. Project No. 3.6263.2017 / ВУ

The research results were obtained with equipment of Voronezh State University Centre for Collective Use of Scientific Equipment.

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References

1. Shchekochikhin A. V., Domashevskaya E. P., Karpov S. I. Condensed Matter and Interphases, 2006, vol. 8, no. 1, p. 64-66. Available at: http://www.kcmf.vsu.ru/resources/t_08_1_2006_013.pdf (in Russian)
2. Schekochikhin A. V., Domashevskaya E. P., Karpov S. I., Stognei O. V. // Bulletin of VSU, Series: Physics. Mathematics, 2008, no. 1, pp. 109-114. Available at: http://www.vestnik.vsu.ru/pdf/physmath/2008/01/schekochihin.pdf (in Russian)
3. Domashevskaya E. P., Storozhilov S. A., Turischev S. Yu., Kashkarov V. M., Terekhov V. A., Stogney O. V., Kalinin Yu. E., Sitnikov A. V., Molodtsov S. L. Phys. Solid State, 2008, vol. 50, no. 1, pp. 139 - 145. doi:10.1134/S1063783408010253
4. Domashevskaya E. P., Storozhilov S. A., Turischev S. Yu., Kashkarov V. M., Terekhov V. A., Stogney O. V., Kalinin Yu. E., Sitnikov A. V. , Molodtsov S. L. Bulletin of the Russian Academy of Sciences: Physics, 2008, vol. 72, no. 4, pp. 439-442 DOI: 10.3103/S1062873808040059
5. Domashevskaya E. P., Storozhilov S. A., Turishchev S. Yu., Kashkarov V. M., Terekhov V. A., Stognej O. V., Kalinin Yu. E., Molodtsov S. L. Journal of Electron Spectroscopy and Related Phenomena, 2007, vol. 156 - 158, pp. 180 - 185. http://doi.org/10.1016/j.elspec.2006.11.035
6. Domashevskaya E. P., Chernyshev A. V., Turischev S. Yu., Kalinin Yu. E., Sitnikov A. V., Marchenko D. E. Phys. Solid State, 2013, vol. 55, no. 6, p. 1294-1303. doi:10.1134/S1063783413060097
7. Domashevskaya E. P., Chernyshev A. V., Turischev S. Yu., Kalinin Yu. E., Sitnikov A. V., Marchenko D. E. Phys. Solid State, 2014, vol. 56, no. 11, pp. 2294–2306. doi:10.1134/S1063783414110067
8. Domashevskaya E. P., Terekhov V. A., Turischev S. Yu., Spirin D. E., Chernyshev A. V., Kalinin Yu. E., Sitnikov A. V. Phys. Solid State, 2016, vol. 58, no. 5, pp. 1024–1033. doi:10.1134/S1063783416050061
9. Domashevskaya E. P., Guda A. A., Chernyshev A. V., Sitnikov V. G. Phys. Solid State, 2017, vol. 59, no. 2, pp. 385–391. doi:10.1134/S1063783417020068
10. Aronzon B. A., Granovsky A. B., Davydov A. B., Dokukin M. E., Kalinin Yu. E., Nikolaev S. N., Rylkov V. V., Sitnikov A. V. , Tugushev V. V. J. Exp. Theor. Phys., 2006, vol. 103, no. 1,
110–118. doi:10.1134/S1063776106070120
11. Stogney O. V., Kalinin Yu. E., Sitnikov A. V. The Physics of Metals and Metallography, 2001, vol. 91, no. 1, p. 21-28.
12. Bouzourâa M. B., Rahmani M., Zaïbi M. A., Lorrain N., Hajji L., Oueslatihttps M. // hal.inria.fr/file/index/docid/840826//pp.1-16.
13. Chetverikova A. G., Maryakhina V. S. The Bulletin of the Orenburg State University, 2015, vol. 176, no. 1, pp. 250-255.
14. Pankov V. V., Ivanovskaya M. I., Kotikov D. A. Chemical Problems of Creating New Materials and Technology. Sat. Ed. by Ivashkevich O. A., Minsk, BSU Publ., 2008, iss. 3, pp. 24-38.
15. Kiose T. L., Dzhiga T. A., Toporov A. M., Rakitska S. V. News of ONU, Khimiya, 2012, vol. 17, no. 1 (41) pp. 13-19.
16. Pérez Bernal M. E., Ruano Casero R. J., Rives V. Ceramics - Silikáty, 2004, vol. 48, no. 4, pp. 145-154.
17. Spring Marika, Higgiti Catherine, Saunders David. National Gallery Technical Bulletin, 2005, vol. 26, pp. 56-70.