INTERLAYER SELF-ASSEMBLY OF 2D NANOCOMPOSITES BASED ON LAYERED PRECURSOR

  • Tatyana V. Kulikova postgraduate student, Department of Physics of Semiconductors and Microelectronics, Voronezh State University; ph.: +7 (908) 1445155, e-mail: kaimt@mail.ru
  • Andrey V. Tuchin Cand. Sci. (Phys.-Math.), Department of Physics of Semiconductors and Microelectronics, Voronezh State University; ph.: +7 (908) 1485775, e-mail: a.tuchin@bk.ru
  • Dmitriy А. Testov student of Department of Physics of Semiconductors and Microelectronics, Voronezh State University; ph.: +7 (910) 2406971, e-mail: dmitriytestov@gmail.com
  • Larisa А. Bityutskaya Bityutskaya Larisa A. – Cand. Sci. (Chem.), Department of Physics of Semiconductors and Microelectronics, Voronezh State University; ph.: +7 (473) 2208481, e-mail: me144@phys.vsu.r
Keywords: composite, self-assembly, layered precursor, colloidal solution, ultrasound, hydrodynamics, instability, electrostatics

Abstract

The purpose of this work is to study the conditions of formation of the composite structures in colloidal solutions of layered precursors (antimony, graphite).

Two-dimensional (2D) allotropes can be considered as building blocks in colloidal solutions of layered precursors. To study the possible interactions of the mono- and multilayers in a colloidal solution of antimony, we carried out quantum-chemical modeling based on the density functional theory (DFT). With a consecutive increase in the number of layers in the structure of antimony, a qualitative change in the distribution of the electron density occurs and it induces an excess positive charge on the outer faces of the layers. The inside layers are neutral as in a single-layer antimonene.

Thus, the presence of charge in the layers is the basis for developing methods and technology of the self-assembly of planar 2D structures of layered precursors and composites based on them.

The formation of the planar 2D structures of antimony and graphite and composites based on them occurs as a result of many hours of ultrasonic exposure to a solution of isopropyl alcohol and water and a finely dispersed single crystal of antimony or highly oriented pyrolytic graphite. The occurrences of self-activated colloidal solutions are determined.  The self-activated colloidal solutions are characterized by the presence of long-term nonlinear hydrodynamic effects in a colloidal solution of the antimony, correlated with periodic changes in the particle size in the solution. The experimentally observed processes indicate the presence of 2D structures with a different number of layers in the volume of the solution, differing in the type and magnitude of the charge.

The electrostatically active environment of the colloidal solution creates conditions for the self-assembly of the planar structures of the original precursors and composite structures based on them.

As a result, multilayered 2D allotropes of antimony, graphite and two types of composite structures: a multilayer multigrahene / antimony structure and a polymorphic – multigrafene/nanofiber were obtained.

ACKNOWLEDGMENTS

The reported study was funded by RFBR according to the research(project No. 16-43-360281 р_а)

The research results were obtained with equipment of Voronezh State University Centre for Collective Use of Scientific Equipment.

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References

1. Novoselov K. S. UFN, 2011, no. 181, pp. 1299–1311. DOI: 10.3367/UFNr.0181.201112f.1299
2. Geim A. K. UFN, 2011, no. 181, pp. 1284–1298. DOI: 10.3367/UFNr.0181.201112e.1284
3. Yuanfeng Xu, Bo Peng, Hao Zhang, et al. Ann. Phys. (Berlin), 2017, p. 1600152. DOI: 10.1002/andp.201600152
4. Shengli Zhang, Zhong Yan, Yafei Li, et al. Angew. Chem. Int. Ed., 2015, no. 54, vol. 10, pp. 3112–3115. DOI: 10.1002/anie.201411246
5. Mingwen Zhao, Xiaoming Zhang, Linyang Li. Scientific Reports, 2015, vol. 5, p. 16108. DOI: 10.1038/srep16108
6. Bian G., Miller T., Chiang T.-C. Physical Review Letters, 2011, no. 107, vol. 3, p. 036802. DOI: 10.1103/PhysRevLett.107.036802
7. Sung Hwan Kim, Kyung-Hwan Jin, Joonbum Park, et al. Scientific Reports, 2016, vol. 6, p. 33193. DOI: 10.1038/srep33193
8. Pablo Ares, Fernando Aguilar-Galindo, David Rodríguez-San-Miguel, et al. Adv. Mater., 2016, no. 28, vol. 30, pp. 6332–6336. DOI: 10.1002/adma.201602128
9. Carlos Gibaja, David Rodriguez-San-Miguel, Pablo Ares, et al. Angew. Chem. Int. Ed., 2016, no. 55, vol. 46, pp. 14345–14349. DOI: 10.1002/anie.201605298
10. Jianping Ji, Xiufeng Song, Jizi Liu, et al. Nature Communications, 2016, vol 7, p. 13352. DOI: 10.1038/ncomms13352
11. Jiangfeng Qian, Yao Chen, Lin Wu, et al. Chem. Commun., 2012, no. 48, pp. 7070-7072. DOI:10.1039/C2CC32730A
12. Nithya C., Gopukumar S. J. Mater. Chem. A, 2014, no. 2, pp. 10516-10525. DOI:10.1039/C4TA01324G
13. Zhu Y., Han X., Xu Y., et al. ACS Nano, 2013, no. 7, vol. 7, pp. 6378–6386. DOI: 10.1021/nn4025674
14. Zhou X., Zhong Y., Yang M., et al. Chem. Commun., 2014, no. 50, pp. 12888-12891. DOI: 10.1039/C4CC05989A
15. Hou H., Jing M., Yang Y., et al. ACS Appl. Mater. Interfaces, 2014, no. 6, vol. 18, pp. 16189–16196. DOI: 10.1021/am504310k
16. Zhou X., Dai Z., Bao J., Guo Y.-G. J. Mater. Chem. A, 2013, no. 1, pp. 13727-13731. DOI: 10.1039/C3TA13438E
17. Wen Luo, Pengfei Zhang, Xuanpeng Wang, et al. Journal of Power Sources, 2016, no. 304 (340e345). DOI 10.1016/j.jpowsour.2015.11.047
18. Fang Wan, Jin-Zhi Guo, Xiao-Hua Zhang, et al. ACS Appl. Mater. Interfaces, 2016, no. 8, vol. 12, pp. 7790–7799. DOI: 10.1021/acsami.5b12242
19. Ning Zhang, Yongchang Liu, Yanying Lu, et al. Nano Res., 2015, vol. 8, p. 3384. DOI:10.1007/s12274-015-0838-3
20. Tuchin A. V., Zhukalin D. A., Bityutskaya L. A., Kalashnikov A. V. Letters on Materials, 2016, no. 6, vol. 4, pp. 333–337
21. Zhukalin D. A., Tuchin A. V., Goloshchapov D. L., Bityutskaya L. A. Technical Physics Letters, 2015, no. 41, vol. 4, pp. 1–6.
22. Mansoori G.A. Principles of Nanotechnology. World Scientific Publishing Co. Pte. Ltd., 2005, 360 p.
23. Wei Fan, Longsheng Zhang, Tianxi Liu. Graphene-Carbon Nanotube Hybrids for Energy and Environmental Applications. Springer Singapore, 2017, 104 p. DOI: 10.1007/978-981-10-2803-8
Published
2017-11-07
How to Cite
Kulikova, T. V., Tuchin, A. V., TestovD. А., & BityutskayaL. А. (2017). INTERLAYER SELF-ASSEMBLY OF 2D NANOCOMPOSITES BASED ON LAYERED PRECURSOR. Condensed Matter and Interphases, 19(3), 368-375. https://doi.org/10.17308/kcmf.2017.19/213
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